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991.
Functionalized crosslinked polystyrene-co-divinylbenzene-co-chloromethylstyrene magnetic latex particles were prepared via emulsifier-free miniemulsion polymerization using 2, 2′ azobis (2-amidinopropane) dihydrochloride (V-50) as an initiator and in the presence of magnetite nanoparticles in the monomers. Transmission electron microscopy (TEM) proved the presence of magnetite nanoparticles in polymer particles. Differential scanning calorimetery (DSC) analysis of the product showed an exothermic signal due to crosslinking of chains through electrophilic aromatic substitution of phenyl groups with chloromethyl groups in the presence of the dispersed Fe3O4 as Lewis acid. This was proven by thermogravimetric analysis (TGA) via the loss of gaseous HCl. The results were also compared with those of magnetite-free miniemulsion polymerization using V-50. 相似文献
992.
Parviz Norouzi Gholam-Reza Nabi Bidhendi Mohammad Reza Ganjali Ali Sepehri Maryam Ghorbani 《Mikrochimica acta》2005,149(1-2):123-129
A novel chemiluminogenic reagent, refered to as spiro form fluorescein hydrazide, was synthesized, and its application to chemiluminescence (CL) determination of Co2+ is described. The method is based on the catalytic effect of Co2+ on the autoxidation of sulfite in basic solution to generate a series of powerful oxidative intermediates, which then oxidize colorless, nonfluoresent fluorescein hydrazide to generate strong CL emission. The CL signal is linearly related to the concentration of Co2+ in the range of 0.1–200nM with a detection limit of 0.04nM. The optimal conditions for the detection of Co2+ were evaluated, and the possible CL mechanism is discussed. The proposed method has been applied to the determination of Co2+ in pharmaceutical preparations and in soil samples. 相似文献
993.
High-throughput capillary electrophoresis for the identification and differentiation of seven species of Eimeria from chickens 总被引:2,自引:0,他引:2
A capillary electrophoretic approach has been evaluated for the identification of seven currently recognised species of Eimeria infecting chickens. The second internal transcribed spacer of ribosomal DNA is PCR-amplified from any of the seven species using a single set of oligonucleotide primers (one of which is fluorescently labelled). The amplicons are heat-denatured and subjected to capillary electrophoresis in a MegaBACE 1000 (Amersham). The chromatograms captured are stored electronically and then analysed using MegaBACE Fragment Profiler software. Using control DNA samples representing monospecific lines of Eimeria, specific peaks in the chromatograms were defined for the unequivocal identification of each of the seven species and their differentiation. Electrophoretic reading and analysis are carried out automatically, thus making it a time- and cost-effective method. This procedure should find applicability as a tool for the quality control of Eimeria vaccines, the monitoring of coccidiosis outbreaks and the high-throughput analysis of oocyst samples for epidemiological surveys. 相似文献
994.
We present experimental measurements of the polarization dependence of two-photon absorption in silicon photodiodes at 1550 nm, and we offer a simple theory that explains our observations. Based on this theory, we propose and demonstrate that it is possible to construct an optical cross-correlation system that is polarization insensitive, provided that one of the two input polarization states can be controlled. 相似文献
995.
Ali Reza Harifi‐Mood Aziz Habibi‐Yangjeh Mohammad Reza Gholami 《Journal of Physical Organic Chemistry》2008,21(9):783-788
The second‐order rate constants for cycloaddition reaction of cyclopentadiene with naphthoquinone were determined spectrophotometrically in various compositions of 1‐(1‐butyl)‐3‐methylimidazolium terafluoroborate ([bmim]BF4) with water and methanol at 25 °C. Rate constants of the reaction in pure solvents are in the order of water > [bmim]BF4 > methanol. Rate constants of the reaction decrease sharply with mole fraction of the ionic liquid in aqueous solutions and increase slightly to a maximum in alcoholic mixtures. Multi‐parameter correlation of logk2 versus solute–solvent interaction parameters demonstrated that solvophobicity parameter (Sp), hydrogen‐bond donor acidity (α) and hydrogen‐bond acceptor basicity (β) of media are the main factors influencing the reaction rate constant. The proposed three‐parameter model shows that the reaction rate constant increases with Sp, α and β parameters. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
996.
