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111.
Mike A. Miller 《Colloid and polymer science》1937,80(3):327-333
Zusammenfassung Aus einer Reihe von Untersuchungen über Bildung, Niederschlagung, scheinbaren Bewegung und Austausch von kristallinem Jod
und unl?slichen kristallinen Jodiden in verschiedenen Gelen und anderen Mitteln wurde gefolgert, da? die Prozesse der Niederschlagung
des Reaktionsproduktes und der Diffusion dieses Produktes nicht voneinander getrennt werden k?nnen. Es wurde darauf hingewiesen,
da? die offensichtliche Wanderung von kristallinem Jod und unl?slichen kristallinen Jodiden in Gelstrukturen sich als eine
Folge der Wiederaufl?sung in einem Teil der Kristallmasse und der Wiederablagerung an einem andern Teile zu ergeben scheint.
Untersuchungen über den Austausch von kristallinem Jod durch unl?sliche Jodide und umgekehrt haben gezeigt, da? unter gewissen
passenden Diffusionsbedingungen, wie z. B. im Kiesels?uregel, sich pseudomorphe Kristalle bilden k?nnen. Pseudomorphe Kristalle
wurden in kapillaren R?umen zwischen Glasplatten nicht erhalten, obzwar sich eine ausgesprochene Neigung hierzu zeigte.
Material wurde dargelegt, um zu zeigen, da? sich verschiedene Arten von Jodablagerungen als eine Folge der Wirkung des Mittels
ergeben k?nnen. Diese Ablagerungen k?nnen sich von kolloiden bis zu makroskopischen Dimensionen und von sehr verzerrten bis
zu fast vollkommenen kristallinen Formen erstrecken. Unter gewissen Bedingungen scheinen sich Somatoide zu bilden. Umgebungen,
in denen diese Reaktionen ausgeführt wurden, waren a) verschiedene Gele, b) Schichten zwischen Glasplatten, c) Poren absorbierenden
Papiers und d) Membranoberfl?chen. 相似文献
112.
Synthesis and Structures of Gallium‐β‐Diketiminate Complexes: Isolation of a Dinuclear Gallium(II) Complex 下载免费PDF全文
The sterically demanding β‐diketiminate ligand Ldmp [Ldmp = HC{(CMe)N(dmp)}2, dmp = C6H3‐2,6‐Me2] was used to stabilize various gallium complexes in the formal oxidation states +II and +III. The reaction of in situ generated [LdmpLi] with gallium chloride affords [LdmpGaCl2] ( 1 ), which was used as starting complex to synthesize a variety of gallium(III) compounds [LdmpGaX2] [X = F ( 2 ), I ( 3 ), H ( 4 ), and Me ( 5 )]. Synthesis of the dinuclear complex [LdmpGaI]2 ( 6 ), with gallium in the formal oxidation state +II was accomplished by converting “GaI” with in situ generated [LdmpLi] in toluene. All compounds were characterized by elemental analyses, NMR spectroscopy, LIFDI‐TOF‐MS, and single‐crystal X‐ray diffraction. Additionally DFT calculations were performed for analysis of the bonding in 6 . 相似文献
113.
The system constants of the solvation parameter model are used to prepare system maps for the retention of small neutral compounds on an ethyl-bridged, ocatadecylsiloxane-bonded superficially porous silica stationary phase (Kinetex EVO C18) for aqueous mobile phases containing 10–70% (v/v) methanol or acetonitrile. Electrostatic interactions (cation-exchange) are important for the retention of weak bases with acetonitrile–water but not methanol–water mobile phase compositions. Compared with a superficially porous octadecylsiloxane-bonded silica stationary phase (Kinetex C18) with a similar morphology but different topology statistically significant differences in selectivity at the 95% confidence level are observed for neutral compounds that vary by size and hydrogen-bond basicity with other intermolecular interactions roughly similar. These selectivity differences are dampened with acetonitrile–water mobile phases, but are significant for methanol–water mobile phase compositions containing <30% (v/v) methanol. A comparison of a totally porous ethyl-bridged, octadecylsiloxane-bonded silica stationary phase (XBridge C18) with Kinetex EVO C18 indicated that they are effectively selectivity equivalent. 相似文献
114.
Luana Bettanin Sumbal Saba Fábio Z. Galetto Gustavo A. Mike Jamal Rafique Antonio L. Braga 《Tetrahedron letters》2017,58(50):4713-4716
We describe herein a simple, fast and inexpensive protocol for the oxidative coupling of thiols employing a stoichiometric amount of DMSO and iodine as the catalyst. Various aromatic disulfides were obtained in good to excellent yields in short reaction times at room temperature, while aliphatic disulfides were achieved in good yields when the reactions were conducted under microwave irradiation. 相似文献
115.
