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121.
To identify and eliminate the inner filter effects (IFEs), prepositive and side cells containing absorbents are fixed beside
the fluorescer contained cell. In this way, excitation and emission lights can be quenched by primary and secondary outer
filter effects respectively, depending on absorbent concentration and cell length. Herein the quenching of emission fluorescence
caused by IFEs can be equally reduced by outer filter effects (OFEs) and the interference of IFEs was eliminated. This approach
was experimentally used for identifying the interaction mode and mechanism between BSA and nanoAg. Results showed that the
quenching of BSA fluorescence and synchronous fluorescence mainly attributes to IFEs, instead of static/dynamic fluorescent
quenching. In view of the above, the elimination of the interference of IFEs by the design of OFEs plays an important part
in the precise application of fluorescence detector. 相似文献
122.
123.
Effects of doping on the surface energies of nanocrystals and evidence from studies at high pressure
Zn1−XMnXS (X=0.85% and 1.26%) nanoparticles have been synthesized using a specially designed equipment and we have studied the influence of doping Mn2+ on the surface energy of ZnS. The high pressure behaviors of ZnS nanocrystals with different dopant contents have been investigated using angle-dispersive synchrotron X-ray powder diffraction up to 45.1 GPa. Theoretical calculations show that doping with Mn2+ increases the surface energy of the nanocrystals. The theoretical result has been further corroborated by our experimental observation of an increase in the phase transition pressure of Mn2+ doped ZnS nanocrystals in diamond-anvil-cell studies. 相似文献
124.
A high-power 880-nm diode-directly-pumped passively mode-locked 1342 nm Nd:YVO? laser was demonstrated with a semiconductor saturable absorber mirror (SESAM). The laser mode radii in the laser crystal and on the SESAM were optimized carefully using the ABCD matrix formalism. An average output power of 2.3 W was obtained with a repetition rate of 76 MHz and a pulse width of 29.2 ps under an absorbed pump power of 12.1 W, corresponding to an optical-optical efficiency of 19.0% and a slope efficiency of 23.9%, respectively. 相似文献
125.
Conjugatedpolymerswithlargethird-orderopticalnonlinearityhavebeedfocusedfortheirpromisingpotentialsforadvancedmaterialsapplications'.Recently,investigationsoftransitionmetalwithorganicligandsystemshavebeengreatlyintensifiedduetothedelectronsincorporatedintheconjugatedsystem,whichareexpectedtoellhancethehyperpolarizability.Phenylacetyleneandthemetalphenylacetylidesplayimportantrolesinformationofuniquecoordinatedc-lusters',butitseamsthatthestudyofmetalphenylacetylides,particularlyofthesilverphen… 相似文献
126.
Some properties of solutions for the difference Riccati equations are obtained. The existence and forms of rational solutions,
and the Borel exceptional value, zeros, poles and fixed points of transcendental solutions are researched. 相似文献
127.
磁约束等离子体中杂质(特别是高Z杂质)的存在将大大增强等离子体辐射功率损失,破坏等离子体的约束性能。杂质行为的定量研究首先要求对杂质测量的光谱诊断系统进行绝对强度标定,获得灵敏度响应曲线。介绍了EAST托卡马克上的快速极紫外光谱仪系统绝对强度的原位标定方法。在波长范围20~150Å内,通过对比极紫外(EUV)波段连续轫致辐射强度的计算值和测量值得到光谱仪的绝对强度标定。在此过程中,首先由(523±1) nm范围内可见连续轫致辐射强度的绝对测量值计算出有效电荷数Zeff,进而结合电子温度和密度分布计算EUV波段连续轫致辐射强度;EUV波段连续轫致辐射强度的测量值即为不同波长处探测器的连续本底计数扣除背景噪声计数值。对于较长波段范围130~280Å,通过对比等离子体中类锂杂质离子(Fe23+,Cr21+,Ar15+)和类钠杂质离子(Mo31+,Fe15+)发出的共振谱线对(跃迁分别为1s22s 2S1/2-1s22p 2P1/2, 3/2及2p63s 2S1/2-2p63p 2P1/2, 3/2)强度比的理论和实验值进行相对强度标定。其中共振谱线对强度比的理论值由辐射碰撞模型计算得到,模型中处在各个能级的离子数主要由电子碰撞激发,去激发以及辐射衰变三个过程决定。两种方法相结合,实现了光谱仪20~280Å范围的绝对强度标定。考虑轫致辐射、电子温度及电子密度的测量误差,绝对标定误差约为30%。在绝对标定的基础上,我们对杂质特征谱线强度进行绝对测量,并将测量结果与杂质输运程序结合ADAS(Atomic Data and Analysis Structure)原子数据库计算得到的模拟值进行比较,进而估算等离子体中的杂质浓度。 相似文献
128.
Zong Xin PI Hou Wen XIN* Department of Chemical Physics University of Science Technology of China Hefei 《中国化学快报》2001,(3)
IntroductionStochastic resonance (SR) is a nonlinear effect which describes the optimal detection of a weak periodic signal by the action of external noise in nonlinear systems. SR was originally proposed to account for periodicity in the Earth's ice ages1, and it has been observed in a wide range of biological2-4 , physical5 and chemical6 systems. The systems mentioned above which may give rise to SR have a denominator despite many examples of SR in different scientific areas. It is noted… 相似文献
129.
Li‐Ying Li Wei‐Dong He Wen‐Tao Li Ke‐Ren Zhang Ting‐Ting Pan Zong‐Lei Ding Bo‐Yu Zhang 《Journal of polymer science. Part A, Polymer chemistry》2010,48(22):5018-5029
Well‐defined H‐shaped pentablock copolymers composed of poly(N‐isopropylacrylamide) (PNIPAM), poly(N,N‐dimethylaminoethylacrylamide) (PDMAEMA), and poly(ethylene glycol) (PEG) with the chain architecture of (A/B)‐b‐C‐b‐(A/B) were synthesized by the combination of single‐electron‐transfer living radical polymerization, atom‐transfer radical polymerization, and click chemistry. Single‐electron‐transfer living radical polymerization of NIPAM using α,ω azide‐capped PEG macroinitiator resulted in PNIPAM‐b‐PEG‐b‐PNIPAM with azide groups at the block joints. Atom‐transfer radical polymerization of DMAEMA initiated by propargyl 2‐chloropropionate gave out α‐capped alkyne‐PDMAEMA. The H‐shaped copolymers were finally obtained by the click reaction between PNIPAM‐b‐PEG‐b‐PNIPAM and alkyne‐PDMAEMA. These copolymers were used to prepare stable colloidal gold nanoparticles (GNPs) in aqueous solution without any external reducing agent. The formation of GNPs was affected by the length of PDMAEMA block, the feed ratio of the copolymer to HAuCl4, and the pH value. The surface plasmon absorbance of these obtained GNPs also exhibited pH and thermal dependence because of the existence of PNIAPM and PDAMEMA blocks. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
130.
强奇异卷积算子交换子的Hardy型空间估计 总被引:2,自引:0,他引:2
本文给出了强奇异卷积算子交换子[6,T]在Hardy型空间中的估计,其中 b∈BMO(Rn)且一致连续, T为强奇异卷积算子. 相似文献