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41.
合成了Fe3O4@Au磁性纳米粒子,并根据单链寡聚核苷酸(ss-DNA)杂交原理,利用量子点电化学发光,构建了DNA电化学传感器.在磁控玻碳电极(MCGCE)表面,将5′-SH-ssDNA捕获探针自组装在Fe3O4@Au磁性纳米粒子上,然后与目标DNA互补的一端杂交形成dsDNA,再与双标记了量子点的5′-NH2-ssDNA-NH2-3′信号探针杂交形成三明治杂交的DNA.应用循环伏安法对DNA的固定与杂交进行了表征.目标DNA浓度在1.0×10-13~1.0×10-11 mol/L范围与其响应的ECL信号呈线性关系,检出限为1.8×10-14mol/L.由于采用量子点双标记法,检测的灵敏度显著提高. 相似文献
42.
设π是一个素数集合Isaacs建立了特征标π-理论,推广了Brauer模特征标理论.基于Isaacs的工作,定义了M_π-群,推广了M_p-群的概念,证明了若G是一个有限π-幂零群,则G是M-群当且仅当G是M-群. 相似文献
43.
采用共沉淀耦合机械混合法制备了Cu/ZnO/Al2O3/Cr2O3+H-ZSM-5双功能催化剂,并用于二甲醚水蒸气重整制氢反应,结合热重、傅里叶红外光谱、XRD、BET、H2-TPR表征,考察了焙烧温度对Cu/ZnO/Al2O3/Cr2O3催化剂物理化学性质及双功能催化剂催化性能的影响。研究结果表明,400℃焙烧时,析出CuO粒子的同时伴有尖晶石相,进而在反应过程中对金属铜粒子起到良好的隔离作用。而焙烧温度较低时,催化剂分解不完全,催化剂活性位较少。焙烧温度大于500℃时,CuO粒子发生二次团聚,同时尖晶石相大量生成,造成催化剂活性位减少,活性较低。合适的焙烧温度为400℃,此时二甲醚转化率为92.9%,氢气收率可达到76.5%,具有较好的反应效果。 相似文献
44.
CdMoO(4):Mn nanocrystals with a tetragonal crystal structure were prepared by aqueous coprecipitation method at a low temperature of 2 °C under different pH values. The size of the CdMoO(4):Mn nanocrystals of spherical morphology increases with the Mn dopant concentration from 35 to 55 nm for pH = 4. The morphology could be tuned from nanocrystals to microstructures consisting of smaller nanoparticles by the Mn concentration when the pH value of the precursor was increased to 8. The thermal stability of the luminescence and magnetic properties of the Mn-doped samples also depend on the pH and the doping level. The effects of the pH and dopant on the luminescence and magnetic properties, including magnetic susceptibility and electron paramagnetic resonance, were investigated. This approach contributes to better understanding of aqueous chemistry methods to control the growth of nanocrystals. 相似文献
45.
Quantum Signatures of Chaos in Adiabatic Interaction Between a Trapped Ion and a Laser Standing Wave
LI Hui HAI Wen-Hua XU Jun 《理论物理通讯》2008,49(1):143-152
We study quantum motion around a classical heteroclinic point of a single trapped ion interacting with a strong laser standing wave. We construct a set of exact coherent states of the quantum system and from the exact solutions reveal that quantum signatures of chaos can be induced by the adiabatic interaction between the trapped ion and the laser standing wave, where the quantum expectation values of position and momentum correspond to the classically chaotic orbit. The chaotic region on the phase space is illustrated. The energy crossing and quantum resonance in time evolution and the exponentially increased Heisenberg uncertainty are found. The results suggest a theoretical scheme for controlling the unstable regular and chaotic motions. 相似文献
46.
Theoretical analysis of the DNA dynamics reveals that interaction between the single solitons and plane wave implies Smale-horseshoe chaos in the double helices. Solutions of the chaotic solitons are derived from a direct perturbation technique. It is demonstrated that to produce the bounded chaotic solitons, velocities of the solit ons nust be the same and equal to propagation velocity of the plane wave in DNA. The result shows that the DNA structure may be destroyed by the long action of an electromagnetic wave. It also supplies a useful method for controlling the velocities and unboundedness of the DNA motion in a tumour cell by using a plane wave.`` 相似文献
47.
LIFei HAIWen-Hua CHONGGui-Shu XIEQiong-Tao 《理论物理通讯》2004,42(4):599-604
A classically chaotic system consisting of a Paul trapped ion and a sequences of standing laser pulses is treated quantum-mechanically. Under the circumstance of time-dependence, we derive the transition probability from the ion‘s motional state n to n‘, and find, in the first-order approximation, the classically chaotic character disappears.Theoretical analysis and numerical calculations show that by regulating the phase parameter Ф we can control thetransition probability. When Ф reaches some specific values, the transition from the state n to n‘ is forbidden and, for some laser periods, resonance occurs, which leads to the corresponding transitions between different motional states.The time-evolution of an initial motional state |ψz) just over one period is also studied in detail. 相似文献
48.
本文使用π-special特征标和Bπ-特征标的一些性质,给出了有限群有正规π-补的一些条件,我们的结果推广了一些著名的定理。 相似文献
49.
50.
A classically chaotic system consisting of a Paul trapped ion and a sequences of standing laser pulses is treated quantum-mechanically. Under the circumstance of time-dependence, we derive the transition probability from the ion‘s motional state n to n‘, and find, in the first-order approximation, the classically chaotic character disappears.Theoretical analysis and numerical calculations show that by regulating the phase parameter φ we can control the transition probability. When φ reaches some specific values, the transition from the state n to n‘ is forbidden and, for some laser periods, resonance occurs, which leads to the corresponding transitions between different motional states. 相似文献