Geometric aspects of transversal Killing spinors on Riemannian flows

We study a Killing spinor type equation on spin Riemannian flows. We prove integrability conditions and partially classify those flows carrying non-trivial solutions.      

Boundary voltage perturbations caused by small conductivity inhomogeneities nearly touching the boundary

We establish an asymptotic expansion of the steady-state voltage potentials in the presence of a diametrically small conductivity inhomogeneity that is nearly touching the boundary. Our asymptotic formula extends those already derived for a small inhomogeneity far away from the boundary and is expected to lead to very effective algorithms, aimed at determining location and certain properties of the shape of a small inhomogeneity that is nearly touching the boundary based on boundary measurements. Viability of the asymptotic formula is documented by numerical examples.     

Efficient way for detection of alcohols using hollow core photonic crystal fiber sensor

Optical Review - In this study, a simple hollow core hexagonal structured photonic crystal fiber is offered and analyzed to discern commonly used different type of alcohols in our daily life. The...     

Determination of Chromium (VI) in Airborne Particulate Matter by Electrothermal Atomic Absorption Spectrometry

Hexavalent chromium Cr(VI) is a well-established carcinogen associated with lung, nasal, and sinus cancer. Cr(VI) threshold limit values in workroom air have been recently lowered. Consequently, the currently available analytical methods are insufficiently sensitive or high cost. In this paper, a simple, cost-effective, sensitive, and reproducible method using solid-phase extraction with electrothermal atomic absorption spectrometry for determination of hexavalent chromium in airborne samples is reported. The method validation included selectivity, linearity, accuracy, and precision. Interferences from other ions likely to be present in airborne samples, including trivalent chromium, were tested and selectivity was demonstrated. The detection and quantification limits were, respectively, as low as 0.1 and 0.4?µg?L^?1. The linearity ranged from 0.5 to 50.0?µg?L^?1, with a regression coefficients exceeding 0.998. The extraction recovery exceeded 98%. The developed method was successfully compared with a reference spectrophotometric method. The performances achieved were similar to ion chromatography and high-performance liquid chromatography approaches. The novel method was tested on airborne samples collected from the workplace. The method’s performance suggests that it may be an alternative to high-cost techniques for monitoring occupational exposure to hexavalent chromium.     

Comparative Evaluation of Six Electrolyte Local Composition Activity Coefficient Models Applied to Binary Aqueous Solutions of Ionic Liquids

The capability of six popular local composition models including electrolyte NRTL, modified electrolyte NRTL, electrolyte NRTL–NRF, electrolyte Wilson, modified electrolyte Wilson, and electrolyte NRF–Wilson models to predict the activity coefficients of ionic liquids in aqueous solutions was examined by correlating the experimental data of 16 ionic liquids available in the literature. The adjustable parameters and standard deviations of the fit were estimated for all of these models. Results indicate that the modified electrolyte Wilson model represents the activity coefficients with higher precision.     

Iron,copper and zinc ammonium-1-hydroxyalkylidene-diphosphonates with zero-, one- and two-dimensional covalent metal–ligand structures extended into three-dimensional supramolecular networks by charge-assisted hydrogen-bonding

