Action des Hydrazines Fluoroalkylées Sur Les α-Cetophosphonates: Synthèse des Hydrazones α-Phosphonylées N-Fluoroalkylées

In the present work, we study the reaction of fluorinated hydrazines H ₂ N-NHR _F with α-ketophosphonates 1, which lead to N-fluoroalkylated α-phosphonylated hydrazones 2. The stereochemistry of the hydrazones 2 was determined by multinuclear NMR experiments ( ¹ H, ¹³ C, ¹⁹ F, and ³¹ P) and IR spectroscopy.     

Ni/TiO_2-SiO_2上光催化重整葡萄糖以低CO选择性制H_2(英文)

Nano-sized Ni particles on TiO2-SiO2 were synthesized by the two methods of photo-assisted deposition(PAD) and impregnation.H2,which is a promising energy carrier,with a low CO concentration was produced by the photocatalytic reforming of glucose(a model biomass) on the Ni/TiO2-SiO2 catalyst.The supported Ni enhanced the rate of H2 production while it suppressed CO selectivity.The catalysts were characterized by X-ray diffraction,X-ray absorption fine structure,transmission electron microscope,and nitrogen adsorption analysis.Both H2 production and CO selectivity were strongly dependent on the preparation method,and PAD-Ni/TiO2-SiO2 was the better catalyst for H2 production with the lowest CO concentration.     

基于光电振荡器的宽带射频下转换及在高清视频传输的应用

以无压缩全高清视频的光载无线传输为背景,通过研究宽带射频光子下转换技术,从而构建全高清视频的实时传输系统,其中下转换系统主要基于光电振荡器实现.由于光电振荡器的注入锁定,光微波信号中的载波信号被提取出来,并反馈至调制器,与宽带光微波信号混频,在光域实现信号下转换.实验论证了载频为10GHz,码率大于2Gb/s的信号下转换和有线无线传输.利用天线和光纤实现了距离为0.5m的无线分发和距离为10km的有线传输.本文还成功实现了1.5Gb/s无压缩高清视频信号的实时传输.实验结果表明,该系统具有大带宽、抗电磁干扰等优点,同时利用光电振荡器的自动相位跟踪技术,无须外加锁相等操作.整个下转换系统简单稳定,为高清视频的有线无线传输提供了论证和演示平台.     

Common tripled fixed point results in cone metric type spaces

In this paper, we prove some common tripled fixed point and tripled coincidence point results for contractive conditions in a cone metric type space. Our results extend, unify and generalize well-known results in the literature, in particular the recent results of Aydi et al. (Fixed Point Theory Appl 2012:134, 2012). Some examples are also presented to validate our obtained results and new concepts.     

Positive Solutions of Nonlinear Elliptic Problem in a Non-Smooth Planar Domain

We find and prove 3G inequalities for the Laplacian Green function with the Dirichlet boundary condition, which are applied to show the existence of positive continuous solutions of the nonlinear equation Δu-Vu=g（·,u）, where V and g are Borel measurable functions, required to satisfy suitable assumptions related to a new functional class J. Our approach uses the Schauder fixed point theorem.     

Hybrid nanocomposites for optical applications

Incorporating inorganic particles into conjugated polymer matrices is an area of current interest in the fields of optoelectronics and solar energy. The hybrid nanocomposites exhibit interesting physical properties thanks to good optical properties of polymers and to high carrier mobility of inorganic semiconductors. A judicious combination of organic/inorganic can therefore provide materials of low cost, ease processing, high stability, with specific electrical and optical properties.In the present study, we briefly review the composite materials that have been successfully utilized in the field of optoelectronics and photovoltaic conversion. We shall describe in particular a family of nanocomposites using polyhedral oligomeric silsesquioxanes (POSS) of general formula (RSiO_3/2)n where R is an organic group as a core. The composites are made by grafting functional polymer groups to the core, which allows the control of their optical properties. Such composites have high mechanical resistance and stability because of the special structure of the core. For illustration, we present a study of polyfluorene (PF)/POSS materials used as an active layer in organic light emitting diodes, with improved performance as compared to those using polymer only, and we discuss the role of the particles in the transport and emission processes in the devices studied.     

Optimization of the separation conditions of tetracyclines on a preselected reversed-phase column with embedded urea group

The use of a C12 stationary phase with embedded polar group has been investigated for the separation of seven tetracyclines. The influence of pH, organic modifier, buffer, and temperature on the peak shape and analyte separation was discussed. It appears that all the chromatographic conditions had a great effect on both the resolution and peak shape whereas the elution order was not affected. The baseline separation with symmetrical peaks of the seven tetracyclines can be obtained with a mobile phase containing either 5 mM phosphate buffer pH 2.5/ACN (84:16 v/v) or 5 mM perchlorate buffer pH 2.5/ACN (75:25 v/v) at a temperature not exceeding 20 degrees C. This study reveals that the retention mechanism is ion-pairing.     

Facile synthesis of controlled‐structure primary amine‐based methacrylamide polymers via the reversible addition‐fragmentation chain transfer process

We report here a novel direct method for the syntheses of primary aminoalkyl methacrylamides that requires mild reagents and no protecting group chemistry. The reversible addition‐fragmentation chain transfer polymerization (RAFT) of the aminoalkyl methacrylamide revealed to be highly efficient with 4‐cyanopentanoic acid dithiobenzoate (CTP) as chain transfer agent and 4,4′‐azobis(4‐cyanovaleric acid) (ACVA) as initiator. Cationic amino‐based homopolymers of reasonably narrow polydispersities (M_w/M_n < 1.30) and predetermined molecular weights were obtained without recourse to any protecting group chemistry. A range of block and random copolymers were also synthesized via the RAFT process. The homopolymers and copolymers were characterized by aqueous conventional and triple detection gel permeation chromatography systems. Furthermore, the primary amine‐based methacrylamide monomers and polymers revealed to be highly stable both with the primary amino group in the protonated and deprotonated form. We have also demonstrated that stabilized gold nanoparticles can be generated with the RAFT‐synthesized amine‐based polymers via a photochemical process. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 4984–4996, 2008     

A novel and convenient strategy for the synthesis of phthalazines from an aryne precursor

A novel three-step entry toward phthalazine derivatives has been elaborated. A strategy based on a sequential acyl-alkylation/diazo transfer reaction/Diaza-Wittig reaction led to the desired analogues in moderate to good yields from an aryne precursor. Various aryl groups were introduced on the annulated pyridazine, moreover the presence of an ester group allows further modifications.     

Synthesis of α-Alkylidene-β-Ethoxycarbonyl Cyclopentanones and -γ-Butyrolactones

Synthesis of (E,Z)-α-Alkylidene-β-ethoxycarbonyl cyclopentanones 5 and (E,Z)-α-alkylidene-γ-butyrolactones 7 by condensing phosphonates 3 or 6 with a variety of aldehydes in the presence of aqueous potassium carbonate (6-10M) as base is reported.