吡虫啉的太赫兹(THz)光谱研究

由超短激光脉冲产生的脉冲波是具有较宽频带的电磁辐射,属于远红外波段,该波段电磁波与物质的相互作用是个崭新的研究领域。文章利用太赫兹时域光谱技术测量了室温下吡虫啉在0.2～2.0 THz范围内的吸收谱和折射率谱。结果表明吡虫啉在此波段有明显的特征吸收峰且吸收系数随频率的增加而增大,折射率也随频率的增加而有所增大,其平均折射率为1.65。实验研究的同时,运用半经验理论计算了吡虫啉分子的结构及其在太赫兹波段的振动频率,并根据计算结果对实验数据进行了解析。计算结果与实验光谱吻合得很好,实验光谱的特征吸收峰是由分子的集体振动及扭转形成, 不同的吸收峰位对应分子不同的振转模式。实验和理论研究的对比表明：分子的远红外吸收特征对于分子的结构和空间排列非常敏感,THz-TDS是研究生物分子集体振动模式和构象结构的好方法。     

氟化铵溶液与氯化铝溶液混合有没有沉淀生成

对苏教版《实验化学（选修）》实验“氟化铵溶液与氯化铝溶液反应”作了探究,并从理论上作初步猜想。否定了教学参考书有关该反应无沉淀的论点。     

Initial value problem for a class of fourth-order nonlinear wave equations

In this paper, existence and uniqueness of the generalized global solution and the classical global solution to the initial value problem for a class of fourth-order nonlinear wave equations are studied in the fractional order Sobolev space using the contraction mapping principle and the extension theorem. The sufficient conditions for the blow up of the solution to the initial value problem are given.     

Critical velocity of sandwich cylindrical shell under moving internal pressure

Critical velocity of an infinite long sandwich shell under moving internal pressure is studied using the sandwich shell theory and elastodynamics theory. Propagation of axisymmetric free harmonic waves in the sandwich shell is studied using the sandwich shell theory by considering compressibility and transverse shear deformation of the core, and transverse shear deformation of face sheets. Based on the elastodynamics theory, displacement components expanded by Legendre polynomials, and position-dependent elastic constants and densities are introduced into the equations of motion. Critical velocity is the minimum phase velocity on the desperation relation curve obtained by using the two methods. Numerical examples and the finite element （FE） simulations are presented. The results show that the two critical velocities agree well with each other, and two desperation relation curves agree well with each other when the wave number k is relatively small. However, two limit phase velocities approach to the shear wave velocities of the face sheet and the core respectively when k limits to infinite. The two methods are efficient in the investigation of wave propagation in a sandwich cylindrical shell when k is relatively small. The critical velocity predicted in the FE simulations agrees with theoretical prediction.     

硫叶立德途径立体控制合成乙烯基型环氧化合物

在相转移条件下(CH3CN/KOH/RT)乙烯基型硫叶立德和醛反应高产率地得到以反式为主的产物,而在低温溴化锂存在下(LiBr/KHMDS/THF/-90℃)得到以顺式为主的产物,对于通过反应条件的变换而改变反应产物立体化学的机理,给出了一个初步的解释。     

基于吸收边界条件的有限元方法和离散切比雪夫展开的二维缺陷识别

结合考虑了吸收边界条件的有限元正演方法,通过离散切比雪夫多项式在特定离散点的展开逼近待识别函数,实现了无限区域内二维缺陷的识别。正问题计算中引入的吸收边界条件虽然不能严格地模拟无限域对近场波动的影响,但能够以满足实际需要的精度模拟这一影响,且具有解耦特性,极大地简化了数值计算,在反演计算中,离散点取在切比雪夫多项式的零点处,使逼近时最大偏差最小,数值算例表明此方法的有效性。     

线性极化方法测量混凝土中钢筋的腐蚀速度(英文)

本文尝试用线性极化的方法对埋置于混凝土内部的钢筋的腐蚀速度进行测量 .自行设计了一组特殊结构的辅助电极 ,制备了不同尺寸和保护层厚度的混凝土试样 .通过改变辅助电极 ,调整电位的分布 ,使线性极化方法的测量误差降低到腐蚀速度测量允许的误差范围内 .确定了两种适用于混凝土中钢筋腐蚀速度测量的辅助电极 .     

含锡AB_5型非化学计量贮氢合金Ⅰ.合金的结构

采用X射线衍射法研究了LaNi5 .1 5 ,La(NiSn) 5 .1 4 ,La(NiSnCo) 5 .1 2 ,La(NiSnMn) 5 .1 2 ,La(NiSnCoMnAl) 5 .1 0 5种AB5 型非化学计量贮氢合金的结构。发现主物相中并未产生第二物相 ,AB5 型贮氢合金中B原子数发生正偏移时 ,晶胞体积减小 ,当B侧含有取代元素时 ,这种变化更加明显。对于非化学计量贮氢合金而言 ,少量Sn取代Ni后 ,晶胞体积大大提高。Mn ,Co和Al的加入也会影响晶胞常数。Sn ,Co ,Mn ,Al均会降低贮氢合金放氢平台压力。     

Photoinduced electron transfer of [ Ru (bpy)_2 (4, 4'-dcbpy)]~(2 ) with electron donors

Emission quenching of [Ru(bpy)2(4, 4'-dcbpy)] (PF6)2 (1) by benzenamine,4-[2-[5-[4-[4-dimethylamino]phenyl]-4,5-di-hydro-1-phenyl-1H-pyrazol-3-yl]-ethenyl]-N,N-dimetyl (2) or 1, 5-diphenyl-3-(2-phenothiazine)-2-pyrazoline (3) was observed. Measurements of the emission decay of 1 before and after addition of 2 or 3 by single photon counting technique con-finned the observations. The emission quenching of 1 by 2 or 3 was submitted to Stern-Volmer equation. It was calculated that the quenching rate constants (kq) are 5.5 × 109(mol/L)-1s-1 for 2 and 4.0 × 109(mol/L)-1s-1 for 3, respectively. These results indicated a character of dynamic quenching process. The singlet-state of 2 or 3 was also quenched by 1. The quenching behaviors did not conform to the Stern- Volmer equation and involved both static and dynamic quenching processes. The apparent quenching rate constant (kapp) was calculated to be 3 × 109 (mol/L)-1 for the interaction of excited 2 with 1, and 1.2 × 109 (mol/L)-1 for that of excited 3 wit     

Fe掺杂与天然沸石载体对TiO2光催化活性的影响

以具有多孔结构的天然斜发沸石为载体, FeCl₃和TiCl₄为前驱物制备铁离子掺杂TiO₂光催化剂. 分别在紫外光和太阳光照射下, 研究了Fe-TiO₂, TiO₂/沸石和Fe-TiO₂/沸石对甲基橙溶液(MO)的光催化分解过程, 并通过XRD, AFM, FTIR和吸收光谱等手段, 探讨了Fe和沸石对TiO2的光催化活性的影响. 结果表明, 适当浓度的Fe不仅可以提高TiO₂的光催化效率, 而且能够拓展TiO₂的吸收波长范围至可见光区. 而沸石的引入不仅提高了光催化剂的效率, 而且也增强了光催化剂的抗失活性能.