全文获取类型
收费全文 | 1181篇 |
免费 | 53篇 |
国内免费 | 17篇 |
专业分类
化学 | 727篇 |
晶体学 | 3篇 |
力学 | 20篇 |
数学 | 259篇 |
物理学 | 242篇 |
出版年
2023年 | 16篇 |
2022年 | 14篇 |
2021年 | 47篇 |
2020年 | 32篇 |
2019年 | 50篇 |
2018年 | 59篇 |
2017年 | 36篇 |
2016年 | 56篇 |
2015年 | 42篇 |
2014年 | 35篇 |
2013年 | 46篇 |
2012年 | 103篇 |
2011年 | 112篇 |
2010年 | 50篇 |
2009年 | 58篇 |
2008年 | 62篇 |
2007年 | 72篇 |
2006年 | 69篇 |
2005年 | 73篇 |
2004年 | 36篇 |
2003年 | 40篇 |
2002年 | 33篇 |
2001年 | 5篇 |
2000年 | 3篇 |
1999年 | 14篇 |
1998年 | 6篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1995年 | 2篇 |
1994年 | 6篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 6篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 6篇 |
1973年 | 2篇 |
1961年 | 1篇 |
1960年 | 1篇 |
1934年 | 1篇 |
排序方式: 共有1251条查询结果,搜索用时 15 毫秒
71.
Ying Liu Ximing Rong Mingze Li Maxim S. Molokeev Jing Zhao Zhiguo Xia 《Angewandte Chemie (International ed. in English)》2020,59(28):11634-11640
The incorporation of impurity ions or doping is a promising method for controlling the electronic and optical properties and the structural stability of halide perovskite nanocrystals (NCs). Herein, we establish relationships between rare‐earth ions doping and intrinsic emission of lead‐free double perovskite Cs2AgInCl6 NCs to impart and tune the optical performances in the visible light region. Tb3+ ions were incorporated into Cs2AgInCl6 NCs and occupied In3+ sites as verified by both crystallographic analyses and first‐principles calculations. Trace amounts of Bi doping endowed the characteristic emission (5D4→7F6‐3) of Tb3+ ions with a new excitation peak at 368 nm rather than the single characteristic excitation at 290 nm of Tb3+. By controlling Tb3+ ions concentration, the emission colors of Bi‐doped Cs2Ag(In1?xTbx)Cl6 NCs could be continuously tuned from green to orange, through the efficient energy‐transfer channel from self‐trapped excitons to Tb3+ ions. Our study provides the salient features of the material design of lead‐free perovskite NCs and to expand their luminescence applications. 相似文献
72.
For the three-dimensional incompressible Navier–Stokes equations, we present a formulation featuring velocity, vorticity and helical density as independent variables. We find the helical density can be observed as a Lagrange multiplier corresponding to the divergence-free constraint on the vorticity variable, similar to the pressure in the case of the incompressibility condition for velocity. As one possible practical application of this new formulation, we consider a time-splitting numerical scheme based on an alternating procedure between vorticity–helical density and velocity–Bernoulli pressure systems of equations. Results of numerical experiments include a comparison with some well-known schemes based on pressure–velocity formulation and illustrate the competitiveness on the new scheme as well as the soundness of the new formulation. 相似文献
73.
74.
Yury Yu. Rusakov Leonid B. Krivdin Maxim V. Penzik Vladimir A. Potapov Svetlana V. Amosova 《Magnetic resonance in chemistry : MRC》2012,50(10):653-658
Stereochemical structure of nine Z‐2‐(vinylsulfanyl)ethenylselanyl organyl sulfides has been investigated by means of experimental measurements and second‐order polarization propagator approach calculations of their 1H–1H, 13C–1H, and 77Se–1H spin–spin coupling constants together with a theoretical conformational analysis performed at the MP2/6‐311G** level. All nine compounds were shown to adopt the preferable skewed s‐cis conformation of their terminal vinylsulfanyl group, whereas the favorable rotational conformations with respect to the internal rotations around the C–S and C–Se bonds of the internal ethenyl group are both skewed s‐trans. Stereochemical trends of 77Se–1H spin–spin coupling constants originating in the geometry of their coupling pathways and the selenium lone pair effect were rationalized in terms of the natural J‐coupling analysis within the framework of the natural bond orbital approach. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
75.
Ratnikov MO Lipilin DL Churakov AM Strelenko YA Tartakovsky VA 《Organic letters》2002,4(19):3227-3229
[reaction: see text] The reduction of benzo-1,2,3,4-tetrazine 1,3-dioxides (BTDOs) 1 with Na(2)S(2)O(4) or SnCl(2) is suggested to proceed via intermediate N-nitrosobenzotriazoles 3 to afford benzotriazoles 2. The (15)N-labeling experiments exhibit that the N-3 atom of the tetrazine ring is incorporated into the nitroso group of 3 that is ultimately released into solution. It is possible that the biological activity of BTDOs is due to their ability to release nitrosating species, i.e., N-nitrosotriazol 3 or HNO(2), in the course of reduction. 相似文献
76.