Mohammad Reza R. Moghaddam All Reza Salemkar Ahmad Gholami 《Southeast Asian Bulletin of Mathematics》2000,24(2):255-261
Let be a variety of groups defined by the set of laws V. In this paper we study the concept of -isologism of groups in terms of -extensions and their connections with the Baer-invariant of groups are also discussed.AMS Subject Classification (2000): primary 20F14, 20F19, secondary 20E10 相似文献
997.
Mohammad Reza Ganjali Mahmood Golmohammadi Mohammad Yousefi Parviz Norouzi Masoud Salavati-Niasari Mehran Javanbakht 《Analytical sciences》2003,19(2):223-227
A copper(II) ion-selective PVC membrane sensor based on 2-(1'-(4'-(1'-hydroxy-2'-naphthyl)methyleneamino)butyl iminomethyl)-1-naphthol (BHNB) as a novel Schiff base containing a sensing material has been successfully developed. The sensor exhibits a good linear response of 29 mV per decade within the concentration range of 10(-1)-10(-6) M of Cu2+. The sensor shows good selectivity for copper(II) ion in comparison with alkali, alkaline earth, transition and heavy metal ions. The BHNB-based sensor is suitable for use with aqueous solutions of pH 3.5-7.0 and displays minimal interference by Sr(II), Cd(II), Hg(II), Zn(II) and Pb(II), which are known to interfere with other previously suggested electrodes. The proposed membrane electrode was used as a sensor for determining the Cu(II) content in black tea samples. It was also applied as an indicator electrode in the potentiometric titration of Cu2+ ions with EDTA. 相似文献
998.
LetG be a finite group and #Cent(G) denote the number of centralizers of its elements.G is calledn-centralizer if #Cent(G)=n, and primitiven-centralizer if #Cent(G)=#Cent(G/Z(G))=n. In this paper we investigate the structure of finite groups with at most 21 element centralizers. We prove that such a group is solvable and ifG is a finite group such thatG/Z(G)?A5, then #Cent(G)=22 or 32. Moroever, we prove that A5 is the only finite simple group with 22 centralizers. Therefore we obtain a characterization of A5 in terms of the number of centralizers 相似文献
999.
First-order tests of special relativity are based on a comparison of clocks synchronized with the help of slow clock transport with those synchronized by the Einstein procedure. This comparison enables the measurement of the one-way velocity of light and is equivalent to a measurement of the time dilatation factor. The accuracy of present measurements is of the order 10–7, yielding an upper limit of 3 cm/sec for the ether drift. 相似文献
1000.
Analysis of labile Cu2+ in fresh waters using the Cu2+-catalysed oxidation of 1,10-phenanthroline by superoxide anion radical has been investigated. It was found that certain metal ions, notably Fe3+, Fe2+ and Pb2+ enhance the chemiluminescence (CL) intensity of this reaction by up to an order of magnitude when present in the μM concentration range. This enhancement is considered to arise through coordination of the metal ion to 1,10-phenanthroline, which prevents free rotation of the benzene rings in the excited state intermediate thought to be responsible for light emission. This introduces a potential interference when analyzing fresh waters, which usually contain Fe3+ concentrations of this magnitude. However, the enhancement effect saturates at about 4 μM Fe3+, so that reliable results can be obtained if the water sample is supplemented with Fe3+ to reach this level. Application of the enhanced technique to a river water, and a reservoir to which CuSO4 had been added to control algal growth, are described. In both cases, only a small fraction of total dissolved Cu2+ is labile with respect to the chemiluminesence method. 相似文献