全文获取类型
收费全文 | 1588篇 |
免费 | 102篇 |
国内免费 | 29篇 |
专业分类
化学 | 1148篇 |
晶体学 | 13篇 |
力学 | 74篇 |
数学 | 205篇 |
物理学 | 279篇 |
出版年
2024年 | 4篇 |
2023年 | 18篇 |
2022年 | 36篇 |
2021年 | 73篇 |
2020年 | 62篇 |
2019年 | 89篇 |
2018年 | 80篇 |
2017年 | 78篇 |
2016年 | 121篇 |
2015年 | 74篇 |
2014年 | 93篇 |
2013年 | 193篇 |
2012年 | 106篇 |
2011年 | 118篇 |
2010年 | 83篇 |
2009年 | 65篇 |
2008年 | 56篇 |
2007年 | 47篇 |
2006年 | 33篇 |
2005年 | 25篇 |
2004年 | 31篇 |
2003年 | 23篇 |
2002年 | 28篇 |
2001年 | 15篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 6篇 |
1997年 | 9篇 |
1996年 | 10篇 |
1995年 | 7篇 |
1994年 | 11篇 |
1992年 | 6篇 |
1991年 | 6篇 |
1990年 | 7篇 |
1989年 | 10篇 |
1988年 | 8篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 10篇 |
1984年 | 4篇 |
1983年 | 14篇 |
1982年 | 6篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1973年 | 3篇 |
1956年 | 2篇 |
排序方式: 共有1719条查询结果,搜索用时 312 毫秒
81.
Kamyabi Mohammad Ali Moharramnezhad Mohsen Hajari Nasim 《Journal of Solid State Electrochemistry》2022,26(5):1259-1270
Journal of Solid State Electrochemistry - In this study, a novel electrochemical luminescence based on ternary nanocomposite as CuS/CQDs/g-C3N4NS was demonstrated for accurate determination of... 相似文献
82.
Zeinab Noroozi Tisseh Minoo Dabiri Mohsen Nobahar Hamid Reza Khavasi Ayoob Bazgir 《Tetrahedron》2012,68(6):1769-1773
An approach for the synthesis of new 5-substituted-tetrazoles via multi-component domino Knoevenagel condensation/1,3 dipolar cycloaddition reaction of carbonyl compounds, malononitrile and sodium azide in water without assistance of any catalyst has been reported. This general protocol provides a wide variety of 5-substituted 1H-tetrazoles in good yields under mild reaction conditions. 相似文献
83.
84.
Issa Yavari Mansoureh Aghazadeh Mohsen Tafazzoli 《Phosphorus, sulfur, and silicon and the related elements》2013,188(5):1101-1107
Ethyl 2-arylamino-2-oxo-acetates undergo a complex reaction with dimethyl acetylenedicarboxylate in the presence of triphenylphosphine to produce dimethyl 1-aryl-4-ethoxy-5-oxo-4,5-dihydro-1 H -pyrrole-2,3-dicarboxylates in good yields. Dynamic NMR study of dimethyl 1-(2-methylphenyl)-4-ethoxy-5-oxo-4,5-dihydro-1 H -pyrrole-2,3-dicarboxylate shows a fairly high energy barrier ( j G p = 53.2 kJmol m 1 ) for rotation around the N-aryl single bond, which leads to an observable atropisomerism. 相似文献
85.
Alireza Hasaninejad Khodabakhsh Niknam Abdolkarim Zare Ehsan Farsimadan Mohsen Shekouhy 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):147-155
Silphox [POCl3-n(SiO2)n] efficiently catalyzes the condensation of benzene-1,2-diamine with mono and dicarboxylic acids under microwave irradiation to afford benzimidazole derivatives in high yields and short reaction times. 相似文献
86.
Nasser M. Hosny Farid I. El-Dossoki Mohsen M. Mostafa 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2):402-410
New metal complexes derived from the reaction of N-[(phenylamino)thioxomethyl] hydrazino carbonyl methyl pyridinium chloride (H2L; PTHMPC) with some metal salts of the general formula MX2 [(X = Cl? and/or CH3COO?; M = Cd(II), UO2(II), Mn(II) and Zr(IV)] were synthesized and characterized by elemental analyses, spectral analyses (IR, UV-vis., 1H NMR), thermal analyses (TGA, DTG), and conductance and magnetic measurements. The results showed that the ligand exists in metal complexes either in the keto form or in the enol form. Moreover, the IR spectral data suggest that the acetate ion behaves in a monodentate manner. Semi-empirical calculations ZINDO/1, PM3, and AM1 have been used to study the molecular geometry and the harmonic vibrational spectra of the ligand and its metal complexes with the purpose of assisting the experimental assignment of the complexes. Generally, there is an agreement between the observed and the calculated spectra. Finally, the thermodynamic parameters (ΔE*, ΔH, ΔG, and ΔS) have been calculated from the data of thermal analyses (TGA and DTG). Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. 相似文献
87.
