全文获取类型
收费全文 | 4755篇 |
免费 | 652篇 |
国内免费 | 465篇 |
专业分类
化学 | 3497篇 |
晶体学 | 52篇 |
力学 | 257篇 |
综合类 | 44篇 |
数学 | 553篇 |
物理学 | 1469篇 |
出版年
2024年 | 5篇 |
2023年 | 106篇 |
2022年 | 102篇 |
2021年 | 178篇 |
2020年 | 174篇 |
2019年 | 154篇 |
2018年 | 146篇 |
2017年 | 110篇 |
2016年 | 201篇 |
2015年 | 201篇 |
2014年 | 244篇 |
2013年 | 285篇 |
2012年 | 374篇 |
2011年 | 425篇 |
2010年 | 255篇 |
2009年 | 249篇 |
2008年 | 298篇 |
2007年 | 273篇 |
2006年 | 270篇 |
2005年 | 210篇 |
2004年 | 181篇 |
2003年 | 166篇 |
2002年 | 135篇 |
2001年 | 113篇 |
2000年 | 100篇 |
1999年 | 128篇 |
1998年 | 113篇 |
1997年 | 102篇 |
1996年 | 110篇 |
1995年 | 97篇 |
1994年 | 60篇 |
1993年 | 42篇 |
1992年 | 41篇 |
1991年 | 36篇 |
1990年 | 32篇 |
1989年 | 26篇 |
1988年 | 23篇 |
1987年 | 21篇 |
1986年 | 14篇 |
1985年 | 10篇 |
1984年 | 15篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 9篇 |
1976年 | 7篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1972年 | 2篇 |
1971年 | 2篇 |
排序方式: 共有5872条查询结果,搜索用时 15 毫秒
991.
Yang Li K.W. Wong XiaoFeng Liao ChuanDong Li 《Nonlinear Analysis: Real World Applications》2009,10(3):1712-1716
The issue of impulsive control theory for the synchronization of the nuclear spin generator (NSG) chaotic systems is developed. We propose an impulsive control scheme for the complete synchronization of the NSG system including chaotic systems. A sufficient condition for the impulsive control is derived, with an easily calculated maximum impulsive interval. The proposed impulsive control scheme is applied to the NSG system and the simulation result demonstrates the effectiveness of the method. 相似文献
992.
This paper investigates the existence and uniqueness of positive solutions for a class of nonlinear fractional delay differential
equations. Using a nonlinear alternative of Leray-Schauder type, we show the existence of positive solutions for the equations
in question. 相似文献
993.
Shijun Zheng 《分析论及其应用》2009,25(1):79-85
We prove a complex and a real interpolation theorems on Besov spaces and Triebel-Lizorkin spaces associated with a selfadjoint operator L, without assuming the gradient estimate for its spectral kernel. The result applies to the cases where L is a uniformly elliptic operator or a Schrdinger operator with electro-magnetic potential. 相似文献
994.
High performance PtRuIr catalysts supported on carbon nanotubes for the anodic oxidation of methanol 总被引:1,自引:0,他引:1
Liao S Holmes KA Tsaprailis H Birss VI 《Journal of the American Chemical Society》2006,128(11):3504-3505
We report the formation of a new PtRuIr catalyst using an organic colloid synthesis method, involving acetone as the solvent, ethylene glycol as the reducing agent, citrate as a complexing agent and stabilizer, and multiwall carbon nanotubes (CNT, diameter 8-10 nm) as the support. This catalyst has a very high real surface area and is highly active toward the oxidation of methanol, relevant to fuel cell applications. The Ir component appears to act as a promoter, and the splitting of the Pt(111) XRD feature into four peaks and the shift to larger d spacing reflect the high dispersion of the metallic components. 相似文献
995.
We report for the first time hydrothermal synthesis of lanthanide-pyzcH polymers, [Ln2(C2O4)2(pyzc)2 (H2O)2]n [Ln = Pr (1), Er (2)], in which pyzcH was decomposed into C2O42- and thus caused novel two-dimensional hexagonal lattice networks. The magnetic property of polymer 1 has been studied by an approximate treatment being enlightened by McPherson et al. (Inorg. Chim. Acta 1988, 148, 265), leading to Delta = -4.3 cm-1, zJ' = -11.73 cm-1, and g = 0.79. Complex 2 displays an intense room-temperature, liquid-state luminescent emission. 相似文献
996.