Scalora M Syrchin MS Akozbek N Poliakov EY D'Aguanno G Mattiucci N Bloemer MJ Zheltikov AM 《Physical review letters》2005,95(1):013902
A new generalized nonlinear Schr?dinger equation describing the propagation of ultrashort pulses in bulk media exhibiting frequency dependent dielectric susceptibility and magnetic permeability is derived and used to characterize wave propagation in a negative index material. The equation has new features that are distinct from ordinary materials (mu=1): the linear and nonlinear coefficients can be tailored through the linear properties of the medium to attain any combination of signs unachievable in ordinary matter, with significant potential to realize a wide class of solitary waves. 相似文献
77.
We study the effects of the RKKY interaction between magnetic impurities on the mesoscopic conductance fluctuations of a metal ring with dilute magnetic impurities. At sufficiently low temperatures and strong magnetic fields, the loss of electron coherence occurs mainly due to the scattering off rare pairs of strongly coupled magnetic impurities. We establish a relation between the dephasing rate and the distribution function of the exchange interaction within such pairs. In the case of the RKKY exchange interaction, this rate exhibits 1/B(2) behavior in strong magnetic fields. We demonstrate that the Aharonov-Bohm conductance oscillations may be used as a probe of the distribution function of the exchange interaction between magnetic impurities in metals. 相似文献
78.
We construct supersymmetric Lorentz violating operators for matter and gauge fields. We show that in the supersymmetric standard model the lowest possible dimension for such operators is five, and therefore they are suppressed by at least one power of an ultraviolet energy scale, providing a possible explanation for the smallness of Lorentz violation and its stability against radiative corrections. Supersymmetric Lorentz noninvariant operators do not lead to modifications of dispersion relations at high energies thereby escaping constraints from astrophysical searches for Lorentz violation. 相似文献
79.
Brown AM Ovchinnikov MV Stern CL Mirkin CA 《Journal of the American Chemical Society》2004,126(44):14316-14317
A novel reaction involving the halide-induced rearrangement of ligands within supramolecular Rh(I) complexes containing hemilabile ligands is presented. Three analogous bis- and trishemilabile ligands have been synthesized to construct bi- and trimetallic Rh(I) macrocyclic complexes. An intentionally added halide source results in the formal rotation of only one hemilabile ligand along the axis that is perpendicular to the plane defined by the aryl backbone of the hemilabile ligands. X-ray structures, as determined by X-ray crystallography, of key intermediates and products are presented. 相似文献
80.
Let $G_M$ be either the orthogonal group $O_M$ or the
symplectic group $Sp_M$ over the complex field; in the latter case
the non-negative integer $M$ has to be even. Classically, the
irreducible polynomial representations of the group $G_M$ are
labeled by partitions $\mu=(\mu_{1},\mu_{2},\,\ldots)$
such that $\mu^{\prime}_1+\mu^{\prime}_2\le M$ in the case $G_M=O_M$, or
$2\mu^{\prime}_1\le M$ in the case $G_M=Sp_M$. Here
$\mu^{\prime}=(\mu^{\prime}_{1},\mu^{\prime}_{2},\,\ldots)$ is the partition
conjugate to $\mu$. Let $W_\mu$ be the irreducible polynomial
representation of the group $G_M$ corresponding to $\mu$.
Regard $G_N\times G_M$ as a subgroup of $G_{N+M}$.
Then take any irreducible polynomial representation
$W_\lambda$ of the group $G_{N+M}$.
The vector space
$W_{\lambda}(\mu)={\rm Hom}_{\,G_M}( W_\mu, W_\lambda)$
comes with a natural action of the group $G_N$.
Put $n=\lambda_1-\mu_1+\lambda_2-\mu_2+\ldots\,$.
In this article, for any standard Young tableau $\varOmega$ of
skew shape $\lm$ we give a realization of $W_{\lambda}(\mu)$
as a subspace in the $n$-fold tensor product
$(\mathbb{C}^N)^{\bigotimes n}$, compatible with the action of the group $G_N$.
This subspace is determined as the image of a certain linear operator
$F_\varOmega (M)$ on $(\mathbb{C}^N)^{\bigotimes n}$, given by an explicit formula.
When $M=0$ and $W_{\lambda}(\mu)=W_\lambda$ is an irreducible representation of
the group $G_N$, we recover the classical realization of $W_\lambda$
as a subspace in the space of all traceless tensors in $(\mathbb{C}^N)^{\bigotimes n}$.
Then the operator $F_\varOmega\(0)$ may be regarded as the analogue
for $G_N$ of the Young symmetrizer, corresponding to the
standard tableau $\varOmega$ of shape $\lambda$.
This symmetrizer is a certain linear operator on
$\CNn$$(\mathbb{C}^N)^{\bigotimes n} $ with the image equivalent to the irreducible
polynomial representation of the complex general linear group
$GL_N$, corresponding to the partition $\lambda$. Even in the case
$M=0$, our formula for the operator $F_\varOmega(M)$ is new.
Our results are applications of the representation
theory of the twisted Yangian, corresponding to the
subgroup $G_N$ of $GL_N$. This twisted Yangian
is a certain one-sided coideal subalgebra of the Yangian corresponding
to $GL_N$. In particular, $F_\varOmega(M)$ is an intertwining
operator between certain representations of the twisted Yangian
in $(\mathbb{C}^N)^{\bigotimes n}$. 相似文献