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681.
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Yasuo Gotoh Yoshitaka Nagara Tamaki Nakano Yoshio Okamoto Yutaka Ohkoshi Masanobu Nagura 《Journal of Polymer Science.Polymer Physics》2004,42(5):800-808
The viscoelastic behavior and molecular motion of highly syndiotactic poly(vinyl alcohol) (S‐PVA) fibers with a dyad syndiotacticity (r) of 69% were studied by dynamic mechanical thermal analysis and wide‐angle X‐ray diffraction and compared with those of atactic poly(vinyl alcohol) (A‐PVA) fibers with r = 54%. The βc dispersion, based on the molecular motion of the chain molecules in the crystalline regions, was observed for A‐PVA around 120–140 °C, and the only primary (αc) dispersion was observed for S‐PVA around 180 °C. The thermal expansion coefficients for the a and c axes of the A‐PVA crystal changed discontinuously around 120 °C, which corresponded to the βc dispersion. For S‐PVA, the coefficient for the (002) plane changed discontinuously around 100 °C, similarly to A‐PVA, but that for the (100) plane remained unchanged between 20 and 220 °C. These results showed that the intermolecular hydrogen bonding of S‐PVA was stronger in the direction of the a axis than in the other directions, suppressing the βc dispersion. The storage modulus and thermal expansion coefficient of the (020) plane (molecular axis) of S‐PVA decreased markedly around 180 °C, and this indicated that the αc dispersion was due to the torsional motion of the molecular chains in the crystalline regions. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 800–808, 2004 相似文献
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The optical reflectivity spectrum (2500–5000 Å) of extremely heavily phosphorus (P)-doped Si has been studied. The E1 and E2 peaks, which represent the completeness of the Si crystal, are slightly affected when doping concentrations are less than 1021 cm-3 (2% Si : P). However,they appreciably degrade as the doping concentration increases from 1021 to 5×1021cm-3 (10% Si : P). As the result of band calculations using a supercell configuration and pseudopotential method, we have been able to ascribe this behavior to the substitutional disorder effect. 相似文献
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TCNE photo-sensitized decompositions of oxasilacyclopropane (1) generated carbene and silanone, while the DCA sensitized or direct photolysis of (1) gave silylene and indanone. 相似文献
687.
Shuting Cai Kaori Nagatou Yoshitaka Watanabe 《Numerical Functional Analysis & Optimization》2013,34(10):1195-1220
We propose a numerical method to enclose a solution of the FitzHugh-Nagumo equation with Neumann boundary conditions. We construct, on a computer, a set which satisfies the hypothesis of Schauder's fixed point theorem for a compact map in a certain Sobolev space, which, therefore contains a solution. Several verified results are presented. 相似文献
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An efficient catalytic enantioselective fluorination of tert-butoxycarbonyl lactones and lactams is reported. Reactions of the lactone substrates proceeded smoothly in an alcoholic solvent with a catalytic amount of chiral Pd(II) complex. In the case of the less acidic lactam substrates, concurrent use of the Pd complex and 2,6-lutidine as a cocatalyst was effective. Under the reaction conditions, the fluorinated lactones and lactams were obtained in good yield with excellent enantioselectivity (94-99% ee). 相似文献
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