Zhang R Li B Iovu MC Jeffries-El M Sauvé G Cooper J Jia S Tristram-Nagle S Smilgies DM Lambeth DN McCullough RD Kowalewski T 《Journal of the American Chemical Society》2006,128(11):3480-3481
Low polydispersity regioregular polythiophenes with number average molecular weights ranging from 2 to 13 kDa were cast under the same conditions from solution to form a series of field effect transistors (FETs). Tapping mode AFM and grazing incidence small-angle X-ray scattering revealed that in all cases the polymers formed regular nanofibrillar morphologies with the width of nanofibrils proportional to the weight average contour length of polymer chains, indicating that conjugated backbones were oriented perpendicular to the nanofibril axes. FET charge carrier mobilities exhibited exponential dependence on nanofibril width, pointing to the decisive role of extended conjugated pathways in charge transport. 相似文献
997.
Waterborne polyurethane (WPU) was synthesized and followed by adding colloidal silica to prepare WPU-silica hybrids. The silica content in the hybrid thin films was varied from 0 to 50 wt%. The experimental results revealed that the viscosity of these hybrid solutions increased with increasing silica content and resulted in the aggregation of silica particle in the hybrid films. The latter result was evidenced by SEM examination. The effect of interaction between silica particle and urethane polymer chains is more significant with increasing silica content. The prepared hybrid films show much better thermal stability and mechanical properties than pure WPU. The optical transparence did not linearly decrease with increasing the silica fraction in the hybrid thin film. At below 20% silica content, the film transparence decreased with increasing silica content; the converse is true at above 20% silica content. These results showed that the prepared hybrid films demonstrated tunable transparence with the silica fraction in the films. 相似文献
998.
Manimaran B Lai LJ Thanasekaran P Wu JY Liao RT Tseng TW Liu YH Lee GH Peng SM Lu KL 《Inorganic chemistry》2006,45(20):8070-8077
Alkoxy- and thiolato-bridged Re(I) molecular rectangles [{(CO)3Re(mu-ER)2Re(CO)3}2(mu-bpy)2] (ER = SC4H9, 1a; SC8H17, 1b; OC4H9, 2a; OC12H25, 2b; bpy = 4,4'-bipyridine) exhibit strong interactions with several planar aromatic molecules. The nature of their binding was studied by spectral techniques and verified by X-ray diffraction analysis. Standard absorption and fluorescence titrations showed that a relatively strong 1:1 interaction occurs between aromatic guests such as pyrene and these rectangles. The results of a single-crystal X-ray diffraction analysis show that the recognition of 1 with a pyrene molecule is mainly due to CH...pi interactions and the face of the guest pyrene is located over the edges of the bpy linkers of 1. This is a fairly novel example of an interaction that is rarely designed into a host-guest pair. Furthermore, the interaction of 1 with Ag+ results in the self-organization of supramolecular arrays, as revealed by solid-state data. 相似文献
999.
Single crystals of two new cobaltites, Ba2Co9O14 and Ba3Co10O17, were obtained from the flux of K2CO3 in the temperature range 800-890 degrees C. They crystallize in an intergrowth structure containing perovskite block and CdI2-type layers and can be attributed to the n = 1 and 2 members in a new intergrowth series of cobaltites, Ba(n+1)Co(n)O(3n+3)(Co8O8). Both Ba2Co9O14 and Ba3Co10O17 are metastable and transform into the known 2H-perovskite-related oxides at high temperature. 相似文献
1000.
A simple method for separation of different anionic and zwitterionic phospholipid classes by capillary zone electrophoresis (CZE), using indirect UV detection with adenosine monophosphate (AMP) as background electrolyte and the UV-absorbing additive, was successfully developed in this study. The separation conditions including apparent pH (pH*) of running buffer, concentration of AMP, organic solvent, applied voltage and capillary temperature were systematically optimized. The application of this method to human blood sample was also briefly examined. 相似文献