全文获取类型
收费全文 | 1730篇 |
免费 | 70篇 |
国内免费 | 20篇 |
专业分类
化学 | 985篇 |
晶体学 | 9篇 |
力学 | 39篇 |
数学 | 525篇 |
物理学 | 262篇 |
出版年
2023年 | 12篇 |
2022年 | 36篇 |
2021年 | 78篇 |
2020年 | 70篇 |
2019年 | 66篇 |
2018年 | 89篇 |
2017年 | 70篇 |
2016年 | 88篇 |
2015年 | 57篇 |
2014年 | 77篇 |
2013年 | 123篇 |
2012年 | 114篇 |
2011年 | 121篇 |
2010年 | 78篇 |
2009年 | 63篇 |
2008年 | 101篇 |
2007年 | 68篇 |
2006年 | 54篇 |
2005年 | 56篇 |
2004年 | 34篇 |
2003年 | 34篇 |
2002年 | 25篇 |
2001年 | 15篇 |
2000年 | 8篇 |
1999年 | 11篇 |
1998年 | 11篇 |
1997年 | 8篇 |
1996年 | 13篇 |
1995年 | 16篇 |
1994年 | 16篇 |
1993年 | 12篇 |
1992年 | 13篇 |
1991年 | 11篇 |
1990年 | 10篇 |
1989年 | 12篇 |
1988年 | 6篇 |
1987年 | 7篇 |
1986年 | 11篇 |
1985年 | 15篇 |
1984年 | 7篇 |
1983年 | 6篇 |
1982年 | 18篇 |
1981年 | 12篇 |
1980年 | 8篇 |
1979年 | 9篇 |
1978年 | 7篇 |
1977年 | 7篇 |
1976年 | 8篇 |
1975年 | 7篇 |
1973年 | 8篇 |
排序方式: 共有1820条查询结果,搜索用时 15 毫秒
41.
Phytochemistry of genus Gentiana XXV: Study of the flavonic and xanthonic compounds in leaves of Gentiana X marcailhouana RY . New cinnamoyl-C-glucosyl-flavones Nine flavonic compounds: isoorientin ( 1 ), isovitexin ( 2 ), isoorientin-4′-O-β-D -glucoside ( 3 ), isovitexin-4′-O-β-D -glucoside ( 4 ), luteolin-7-O-β-D -glucoside ( 5 ), trans-cafeoyl-2′′-isoorientin ( 6 ), trans-feruloyl-2′′-isoorientin ( 7 ), trans-p-coumaroyl-2′′-isoorientin ( 8 ), p-O-β-D -glucosyl-trans-cafeoyl-2′′-isoorientin ( 9 ) and three xanthones: gentioside ( 10 ), isogentisine ( 11 ), mangiferin ( 12 ), have been identified from leaves of Gentiana X marcailhouana RY . Compounds 8 and 9 were described for the first time. The cyclitol L -(+)-bornesitol ( 13 ) has been also isolated. 相似文献
42.
43.
Mach Nguyet Minh 《Mathematische Nachrichten》2014,287(11-12):1341-1362
We show that under some appropriate assumptions, every weak solution (e.g. energetic solution) to a given rate‐independent system is of class SBV, or has finite jumps, or is even piecewise C1. Our assumption is essentially imposed on the energy functional, but not convexity is required. 相似文献
44.
45.
α-n-amylcinnamaldehyde (jasminaldehyde) was obtained with 82 % yield by solid-liquid phase transfer catalysis without solvent within 3 days at room temperature. By use of domestic microwave irradiation, the same yield was obtained within 1 minute at a power of 600 W. 相似文献
46.
47.
H. T. Hoang A. A. Sertsova S. I. Marakulin E. N. Subcheva M. P. Zaitseva E. V. Yurtov 《Russian Journal of Inorganic Chemistry》2018,63(11):1414-1418
MgO@SiO2 core–shell nanoparticles were manufactured, and a synthetic protocol was developed to prepare MgO nanoparticles where the SiO2 shell thickness was less than 10 nm. The influence of synthesis parameters on the formation of MgO@SiO2 nanoparticles was studied. The fact of a SiO2 shell being formed on the MgO surface was established and the sizes of the thus-prepared MgO@SiO2 nanoparticles were determined by TEM and Fourier-transform IR spectroscopy. 相似文献
48.
Energy management in buildings is addressed in this paper. The energetic impact of buildings in the current energetic context
is first depicted. Then the studied optimization problem is defined as the optimal management of production and consumption
activities in houses. A scheduling problem is identified to adjust the energy consumption to both the energy cost and the
inhabitant’s comfort. The available flexibilities of the services provided by domestic appliances are used to compute optimal
energy plans. These flexibilities are associated to time windows or heating storage abilities. A constraints formulation of
the energy allocation problem is given. A derived mixed linear program is used to solve this problem. The energy consumption
in houses is very dependent to uncertain data such as weather forecasts and inhabitants’ activities. Parametric uncertainties
are introduced in the home energy management problem in order to provide robust energy allocation. Robust linear programming
is implemented. Event related uncertainties are also addressed through stochastic programming in order to take into account
the inhabitant’s activities. A scenario based approach is implemented to face this robust optimization problem. 相似文献
49.
Dr. Minh T. Nguyen Dr. Matthew D. Krzyaniak Dr. Magdalena Owczarek Dr. Daniel P. Ferris Prof. Michael R. Wasielewski Prof. J. Fraser Stoddart 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(21):5889-5894
We report the synthesis of a tetracationic macrocycle which contains two N,N′-bis(methylene)naphthalenediimide units inserted in between the pyridinium rings of the bipyridinium units in cyclobis(paraquat-p-phenylene) (CBPQT4+ or “blue box”) and describe the investigation of its potential use in materials for organic electronics. The incorporation of the two naphthalenediimide (NDI) units into the constitution of CBPQT4+, not only changes the supramolecular properties of the tetracation in the solid state, but also has a profound influence on the electrochemical and electronic behavior of the resulting tetracationic macrocycle. In particular, the solid-state (super)structure, investigated by single-crystal X-ray diffraction, reveals the formation of a three-dimensional (3D) supramolecular framework with ca. 2.8 nm diameter one-dimensional (1D) hexagonal channels. Electrochemical studies on solid-state thin films of the macrocycle show that they exhibit semiconducting properties with a redox-conductivity of up to 7.6×10−4 S m−1. Moreover, EPR and ENDOR spectroscopies show that charge is equally shared between the NDIs within the one-electron reduced state of the NDI-based macrocycle on the time scale of these techniques. 相似文献
50.
Ngoc Anh Dung Do Izabela Ewa Nielsen Gang Chen Peter Nielsen 《Annals of Operations Research》2016,242(2):285-301
Emissions from idle truck engines are a main source of pollution at container terminals. In this study, we focus on reducing such emission from waiting trucks as well as the related crane operations with a new truck arrival control method that gives individual truck limited time slots for entry. We develop a method to optimize the time slot assignment for individual trucks, aiming at minimizing total emissions from trucks and cranes at import yards. The method applies discrete event simulation to estimate total truck waiting times and crane moving distance, and then applies a genetic algorithm to minimize the generated emissions from these trucks and cranes. The experiment result shows that the truck arrivals should be controlled based on the stacking of import containers, and that such control is necessary for reducing truck idling emissions at a congested container terminal. 相似文献