Several different models have been proposed to explain the origin of the complex anti-hole features observed in hole-burned (HB) spectra of excitonically coupled systems such as photosynthetic complexes. This lack of consensus presents a serious constraint on the interpretation of HB spectra and the underlying electronic structures of these systems. To resolve this problem we present results of modeling studies of non-resonant HB spectra taking uncorrelated excitation energy transfer and excitonic interactions into account. Simplified analytical results are compared with Monte Carlo simulations in which excitonic interactions are explicitly taken into account in order to disentangle a number of distinct effects. It is shown that these effects can accurately account for both hole shapes and the broad anti-hole structure observed in excitonically coupled systems. We argue that these models will provide a necessary framework for probing the electronic structure of these systems via HB spectroscopy. 相似文献
116.
Peter Ferenc Peter Solár Ján Kleban Jaromír Mikeš Peter Fedoročko 《Journal of photochemistry and photobiology. B, Biology》2010,98(1):25-34
Presented experiment considers combination of genistein and photodynamic therapy with hypericin with a view to achieve higher therapeutic outcome in human breast adenocarcinoma cell lines MCF-7 and MDA-MB-231, both identified in our conditions as photodynamic therapy resistant. Since genistein is known to suppress Bcl-2 expression, we predicted that photodynamic therapy with hypericin might benefit from mutual therapeutic combination. In line with our expectations, combined treatment led to down-regulation of Bcl-2 and up-regulation of Bax in both cell lines as well as to suppression of Akt and Erk1/2 phosphorylation induced by photoactivated hypericin in MCF-7 cells. Although Akt and Erk1/2 phosphorylation was not stimulated by photodynamic therapy with hypericin in MDA-MB-231 cells, it was effectively suppressed in combination. Variations in cell death signaling favoring apoptosis were indeed accompanied by cell cycle arrest in G2/M-phase, activation of caspase-7, PARP cleavage and increased occurrence of cells with apoptotic morphology of nucleus. All these events corresponded with suppression of proliferation and significantly lowered clonogenic ability of treated cells. In conclusion, our results indicate that pre-treatment with tyrosine kinase inhibitor genistein may significantly improve the effectiveness of photodynamic therapy with hypericin in MCF-7 and MDA-MB-231 breast cancer cells. 相似文献
117.
We have studied the potential degradation of poly(lactic acid)-based fabrics treated with commercial softeners and stored under two sets of conditions for one year. Initial wet-processing caused a fall in molecular weight of about 28%, irrespective of after-treatment. Storage at 40 °C and 80% RH produced further degradation which, with few exceptions, was aggravated by the presence of softeners. Ultimately, all samples degraded beyond the point of commercial usefulness. No clear distinction could be made between the effects of softeners having differing compositions. In contrast, fabrics stored under milder conditions of 23 °C and 50% RH showed no significant time-dependent polymer degradation, irrespective of the treatment applied. There were slight changes in tensile properties and some evidence of physical structural effects having occurred, which we attribute to physical aging. However, we do not believe these to be so serious as to call into question the long-term viability of PLA-based textile products. 相似文献
118.
The readily available homochiral ligand (1) was used to prepare four mononuclear nickel and cobalt complexes with a 2:1 ligand:metal ratio. X-ray crystal structures of these revealed that in all cases the N,N,O-tridentate ligand adopts facial coordination to the metal with the pyridine rings trans-disposed and the carboxylate and amine groups cis. The individual crystal structures of these compounds differ significantly in the way the complexes pack, which is mediated by hydrogen bonding involving the cations, anions and water molecules as well as, in one case, π-stacking. 相似文献
119.
120.
Min Liu Mike Ronk Da Ren Judy Ostovic Nina Cauchon Zhaohui Sunny Zhou Janet Cheetham 《Journal of chromatography. A》2010,1217(22):3598-3611
A hydrophilic interaction liquid chromatography (HILIC) method was used to separate a commonly used pharmaceutical starting material, 4-aminomethylpyridine (4-AMP), and its degradants. The structures of the major degradants were characterized and elucidated without prior isolation by accurate mass measurement, MS/MS analysis and on-line hydrogen/deuterium (H/D) exchange experiments. The mass spectra obtained from H/D exchange experiments are particularly useful to differentiate structural isomers, to elucidate the fragmentation pathways, and to aid in structure elucidation in the absence of MS/MS fragmentation information. The impact of deuterium oxide and temperature on HILIC separation has also been explored here. The integration of H/D exchange with HILIC has been described here for the first time and has been demonstrated to be a powerful structure elucidation tool via the study of degradants in 4-AMP. 相似文献