Hydrothermal synthesis with MCl₂ (M = Fe, Cu, and Zn) and disodium 5-ammonium-1-hydroxypentylidene-1,1-bisphosphonate, (Na⁺)₂[⁺H₃N(CH₂)₄C(OH)(PO₃²⁻)(PO₃H⁻)] (Na₂HAC₅OHP₂) or sodium 3-ammonium-1-hydroxypropylidene-1,1-bisphosphonate hydrate, Na⁺[⁺H₃N(CH₂)₂C(OH)(PO₃H^–)(PO₃H^–)]·H₂O (NaH₂PAM·H₂O) the sodium salt of pamidronic acid, H₃PAM) yielded the one-dimensional (1D) iron, molecular copper and two-dimensional (2D) zinc compounds 1D-{[Fe(μ₃-η⁵-HAC₅OHP₂)]·H₂O}, 1, [Cu(η²-H₂AC₅OHP₂)₂], 2, 2D-{[Zn₂(μ₅-η⁷-AC₅OHP₂)Cl], 3, and 2D-{[Zn(μ₂-η³-H₂PAM)₂], 4, respectively. The bisphosphonate ligand bridges (μ_n) between 2–5 metal atoms and uses 2–7 oxygen donor atoms towards metal coordination (ηⁿ). The zwitterionic nature of the now bis- or tetrakis-deprotonated ammonium–bisphosphonate is retained in the metal complexes. From the reaction of NiCl₂ and Na₂HAC₅OHP₂ the zwitterionic 5-ammonium-1-hydroxypentylidene-1-phosphonic acid, ⁺H₃N(CH₂)₄CH(OH)PO₃H⁻, 5 was obtained as a product of the ligand P–C bond hydrolysis. Adjacent strands, molecules or layers in 1–4, respectively are organized through the Coulomb attraction between the positive ammonium group and the negative phosphonate groups, supported by hydrogen-bonding. Each protic H atom on the C–OH, NH₃⁺ and –PO₃H⁻ group is involved in charge-assisted hydrogen-bonding. The ammonium-pentylidene groups act as hydrophobic separators between the hydrophilic units with the polar M{C(OH)(PO₃)₂} and {NH₃} units. Bond valence sum calculations support the Fe(II) oxidation state in 1, which was experimentally determined from a quantitative polarographic Fe(II)/Fe(III) speciation analysis as well as a temperature variable magnetic study.     

New concept of failure of thin organic films

A critical (steady state) value of the thermal expansion coefficients of different coatings was determined by a nondestructive technique (NDT) known as laser shearography. The behavior of organic coatings, i.e., ACE premium-grey enamel, a yellow acrylic lacquer, and a gold nail polish on a metallic alloy, i.e., a carbon steel, was investigated over a temperature range of 20–60 °C. The value of the thermal expansion coefficients of coatings was derived from the slope of the plot of the thermal deformation (strain) versus the applied temperature. The integrity of the coatings with respect to time was assessed by comparison the measured coefficients of thermal expansion (CTE) to the critical (steady state) or asymptotic value of CTE. By shearography, measurement of coating properties could be performed independent of parameters such as UV exposure, humidity, presence of chemical species, and other parameters which may normally interfere with conventional methods of the assessing of the integrity of coatings. Therefore, one may measure CTE of coatings, regardless of the history of the coating, in order to assess the integrity of coatings. Also, the obtained shearography data were found to be in a reasonable trend with the data of electrochemical impedance spectroscopy (EIS) in 3%NaCl solution.     

A nonlocal Levinson beam model for free vibration analysis of zigzag single-walled carbon nanotubes including thermal effects

A nonlocal Levinson beam model is developed to study the free vibrations of a zigzag single-walled carbon nanotube (SWCNT) in thermal environments. The equivalent Young’s modulus and shear modulus for a zigzag SWCNT are derived using an energy-equivalent model. The present study illustrates that the vibration characteristics of an SWCNT are strongly dependent on the temperature change and on the chirality of a zigzag carbon nanotube. The investigation of the chirality and temperature effects on free vibration of carbon nanotubes may be used as a useful reference for the application and the design of nanoelectronic and nanodrive devices, nano-oscillators, and nanosensors, in which carbon nanotubes act as basic elements.     

A 3D numerical simulation of mixed convection of a magnetic nanofluid in the presence of non-uniform magnetic field in a vertical tube using two phase mixture model

In this paper, results of applying a non-uniform magnetic field on a ferrofluid (kerosene and 4 vol% Fe₃O₄ ) flow in a vertical tube have been reported. The hydrodynamics and thermal behavior of the flow are investigated numerically using the two phase mixture model and the control volume technique. Two positive and negative magnetic field gradients have been examined. Based on the obtained results the Nusselt number can be controlled externally using the magnetic field with different intensity and gradients. It is concluded that the magnetic field with negative gradient acts similar to Buoyancy force and augments the Nusselt number, while the magnetic field with positive gradient decreases it. Also with the negative gradient of the magnetic field, pumping power increases and vice versa for the positive gradient case.