全文获取类型
收费全文 | 13418篇 |
免费 | 2442篇 |
国内免费 | 3501篇 |
专业分类
化学 | 10570篇 |
晶体学 | 255篇 |
力学 | 864篇 |
综合类 | 346篇 |
数学 | 1752篇 |
物理学 | 5574篇 |
出版年
2024年 | 21篇 |
2023年 | 255篇 |
2022年 | 423篇 |
2021年 | 498篇 |
2020年 | 592篇 |
2019年 | 584篇 |
2018年 | 481篇 |
2017年 | 556篇 |
2016年 | 672篇 |
2015年 | 754篇 |
2014年 | 815篇 |
2013年 | 1142篇 |
2012年 | 1025篇 |
2011年 | 1156篇 |
2010年 | 950篇 |
2009年 | 930篇 |
2008年 | 1042篇 |
2007年 | 872篇 |
2006年 | 849篇 |
2005年 | 758篇 |
2004年 | 659篇 |
2003年 | 488篇 |
2002年 | 559篇 |
2001年 | 501篇 |
2000年 | 477篇 |
1999年 | 369篇 |
1998年 | 245篇 |
1997年 | 182篇 |
1996年 | 206篇 |
1995年 | 157篇 |
1994年 | 190篇 |
1993年 | 145篇 |
1992年 | 111篇 |
1991年 | 124篇 |
1990年 | 123篇 |
1989年 | 80篇 |
1988年 | 79篇 |
1987年 | 58篇 |
1986年 | 44篇 |
1985年 | 53篇 |
1984年 | 28篇 |
1983年 | 26篇 |
1982年 | 21篇 |
1981年 | 19篇 |
1980年 | 11篇 |
1979年 | 7篇 |
1965年 | 4篇 |
1957年 | 4篇 |
1955年 | 2篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
High aspect-ratio, single crystal BaWO4 nanowires with diameters as small as 3.5 nm and lengths up to more than 50 microns were synthesized in catanionic reverse micelles formed by an equimolar mixture of two surfactants: undecylic acid and decylamine. 相似文献
992.
A stable paramagnetic calix[4]arene(III) bearing two nitroxide groups on the upper rim is synthesized, which exhibits a strong intramolecular spin-spin exchange interaction and is found to be able to undergo reversible conformational transitions upon heating. 相似文献
993.
Aubert B Boutigny D Gaillard JM Hicheur A Karyotakis Y Lees JP Robbe P Tisserand V Palano A Pompili A Chen GP Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Stugu B Abrams GS Borgland AW Breon AB Brown DN Button-Shafer J Cahn RN Clark AR Gill MS Gritsan AV Groysman Y Jacobsen RG Kadel RW Kadyk J Kerth LT Kolomensky YG Kral JF LeClerc C Levi ME Lynch G Oddone PJ Pripstein M Roe NA Romosan A Ronan MT Shelkov VG Telnov AV Wenzel WA Harrison TJ Hawkes CM Knowles DJ O'Neale SW Penny RC Watson AT 《Physical review letters》2002,88(22):221802
Flavor oscillations of neutral B mesons have been studied in e+e- annihilation data collected with the BABAR detector at center-of-mass energies near the upsilon(4S) resonance. The data sample used for this purpose consists of events in which one B0 meson is reconstructed in a hadronic decay mode, while the flavor of the recoiling B0 is determined with a tagging algorithm that exploits the correlation between the flavor of the heavy quark and the charges of its decay products. From the time development of the observed mixed and unmixed final states, we determine the B0-B-0 oscillation frequency deltamd to be 0.516+/-0.016(stat)+/-0.010(syst) ps-1. 相似文献
994.