Five new optically active aromatic poly(amide-imide)s (PAIs) 5a–e were prepared from a direct polycondensation reaction of a new diacid of N,N′-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetra carboxylic)-bis-L-isoleucine 3 with various aromatic diamines 4a–e in a medium consisting of triphenyl phosphite (TPP), calcium chloride (CaCl2), pyridine (Py) and N-methyl-2-pyrrolidone (NMP). The polycondensation reaction produced a series of novel poly(amid-imide)s 5a–e in quantitative yields with inherent viscosities of 0.39–0.51 dL/g. The resulting polymers were fully characterized by means of 1H-NMR, FT-IR spectroscopy, elemental analyses, inherent viscosity, solubility test, specific rotation and thermal properties of them were investigated using TGA/DTG and differential scanning calorimeter (DSC). The diacid 4 was synthesized by the condensation reaction of bicyclo[2,2,2]oct-7-ene-2,3,5,6- tetracarboxylic dianhydride 1 with L-isoleucine 2 in acetic acid solution. 相似文献
88.
Sayed Yahya Kazemi 《Journal of the Iranian Chemical Society》2013,10(5):915-920
The present work deals with the first attempt to study the effect of l-tyrosine on the characteristics of the peroxyoxalate chemiluminescence. Berberine was applied as an efficient fluorophore. The investigated parameters include rise and fall rate constant for the chemiluminescence burst, theoretical and experimental maximum intensity, the time needed to reach maximum intensity and the total light yield emission, which is theoretically evaluated using the pooled intermediate model by a computerized non-linear least-squares curve fitting program (KINFIT). Furthermore, based on the observed quenching effect of tyrosine, the Stern–Volmer plot with K Q value of 7.7 × 104 M?1 in the quencher concentration range 4 × 10?6–5 × 10?5 M. Moreover, this method is applied to determinate tyrosine in biological samples successfully. 相似文献
89.
Mohammad Ali Karimi Rasul Shahin Sayed Zia Mohammadi Abdolhamid Hatefi‐Mehrjardi Javad Hashemi Javad Yarahmadi 《中国化学会会志》2013,60(11):1339-1346
A new solid phase extraction (SPE) method has been developed for the speciation of Cr(III) and Cr(VI). This method is based on the adsorption of Cr(VI) on modified alumina‐coated magnetite nanoparticles (ACMNPs). Total chromium in different samples was determined as Cr(VI) after oxidation of Cr(III) to Cr(VI) using H2O2. The chromium concentration has been determined by flame atomic absorption spectrometric (FAAS) technique and amount of Cr(III) was calculated by substracting the concentration of Cr(VI) from total chromium concentration. The effect of parameters such as pH, amount of adsorbent, contact time, sample volume, eluent type, H2O2 concentration and cetyltrimethylammonium bromide (CTAB) concentration as modifier on the quantitative recovery of Cr(VI) were investigated. Under the optimal experimental conditions, the preconcentration factor, detection limit, linear range and relative standard deviation (RSD) of Cr(VI) were 140 (for 350 mL of sample solution), 0.083 ng mL?1, 0.1‐10.0 ng mL?1 and 4.6% (for 5.0 ng mL?1, n = 7), respectively. This method avoided the time‐consuming column‐passing process of loading large volume samples in traditional SPE through the rapid isolation of CTAB@ACMNPs with an adscititious magnet. The proposed method was successfully applied to the determination and speciation of chromium in different water and wastewater samples and suitable recoveries were obtained. 相似文献
90.
Reactions of chloroacetamides (5) with N,N‐dimethylformamide dimethyl acetal gave 1,4‐diaryl‐piperazine‐2,5‐diones 11a–e in good yield, rather than 1,5‐diaryl‐3,7‐dimethoxy‐1H,5H‐[1,5]diazocine‐2,6‐diones (9a–e). 相似文献