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991.
Haojing Song Jin Wang Rui Zhang Xiaoyan Liu Guiyan Yuan Chunmin Wei Wenjing Zhao Rong Li Benjie Wang Ruichen Guo 《Biomedical chromatography : BMC》2013,27(11):1398-1405
Bergenin is the major component of Ardisia creanta sims and Rodgersia sambucifolia hemsl with many biological activities. Although bergenin has been used to treat human diseases in China for man years, there is no report regarding its metabolism. This is the first report to separate and identify the metabolites of bergenin in vivo. In the study, HPLC/Q‐TOF‐MS/MS was used to investigate the metabolites of bergenin in vivo by analyzing the rat body fluid and feces samples. Three metabolites of bergenin were finally identified by the TIC chromatograms, and the structures were also confirmed by their MS2 spectra. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
992.
Xiaotian Li Baoluo Wan Tong Yu Linxi Wang Lianqi Hao Maowen Guo 《Biomedical chromatography : BMC》2013,27(12):1595-1602
A reversed‐phase ion pair chromatography method with liquid–liquid extraction analytical method was developed and validated for the determination of antazoline hydrochloride in plasma and excreta of rat. The aim of our study was to characterize the preclinical pharmacokinetics and excretion profiles of antazoline hydrochloride in rats after intravenous injection at the dose of 10 mg/kg. Plasma and excreta samples were extracted with ethyl acetate, and phenacetin was used as the internal standard. The result showed that the method is suitable for the quantification of antazoline hydrochloride in plasma and excreta samples. Analysis of accuracy (90.89–112.33%), imprecision (<7.1%) and recovery (>82.5%) showed adequate values. After a single intravenous administration at 10 mg/kg to rats, plasma concentration profile showed a relative fast elimination proceeding with a terminal elimination half‐life of 3.53 h. Approximately 61.8 and 14.2% of the administered dose were recovered in urine and bile after 72 and 24 h post‐dosing respectively; 5.9% of the administered dose was recovered in feces after 72 h post‐dosing. The above results show that the major elimination route is urinary excretion. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
993.
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995.
We consider the algebraic Riccati equation for which the four coefficient matrices form an M-matrix K. When K is a nonsingular M-matrix or an irreducible singular M-matrix, the Riccati equation is known to have a minimal nonnegative solution and several efficient methods are available to find this solution. In this paper we are mainly interested in the case where K is a reducible singular M-matrix. Under a regularity assumption on the M-matrix K, we show that the Riccati equation still has a minimal nonnegative solution. We also study the properties of this particular solution and explain how the solution can be found by existing methods. 相似文献
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997.
Hongxia Guo Yuechun Qiao Guohua Liu Jingqing Gao 《Russian Journal of Electrochemistry》2013,49(4):396-399
Single-phased nanosized LiFePO4 with thinner thickness along [010] crystallographic direction were successfully fabricated under solvothermal condition by using glycerol as co-solvent. The as-obtained product with thinner thickness is beneficial for fast migration of Li ions in the olivine-structured LiFePO4, hence exhibiting excellent electrochemical performance. 相似文献
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999.
Journal of Radioanalytical and Nuclear Chemistry - Based on the newly-developed techniques, the transfer behaviors of 90Sr and 137Cs under natural conditions were studied. The concentrations of... 相似文献
1000.
Zongxia Guo Yubao Song Ruiying Gong Youbing Mu Yi Jiang Ming Li 《Supramolecular chemistry》2013,25(5-6):383-391
Biomolecule-directed self-assembly of π-conjugated oligomers has attracted great attention in the past decade. In this contribution, two conjugates composed of quaterthiophene and tetrapeptide (Gly-Val-Gly-Val) were synthesised, namely peptide–thiophene–peptide (PTP) and thiophene–peptide–thiophene (TPT), to investigate the influence of peptide content ratio and its location in the molecular structures on the nanostructures and properties of the assemblies. Both conjugates formed organogels consisting of left-handed twisted nanostructures; however, anti-parallel β-sheets were observed in PTP while parallel β-sheets were obtained for TPT, although in both cases oligothiophenes adopted an H-like stacking mode. Obvious solvent-induced supramolecular chirality inversion from the oligothiophene segment was observed for PTP while such phenomenon was not clear for TPT. PTP and TPT gels also showed different stabilities towards temperature increase, as evidenced by variable-temperature circular dichroism study. From the data, it is suggested that the rational design of the location and ratio of peptide plays a key role in constructing materials with determined properties based on peptide–thiophene conjugates. 相似文献