Aubert B Boutigny D Gaillard JM Hicheur A Karyotakis Y Lees JP Robbe P Tisserand V Palano A Chen GP Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Reinertsen PL Stugu B Abbott B Abrams GS Borgland AW Breon AB Brown DN Button-Shafer J Cahn RN Clark AR Gill MS Gritsan AV Groysman Y Jacobsen RG Kadel RW Kadyk J Kerth LT Kluth S Kolomensky YG Kral JF LeClerc C Levi ME Liu T Lynch G Meyer AB Momayezi M Oddone PJ Perazzo A Pripstein M Roe NA Romosan A Ronan MT Shelkov VG Telnov AV Wenzel WA Zisman MS 《Physical review letters》2002,88(10):101805
The branching fractions of the exclusive decays B0-->K(*0)gamma and B+-->K(*+)gamma are measured from a sample of (22.74+/-0.36)x10(6) BB decays collected with the BABAR detector at the PEP-II asymmetric e(+)e(-) collider. We find B (B0-->K(*0)gamma) = [4.23+/-0.40(stat)+/-0.22(syst)]x10(-5), B(B+-->K(*+)gamma) = [3.83+/-0.62(stat)+/-0.22(syst)]x10(-5) and constrain the CP-violating charge asymmetry to be -0.170K(*)gamma)<0.082 at 90% C.L. 相似文献
995.
采用矩量法并结合快速多极子方法,对电磁脉冲模拟器内部场波形进行了数值计算,寻找过渡段结构与电磁脉冲波形等的关系,从理论上对模拟器前后过渡段的锥角进行了优化。结果表明:存在前后过渡段的结构都会激起场强沿传播方向的分量;前过渡段主要对工作区域场波形的上升沿产生影响,当前锥角减小时,场波形的上升时间先减小再缓慢增加;后过渡段主要对场波形的衰减部分产生影响,使场波形的衰减部分随着后锥角的增大而产生严重畸变。最终优化设计的电磁脉冲模拟器前过渡段的锥角为15°,后过渡段的锥角为20°,其仿真得到的波形较光滑,没有出现振荡及明显的畸变。 相似文献
996.
Qi JH Zhang XY Zhang RS Liu MC Hu ZD Xue HF Fan BT 《SAR and QSAR in environmental research》2000,11(2):117-131
It is proposed for the first time a method of prediction of the programmed-temperature retention times of components of naphthas in capillary gas chromatography using artificial neural networks. People are used to predict the programmed-temperature retention time using many formulas such as the integral formula, which requires that four parameters must be determined by calculation or experiments. However the results obtained by the formula are not so good to meet the demand of industry. In order to predict retention time accurately and conveniently, artificial neural networks using five-fold cross-validation and leave-20%-out methods have been applied. Only two parameters: density and isothermal retention index were used as input vectors. The average RMS error for predicted values of five different networks was 0.18, whereas the RMS error of predictions by the integral formula was 0.69. Obviously, the predictions by neural networks were much better than predictions by the formula, and neural networks need fewer parameters than the formula. So neural networks can successfully and conveniently solve the problem of predictions of programmed-temperature retention times, and provide useful data for analysis of naphthas in petrochemical industry. 相似文献
997.
James B. Gerken Claire Badger Christopher Bisbee Sasha Gardner Yan Qi Víctor Durà Vilà John D. Roberts 《Journal of Physical Organic Chemistry》2008,21(3):193-197
Conformational preferences of glutaric, 3‐hydroxyglutaric and 3‐methylglutaric acid, and their mono‐ and dianions have been investigated with the aid of NMR spectroscopy. In contrast to succinic acid, glutaric acid displays essentially statistical conformational equilibria in polar and non‐polar solutions of high and low hydrogen‐bonding ability with no clear evidence for intramolecular hydrogen‐bonding interactions. The acid ionization constant ratios, K 1/K2, in D2O and DMSO of glutaric, 3‐hydroxyglutaric, and 3‐methylglutaric acids also indicate that intramolecular interactions are much less important than, or indeed insignificant, for shorter‐chain acids. FTIR studies on 3‐methylglutaric acid indicate some preference for either association with solvent or dimerization, depending on the solvent, rather than intramolecular hydrogen bonding. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
998.
由游离的三氨基胍和叠氮酸在非水溶剂中合成三氨基胍叠氮酸盐( T A Z),其结构由元素分析、质谱( M S)和 I R谱所证实 相似文献
999.
Extremal rays on higher dimensional projective varieties 总被引:3,自引:0,他引:3
Qi Zhang 《Mathematische Annalen》1991,291(1):497-504
1000.
In this Letter, using Backlund transformation and the new variable separation approach, we find a new general solution to the (3 1)-dimensional Burgers equation. The form of the universal formula obtained from many (2 1)-dimensional systems is extended. Abundant localized coherent structures can be found by seclecting corresponding functions appropriately. 相似文献