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激光超声的原理及其在固体中的应用 总被引:5,自引:0,他引:5
激光超声是指脉冲激光所产生的脉冲超声。激光超声是较新的产生超声的方法。它的主要特色是,可以遥发遥收,这样就有可能在高温、有危险辐射等恶劣环境下以及在样品运动的生产线上进行超声检测。皮秒级和飞秒级的激光所激发的超声近来又用来研究固体中电子和声子的相互作用。文章介绍了固体中激光超声的声学性能及两种产生机理:热弹机理和电子机理。 相似文献
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活性炭富集示波极谱法测定水中痕量钒 总被引:4,自引:0,他引:4
本文研究了钒在活性炭上的吸附行为和解吸附条件,建立了pH3-4条件下吸附,氢氧化钠溶液洗脱,示波极谱法测定水中痕量钒的方法,本法富集倍数为100,对水样的最小检出浓度为0.05μg/L加标回收率为87.4%-100.3%,7份平行样品测定的相对标准偏差为3。5%-12.8%。 相似文献
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This paper proposes an all-optical label processing scheme that uses the multiple optical orthogonal codes sequences (MOOCS)-based optical label for optical packet switching (OPS) (MOOCS-OPS) networks. In this scheme, each MOOCS is a permutation or combination of the multiple optical orthogonal codes (MOOC) selected from the multiple-groups optical orthogonal codes (MGOOC). Following a comparison of different optical label processing (OLP) schemes, the principles of MOOCS-OPS network are given and analyzed. Firstly, theoretical analyses are used to prove that MOOCS is able to greatly enlarge the number of available optical labels when compared to the previous single optical orthogonal code (SOOC) for OPS (SOOC-OPS) network. Then, the key units of the MOOCS-based optical label packets, including optical packet generation, optical label erasing, optical label extraction and optical label rewriting etc., are given and studied. These results are used to verify that the proposed MOOCS-OPS scheme is feasible. 相似文献
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以2,2-二溴甲基-1,3-二溴丙烷(PEBr4)为引发剂,Cu0粉/三(2-二甲氨基乙基)胺(Me6-TREN)为催化体系,在二甲亚砜(DMSO)和H2O的混合溶剂中实现了苯乙烯(St)的单电子转移活性自由基聚合(SET-LRP)。 通过1H NMR和GPC分析表明,所得聚合物为星形结构并具有较窄的分子量分布Mw/Mn=1.20(MGPCn=25.3×103,转化率为42.6%),且聚合物的链端保留了-Br端基。 考察了溶剂、反应温度及相转移催化剂对聚合的影响,结果表明,混合溶剂中H2O的体积分数由10%增加至20%导致了聚合速率的降低,表观聚合速率常数(kappp)由0.026 4 h-1减小至0.019 7 h-1;升高反应温度、增加催化剂用量以及相转移催化剂的加入分别导致聚合体系的kappp增加,同时,催化剂用量的增加和相转移催化剂的加入使聚合物的分子量分布系数降低。 相似文献
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Zhimei Tian Na Zhang Chongfu Song Chang Wang 《International journal of quantum chemistry》2024,124(1):e27262
The interaction behavior of HCl and (ZnS)n (n = 1–12) clusters and HCl effect on Hg0 adsorbed by (ZnS)n have been studied theoretically. The combined genetic algorithm and density functional theory (GA-DFT) method has been used to obtain the structures of (ZnS)nHCl and (ZnS)nHgHCl (n = 1–12) clusters. The structural properties of (ZnS)nHCl and (ZnS)nHgHCl have been analyzed. The adsorption energies and interaction energies have been calculated. Bond length and bond order analysis has revealed that S H and Zn Cl bonds form after HCl adsorbed on (ZnS)n clusters, while Hg0 can only weakly bind with (ZnS)nHCl clusters. According to thermodynamic adsorption analysis, the formation of (ZnS)nHCl clusters from (ZnS)n and HCl are spontaneous because of their negative Gibbs free energy changes. The formation of (ZnS)nHgHCl from (ZnS)nHCl and Hg are nonspontaneous for n = 1–4 and 9, and the Gibbs free energy changes have small negative values for other sizes. Electron localization function and noncovalent interaction (NCI) analysis of (ZnS)10HgHCl manifest that Hg and its nearest Zn form zinc amalgam. Projected density of state study has been performed to obtain the interaction nature of HCl and (ZnS)n clusters and Hg0 adsorption on (ZnS)nHCl clusters. Based on our study, HCl is chemical adsorbed by (ZnS)n clusters except (ZnS)4 cluster. After (ZnS)n adsorbs HCl, Hg0 can physically adsorb on (ZnS)nHCl clusters. The strength of Hg0 on (ZnS)nHCl is comparable to that of Hg0 on (ZnS)n, indicating that HCl can hardly affect the adsorption of Hg0 on ZnS clusters. 相似文献
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对雷达系统,通过在接收前端安置高Q、窄带、高带外抑制的滤波器,可以有效减少信号间的干扰,由此可见高性能的滤波器对于雷达系统来说,具有重要作用.与常规滤波器相比,高温超导滤波器具有带边陡峭、插入损耗小、带外抑制高、可以设计极窄带等特点.在本文中,我们设计加工了一种高性能的12阶切比雪夫(Chebyshev)高温超导带通滤波器,其中心频率为1341兆赫兹、带宽为5.035兆赫兹,可用于雷达系统.在滤波器设计中,我们用Sonnet软件对滤波器进行了仿真计算.最后滤波器在以氧化镁为衬底的双面超导薄膜上制作,衬底直径为2英寸、厚度为0.5毫米.测试结果表明,该滤波器符合设计要求,具有很好的选择性和带外抑制. 相似文献