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991.
In this paper the solution conformation of the response regulator proteins from Deinococcus radiodurans was studied by small-angle X-ray scattering (SAXS). The SAXS curves of Dr-rrA in solutions were obtained at Beamline 1W2A of Beijing Synchrotron Radiation Facility (BSRF). Two possible conformations of the response regulator proteins, compact and incompact conformations, have been represented by the known crystallographic structures. And theoretical solution scattering curves of the two possible conformations were calculated and fitted to the experimental scattering curve of Dr-rrA, respectively. The result indicates that the solution conformation of the response regulator proteins is inclined to the compact one, which is in agreement with the result of biochemical experiments. 相似文献
992.
李广顺 周小红 张玉虎 周厚兵 滑伟 王世陶 丁兵 王海霞 Oshima M Toh Y Koizumi M Osa A Hatsukawa Y Sugawara M 《中国物理 C》2011,35(5):441-444
High-spin states in 185Pt have been reinvestigated via the reaction 173Yb(16O, 4n) at a beam energy of 90 MeV. The previously known band based on the ν7/2-[503](f7/2) Nilsson orbital has been extended to higher spin states. Properties of the ν7/2-[503](f7/2) band have been discussed with an emphasis on the evolution of configuration while increasing the spin. 相似文献
993.
994.
995.
A novel flavanol bearing phenylpropionic acid moiety at C-4 through a C-C bonding,named brainin A(1),was isolated from the rhizomes of Brainea insignis.Its structure was elucidated on the basis of spectral data including 2D NMR and HR-ESI-MS. 相似文献
996.
A novel,simple,rapid,efficient and environment-friendly method for the determination of trace copper in cereal samples was developed by using dispersive liquid-liquid microextraction based on solidification of floating organic drop(DLLME-SFO) followed by flame atomic absorption spectrometry.In the DLLME-SFO,copper was complexed with 8-hydroxy quinoline and extracted into a small volume of 1-dodecanol,which is of low density,low toxicity and proper melting point near room temperature. The experimental parameters affecting the extraction efficiency were investigated and optimized.Under the optimum conditions, the calibration graph exhibited linearity over the range of 0.5—500 ng/mL with the correlation coefficient(r) of 0.9996.The enrichment factor was 122 and the limit of detection was 0.1 ng/mL.The method was applied to the determination of copper in the complex matrix samples such as rice and millet with the recoveries for the spiked samples at 5.0 and 10.0 u,g/g falling in the range of 92.0-98.0%and the relative standard deviation of 3.9-5.7%. 相似文献
997.
(3S,4R)-Bengamide E(2) was synthesized starting from D-glucono-δ-lactone(3) and the key deoxygenation step from 13 to 15 was achieved by the application of NaBH3CN and ZnI2.Compared with natural bengamide E(1),the synthetic compound(35,4R)-bengamide E(2) was inactive against the cell growth of HUVEC and cancer cells.These data represent the significance of the stereochemistry at C-3 and C-4 of bengamides for structural recognition and binding with the target(s). 相似文献
998.
Two new phenethanol glycosides,named ligurobustoside P(1),ligurobustoside Q(2) have been isolated from the leaves of Ligustrum robustum,together with the known compound angoroside A(3) which was firstly isolated from this species.The structures of the two new phenethanol glycosides(1-2) were elucidated by a combination of high-resolution electron ionization mass spectrometry(HR-ESI-MS),1H NMR,13C NMR,HMQC,and HMBC spectra for the first time. 相似文献
999.
Interaction between Janus Green B and bovine serum albumin:Electrochemistry and spectroscopy studies
In this study,voltammetric and spectroscopic investigation of the interaction between Janus Green B(JGB) and bovine serum albumin(BSA) was reported.The interaction was observed at Britton-Robinson buffer(pH 7.0).When JGB was added to solution containing BSA,the peak currents of BSA decrease with the increasing of JGB concentrations which is due to the interaction of JGB and BSA.The binding constant of JGB with BSA was obtained by voltammetric data.Also,this interaction was supported by means of UV-vis spectroscopic measurements.The UV-vis absorption spectra of JGB in the presence of BSA decrease with the increasing of BSA concentrations. 相似文献
1000.
Xiu Li Yue Fang Ma Zhi Fei Dai Meng Liu Lei Xing Hai Yan Fan Zhan Wen Xing Shao Qin Liu 《中国化学快报》2011,22(2):241-244
Amphiphilic terpolymer(TPR) exhibits good film-forming behavior on pure water observed by means ofπ-A isotherms.To gain insight into physical properties of TPR,the films have been deposited on silicon substrates at different surface pressure by Langmuir-Blodgett(LB) technique.It was found that the increase in peak intensities of stretching mode was due to orderly packing of the films.The contact angles increased with increasing surface pressure,indicating an increase in hydrophobicity due to dense packing of chains of TPR.The cyclic voltammetric measurements indicated that TPR showed good current shielding effect for electron-transfer.In a word,LB films of TPR can produce a variety of structures with varied topography,enabling us to control not only the functionality of the surface,but also the interfacial transport characteristics. 相似文献