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981.
Shaikh A. Ali N. Y. Abu‐Thabit Hasan A. Al‐Muallem 《Journal of polymer science. Part A, Polymer chemistry》2010,48(24):5693-5703
The zwitterionic monomer, ethyl 3‐(N,N‐diallylammonio)propanephosphonate, was cyclopolymerized in aqueous solutions using t‐butylhydroperoxide or ammonium persulfate as initiators to afford a polyphosphonobetaine (PPB). The protonation of P(?O)OEtO– and deprotonation of ? NH+ groups in PPB by HCl and NaOH, gave the corresponding cationic polyphosphononic acid (CPP) and anionic polyphosphonate (APP). The presence of two pH‐responsive functionalities in APP has led to establish the equilibria: APP ? PPB ? CPP, the position of which very much dictates the viscosity behavior of its aqueous solution. The PPB demonstrated “antipolyelectrolyte” viscosity behavior; however, in contrast to many polycarbo‐ and polysulfo‐betaines, it was found to be soluble in salt‐free water as well as in salt‐added solutions. Basicity constant (K1) of the amine group in APP, as determined by potentiometric technique, were found to be “apparent,” and as such followed the modified Henderson‐Hasselbalch equation. The study demonstrated a correlation between the basicity constants and viscosity values. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
982.
983.
We investigate theoretically thenonlinear normal modes of a vertical cantilever beam excited by aprincipal parametric resonance. We apply directly the method ofmultiple scales to the governing nonlinear nonautonomousintegral-partial-differential equation and associated boundary conditions.In the absence of damping, it is shown that the system has nonlinear normal modes, as defined by Rosenberg, even in the presence of the parametric excitation.We calculate the spatial correction to the linear mode shapedue to the effects of the inertia and curvature nonlinearities andthe parametric excitation. We compare the result obtained withthe direct approach with that obtained using a single-mode Galerkindiscretization.The deviation between the two predictions increases as the oscillationamplitude increases. 相似文献
984.
The mechanism of peristaltic magnetohydrodynamic (MHD) flow based on slip and heat transfer effects is studied in an asymmetric channel. An incompressible viscous fluid fills the porous space inside the channel. Long wavelength and zero Reynolds number approximation are used in the flow modeling. Expressions of stream function, longitudinal pressure gradient, and temperature are developed. Various interesting phenomena associated with peristalsis, such as pumping and trapping, are discussed in detail. Further the effects of various pertinent parameters on temperature field and heat transfer coefficient are explained with the help of graphs and tables. It is found that pressure rise over one wavelength decreases in pumping region for large values of slip parameter. Similar behavior is observed for temperature field by increasing the slip parameter. However, the volume of trapped bolus decreases by increasing the slip parameter. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
985.
Binary 3-point scheme, developed by Hormann and Sabin [Hormann, K. and Sabin, Malcolm A., 2008, A family of subdivision schemes with cubic precision, Computer Aided Geometric Design, 25, 41-52], has been modified by introducing a tension parameter which generates a family of C1 limiting curves for certain range of tension parameter. Ternary 3-point scheme, introduced by Siddiqi and Rehan [Siddiqi, Shahid S. and Rehan, K., 2009, A ternary three point scheme for curve designing, International Journal of Computer Mathematics, In Press, DOI: 10.1080/00207160802428220], has also been modified by introducing a tension parameter which generates family of C1 and C2 limiting curves for certain range of tension parameter. Laurent polynomial method is used to investigate the continuity of the subdivision schemes. The performance of modified schemes has been demonstrated by considering different examples along with its comparison with the established subdivision schemes. 相似文献
986.
The penetration of ampicillin molecule into the β-cyclodextrin cavity in aqueous solution is studied by 1 H NMR, 2D COSY and ROESY spectroscopy. Obtained data suggest that the phenyl moiety of ampicillin is included inside the
hydrophobic cavity of β-cyclodextrin molecule in the solution, and the mode and depth of this inclusion is confirmed on the
basis of 2D ROESY spectral data. 相似文献
987.
Dumitru Baleanu Alireza K. Golmankhaneh Ali K. Golmankhaneh 《International Journal of Theoretical Physics》2009,48(4):1044-1052
The fractional generalization of Nambu mechanics is constructed by using the differential forms and exterior derivatives of
fractional orders. The generalized Pfaffian equations are obtained and one example is investigated in details.
On leave of absence from Institute of Space Sciences, P.O. Box, MG-23, 76900, Magurele-Bucharest, Romania. 相似文献
988.
The potential between two12C nuclei in linear chain configuration has been calculated microscopically using the Ali-Bodmerα-α potential. This potential shows a pocket and compares well in the tail region with the phenomenological potential extracted
before, from the data on the quasi-molecular resonances of the12C +12C system. This provides support to the diatomic like rotation-vibration picture of quasi-molecular states. 相似文献
989.
Alkyl halides are efficiently converted to their corresponding nitroalkanes under mild and nonaqueous conditions by using polymer supported nitrites. The polymeric reagent is regenerable. 相似文献
990.
Optical shadow-casting (OSC) technique has shown excellent potential for optically implementing two-operand parallel logic gates and array logic operations. The 16 logic functions for two binary patterns (variables) are optically realizable in parallel by properly configuring an array of 2×2 light emitting diodes. In this paper, we propose an enhanced OSC technique for implementing four-operand parallel logic gates. The proposed system is capable of performing 216 logic functions by simply programming the switching mode of an array of 4×4 light emitting diodes in the input plane. This leads to an efficient and compact realization scheme when compared to the conventional two-operand OSC system. 相似文献