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The activity coefficients of NaBr in the NaBr–NaPropionate–H2O and NaBr–NaButyrate–H2O systems were determined from EMF measurements at constant total ionic strength of 0.1 0.5 1.0 1.5 2.0 and 2.5 mol-kg–1 and at 25° C. The activity coefficients were fitted using Scatchard, Pitzer and Lim equations. Finally the excess Gibbs free energy of these mixtures were also calculated. 相似文献
44.
The Hawking radiation of Dirac particles in an arbitrarily rectilinearly accelerating Kinnersley black hole with electromagnetic charge and cosmological constant is investigated by using the generalized tortoise coordinate transformation. Both the location and the temperature of the event horizon depend on the time and the polar angle. The Hawking thermal radiation spectrum of Dirac particles is also derived. 相似文献
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Cai Kairen 《数学年刊B辑(英文版)》1991,12(3):267-271
The author gives an optimum estimate of the first eigenvalue of a compact Riemannian manifold. It is shown that let M be a compact Riemannian manifold, then the first eigenvalue λ_1 of the Laplace operator of M satisfies α_1+max{0,-(n-1)K}≥π~2/d~2 where d is the diameter of M and (n-1)K is the negative lower bound of the Ricci curvature of M. 相似文献
47.
Zi‐Cai Li Tzon‐Tzer Lu Hung‐Tsai Huang Alexander H.‐D. Cheng 《Numerical Methods for Partial Differential Equations》2007,23(1):93-144
In this article we survey the Trefftz method (TM), the collocation method (CM), and the collocation Trefftz method (CTM). We also review the coupling techniques for the interzonal conditions, which include the indirect Trefftz method, the original Trefftz method, the penalty plus hybrid Trefftz method, and the direct Trefftz method. Other boundary methods are also briefly described. Key issues in these algorithms, including the error analysis, are addressed. New numerical results are reported. Comparisons among TMs and other numerical methods are made. It is concluded that the CTM is the simplest algorithm and provides the most accurate solution with the best numerical stability. © 2006 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2007 相似文献
48.
热等离子体裂解天然气制备C2烃 总被引:1,自引:0,他引:1
采用氮气热等离子体来裂解天然气制备乙炔乙烯,着重研究了天然气转化率和乙炔、乙烯收率随氮气流量和天然气流量的变化.结果表明,天然气流量与氮气流量之比为11时,可得到较好的结果.当等离子体功率为15kW、天然气流量为3Nm3*h-1、氮气流量为3Nm3*h-1时得到最好的结果.这时天然气转化率为57%,乙炔、乙烯的收率分别为34%和9%;乙炔在反应气中的体积浓度为7.5%,与部分氧化法相似;扣除不参加反应的氮气,乙炔在气相产品中的体积浓度为13.2%,与热力学平衡计算结果基本符合. 相似文献
49.
The following results are proved in this paper. Let G be a 2k-edge-connected eulerian graph. (i) For every set {e1, e2, ?, e2k+1} ? E(G) there is an eulerian trail T of the form e1, e2, ?, e2k+1, ?. (ii) For every set E* = {e1, e2, ?, ek} ? E(G) there is an eulerian trail T = e1, ?, e2, ?, ek, ? in which the elements of E* are traversed in accordance with a prescribed orientation. © 1995 John Wiley & Sons, Inc. 相似文献
50.
Zhengqian Luo Guoyong Sun Zhiping Cai Miaoling Si Qibo Li 《Optics Communications》2007,277(1):118-124
In this paper, continuous wave Yb3+-doped double-clad fiber lasers (DCFLs) with linear-cavity are investigated theoretically and numerically using the rate equations. Under the steady state conditions, the simplified analytic solutions of Yb3+-doped DCFLs under considering the scattering loss are deduced in the strongly pump condition. Compared with the known analytic solutions in published literatures, our analytic solutions are more accurate, especially, at higher reflectivity of output mirror. In addition, a fast and stable algorithm based on the Newton-Raphson method is proposed to simulate numerically Yb3+-doped DCFLs. The results by simplified analytic solutions are in good agreement with those by the numerical simulation. Moreover, we have performed the optimization of an Yb3+-doped DCFL using the simplified analytic solutions and the numerical simulations, respectively. 相似文献