首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   18146篇
  免费   3302篇
  国内免费   3180篇
化学   13525篇
晶体学   406篇
力学   1106篇
综合类   235篇
数学   2103篇
物理学   7253篇
  2024年   46篇
  2023年   343篇
  2022年   460篇
  2021年   640篇
  2020年   685篇
  2019年   749篇
  2018年   626篇
  2017年   645篇
  2016年   792篇
  2015年   867篇
  2014年   1092篇
  2013年   1485篇
  2012年   1647篇
  2011年   1821篇
  2010年   1366篇
  2009年   1324篇
  2008年   1362篇
  2007年   1327篇
  2006年   1130篇
  2005年   948篇
  2004年   802篇
  2003年   580篇
  2002年   557篇
  2001年   493篇
  2000年   481篇
  1999年   355篇
  1998年   252篇
  1997年   192篇
  1996年   214篇
  1995年   185篇
  1994年   197篇
  1993年   144篇
  1992年   150篇
  1991年   117篇
  1990年   104篇
  1989年   94篇
  1988年   51篇
  1987年   52篇
  1986年   56篇
  1985年   44篇
  1984年   38篇
  1983年   24篇
  1982年   7篇
  1981年   13篇
  1980年   5篇
  1979年   12篇
  1977年   6篇
  1976年   8篇
  1975年   7篇
  1957年   5篇
排序方式: 共有10000条查询结果,搜索用时 523 毫秒
51.
MC模式下顾客需求与厂商供应的纳什均衡   总被引:3,自引:0,他引:3  
在大规模定制(MC,Mass Customization)模式下,基于市场需求的复杂化,厂商对个性化的顾客需求很难做出及时准确的反应,而且由于其自身生产能力的限制,不可能对所有的个性化用户进行一一地满足,只可能对已经存在的个性化需求,根据自身的生产能力和规模,以利润最大化及顾客对产品的满意度为目标,对个性化需求进行较准确地预测,从而正确指导生产。本通过博弈论的方法,提出了一个基于顾客对产品的满意度及企业的利润的一个非合作博弈模型,并给出求解纳什均衡的方法。  相似文献   
52.
A low cost, coolerless 980nm diode pumped, gain flattened L band EDFA with fast transient control, high pump efficiency and gain clamping effect was realized by using FBGs as C band seed generators.  相似文献   
53.
The atom transfer radical copolymerization of N‐substituted maleimides such as N‐phenylmaleimide (PhMI), N‐cyclohexylmaleimide (ChMI), and N‐butylmaleimide (NBMI) with styrene initiated with dendritic polyarylether 2‐bromoisobutyrates in an ionic liquid, 1‐butyl‐3‐methylimidazolium hexafluorophosphate ([bmim][PF6]), at room temperature and anisole at 110 °C was investigated. The dendritic‐linear block copolymers obtained in ionic liquid possessed well‐defined molecular weight and low polydispersity (1.05 < Mw/Mn < 1.32) and could be used as a macroinitiator for chain‐extension polymerization, suggesting the living nature of the reaction system. The ionic liquids containing catalyst could be recycled in the atom transfer radical polymerization systems without further treatment. Compared with polymerization conducted in anisole, the polymerization in ionic liquid had a stronger tendency for alternation. The tendency for alternation decreased in the order PhMI > NBMI > ChMI in [bmim][PF6] and PhMI > ChMI > NBMI in anisole. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2156–2165, 2003  相似文献   
54.
A soluble cyano‐substituted poly[(1,3‐phenylene vinylene)‐alt‐(1,4‐phenylene vinylene)] derivative ( 9 ) was synthesized and characterized. Comparison between 9 and its model compound ( 10 ) showed that the chromophore in 9 remained to be well defined as a result of a π‐conjugation interruption at adjacent m‐phenylene units. The attachment of a cyano substituent only at the β position of the vinylene allowed the maximum electronic impact of the cyano group on the optical properties of the poly(p‐phenylene vinylene) material. At a low temperature (?108 or ?198 °C), the vibronic structures of 9 and 10 were partially resolved. The absorption and emission spectra of a film of 9 were less temperature‐dependent than those of a film of 10 , indicating that the former had a lower tendency to aggregate. A light‐emitting diode (LED) based on 9 emitted yellow light (λmax ≈ 578 nm) with an external quantum efficiency of 0.03%. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3149–3158, 2003  相似文献   
55.
采用高温热解法,以乙二胺为前驱液,在沉积有铁催化剂的p型硅(111)基底上制备出了定向生长的CNx纳米管.利用扫描电子显微镜、高分辨率透射电子显微镜和拉曼光谱对CNx纳米管进行了形貌观察和表征.CNx纳米管的高度在20?μm左右,直径在50—100nm之间,具有明显的“竹节状”结构,结晶有序度较差.对CNx纳米管薄膜进行低场致发射性能测试:外加电场为1.4V/μm,观察到20?μA /cm2发射电流,外电场升至2.54V/μm时发射电流达到1.280mA/cm2,在较高外电场下,没有发现电流“饱和”.这比 关键词: CNx纳米管 高温热解 “竹节状”结构 场致发射  相似文献   
56.
线性均衡约束最优化的一个广义投影强次可行方向法   总被引:1,自引:0,他引:1  
本文讨论带线性均衡约束最优化问题,首先利用摄动技术和一个互补函数将问题等价转化为一般约束最优化问题,然后结合广义投影技术和强次可行方向法思想,建立了问题的一个新算法.算法在迭代过程中保证搜索方向不为零,从而使得每次迭代只需计算一次广义投影.在适当的条件下,证明了算法的全局收敛性,并对算法进行了初步的数值试验.  相似文献   
57.
Two quantities ηrel and are applied to study the nonideal acetone–water association mixture. An all-atom acetone model and a TIP5P water model have been adopted for molecular dynamics simulation. We study the transport properties of the system comparing the 's of strong hydrogen bond and weak contact based on transport properties, MD simulations together with NMR experimental data and find good agreement of concentration dependence, which exhibits the cooperation effect.  相似文献   
58.
用形变的相对论平均场模型,Skyrme-Hartree-Fock模型及宏观-微观模型研究了新核素278113及其α衰变链的α衰变能和半衰期.计算的α衰变能同实验数据比较符合,相应的半衰期也在合理的范围内.计算进一步表明形变对超重核的基态性质有重要影响.  相似文献   
59.
A gas-filled type of recoil separator for heavy element research was installed at an experimental hall of RIKEN Linear Accelerator facility to realize getting higher intensity of primary beam and long beam time. Performance of the separator was studied using target recoils and various nuclear reactions. The results show the high performance of the separator for heave element research. As an application of the GARIS, production and identification of an isotope of the 110th element 271[110] have been performed using the 208Pb(64Ni,1n)271[110] reaction. Three decay chains coincide well both in decay times and energies with the ones reported by the group of SHIP experiment at GSI, Germany. Our results provide a confirmation of the synthesis of an isotope 271[110] of element 110.  相似文献   
60.
Non-dispersive atomic fluorescence spectrometry (NDAFS) coupled with vapor generation (VG) sample introduction was applied to the determination of the concentrations of hazardous heavy metals, such as arsenic, cadmium, lead and mercury, in seawater, soils and total airborne particulate matter (PM) collected around the Xiamen area in China. Almost 100% sample introduction efficiency was achieved by using thiourea and ascorbic acid for the pre-reduction of As(V) to As(III), K3Fe(CN)6 and tartaric acid for pre-oxidation of Pb(II) to Pb(IV), and masking the interferences arising from the co-existing transition metals to As, Cd, Hg and Pb during their vapor generation process. Moreover, a novel sample pretreatment device was developed to avoid the loss of mercury, lead, cadmium and arsenic during sample pretreatment. With such methods, the detection limit (DL) of arsenic, cadmium, lead and mercury was down to 0.08, 0.03, 0.05, 0.01 ng mL(-1) (3sigma), respectively. The relative standard deviations (RSD, n = 11) for arsenic, cadmium, lead and mercury at 10 ng mL(-1) were 0.9%, 1.6%, 1.3% and 2.0%, respectively. The concentrations of hazardous heavy metals in the environmental samples collected in Xiamen, China are in the range from 0.02 +/- 0.001 ng mL(-1) in seawater to 15.3 +/- 0.2 microg g(-1) in soils. Besides flame/GF-AAS and ICP-AES/MS, VG-NDAFS should be another choice for the determination of hazardous heavy metals in environmental samples.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号