LB膜的XPS光谱及其电致发光

采用X射线光电子能谱 (XPS)和UV Vis光谱研究了 2个以 8 氨基喹啉为亲水头基的两亲配体 ;2 长链烷基丙二酸二 (8 氨基喹啉 )酰胺 (H2 A) (H2 A1 2 :长链烷基为十二烷基 ;H2 A1 6 :十六烷基 )在气 /水界面与Cu2 离子的配位作用。配位后H2 A1 2 和H2 A1 6 单分子膜的崩溃压分别由 12 5和 15 6mN·m- 1 增加至 2 8 0和33 8mN·m- 1 。从含Cu2 离子亚相表面组装的LB膜出现了Cu2 离子的特征XPS峰 ,Cu2p为 935和 95 5eV ,XPS表明H2 A与Cu2 的配位比为 1∶1。H2 A的LB膜可以用作电致发光 (EL)器件的空穴传输材料 ,三层EL器件ITO/TPD/LB膜 /Alq3/Al(LB膜分别为 15层H2 A1 2 和 15层H2 A1 6 )的驱动电压分别为 6 5和 7 5V ,最大亮度分别为 6 2 1和 2 0 1cd·m- 2 。     

Growth and studies of Hg1−xCdxTe based low dimensional structures

The band structure of HgTe quantum wells (QWs) has been determined from absorption experiments on superlattices in conjunction with calculations based on an 8×8 k·p model. The band structure combined with self-consistent Hartree calculations has enabled transport results to be quantitatively explained.Rashba spin–orbit, (SO) splitting has been investigated in n-type modulation doped HgTe QWs by means of Shubnikov–de Haas oscillations (SdH) in gated Hall bars. The heavy hole nature of the H1 conduction subband in QWs with an inverted band structure greatly enhances the Rashba SO splitting, with values up to 17 meV.By analyzing the SdH oscillations of a magnetic two-dimensional electron gas (2DEG) in modulation-doped n-type Hg_1−xMn_xTe QWs, we have been able to separate the gate voltage-dependent Rashba SO splitting from the temperature-dependent giant Zeeman splitting, which are of comparable magnitudes. In addition, hot electrons and Mn ions in a magnetic 2DEG have been investigated as a function of current.Nano-scale structures of lower dimensions are planned and experiments on sub-micrometer magneto-transport structures have resulted in the first evidence for ballistic transport in quasi-1D HgTe QW structures.     

The autocorrelation of speckles in deep Fresnel diffraction region and characterizations of random self-affine fractal surfaces

This paper studies the correlation properties of the speckles in the deep Fresnel diffraction region produced by the scattering of rough self-affine fractal surfaces. The autocorrelation function of the speckle intensities is formulated by the combination of the light scattering theory of Kirchhoff approximation and the principles of speckle statistics. We propose a method for extracting the three surface parameters, i.e. the roughness w, the lateral correlation length ξ and the roughness exponent α, from the autocorrelation functions of speckles. This method is verified by simulating the speckle intensities and calculating the speckle autocorrelation function. We also find the phenomenon that for rough surfaces with α= 1, the structure of the speckles resembles that of the surface heights, which results from the effect of the peak and the valley parts of the surface, acting as micro-lenses converging and diverging the light waves.     

HgTe/HgCdTe量子阱中巨大电子Rashba自旋分裂

主要研究具有倒置能带结构的n-HgTe/HgCdTe第三类量子阱Shubnikov-de Haas（SdH）振荡中的拍频现象.发现在量子阱中电子存在强烈的Rashba自旋分裂，通过对SdH振荡进行三种不同方法的分析：SdH振荡对1/B关系的快速傅里叶变换、SdH振荡中拍频节点分析和对SdH振荡拍频数值拟合，得到了完全一致的电子Rashba自旋分裂能量（28—36 meV）. 关键词： n-HgTe/HgCdTe Shubnikov-de Haas振荡 Rashba自旋分裂     

Effect of Bi-substitution on the dielectric properties of polycrystalline yttrium iron garnet

The effect of Bi-substitution on the dielectric properties of yttrium iron garnet (YIG) was studied in this paper. The Bi-substituted YIG (YIG:Bi) polycrystalline samples, having composition of Y_3−xBi_xFe₅O₁₂, were prepared by the solid-state reaction method. x varied from 0 to 1.2. The phase formation and microstructure were performed by X-ray diffraction and scanning electron microscopy, respectively. Ions valency was identified by X-ray photoelectron spectroscopy. The impedance analyzers are used to measure the frequency dependence and the temperature dependence of relative dielectric constant (_r) and loss tangent (tan δ). The experimental results show that the Bi-substitution lowers the phase formation and sintering temperature. Electronic carrier concentration drops dramatically due to limitation of ferric valency variation. Hence, _r and tan δ decrease with addition of Bi. Dispersion characteristic indicates non-Debye-type dispersion. A maximum of _r appears as the temperature rises.     

红外光谱中取代基对苯环骨架振动吸收峰的影响规律

本文初步地探讨了单取代及对位双取代对苯环骨架振动吸收峰频率和强度的影响规律 ,得出结论 :1给电子单取代基随给电子能力增强使苯环骨架振动吸收峰 16 0 0 cm-1增强 ,而吸电子基则相反。 2卤素作为单取代基时 ,使苯环骨架伸缩振动产生强红外吸收峰 ;且随卤素电负性增强吸收峰频率向高波数移动。 3对位取代基为不同类型时 ,16 0 0 cm-1处显强峰 ,而为同一类型时 ,当电子效应相近或相同时 ,16 0 0 cm-1处吸收峰很弱或根本无吸收峰。并讨论了产生这些现象的原因。     

Synthesis and Structural Characterization of a Polyphosphazeneas Photoconductivc Material

n the past decades, photoconductive polymers have received much attention either from atlindamental standpoint or for their potential uses ]' 2. The photoconductivities of manypolymers have been reported, such as phenylmethylpolysilane, poly(pphenylenevinylene ), N-poly(vinylcarbazole ), and so on.Recently we have synthesized a novel polyphosphazene that contains chargetransporting agent for photoconductive application. Polyphosphazene was selectedbecause of its photochemical stability, the go…     

一类二次特征值反问题的中心对称解及其最佳逼近

1引言给定n阶实矩阵M,C和K,二次特征值问题:求数λ和非零向量x使得Q(λ)x=0, (1．1)其中Q(λ)=λ2M λC K称为二次束．数λ和相应的非零向量x分别称为二次束Q(λ)的特征值和特征向量．Tisseur和Meerbergen概述了二次特征值问题的各种应用、数学理论和数值方法．在工程技术,特别是结构动力模型修正技术领域经常遇到与二次特征值问题相反的问题(称之为二次特征值反问题)．对阻尼结构进行动力分析时,应用有限元方法可得到系统的质量矩阵M,阻尼矩阵C和刚度矩阵K,从而可求得二次特征值问题的特征值(频率)和特征向量(振型)．但是有限元模型毕竟是实际结构系统的离散化,并且     

Synthesis and Fluorescent Properties of New Binuclear Europiumβ-Diketone Chelates Eu_mY_(1-m)(TTA)_3phen as Red Electroluminescent Materials

Organicthinfilmelectr0luminescentdisplay(OTFELD)hasgoneintothestageofpracticalstudy'sincePioneerC0.reportedthefirstc0mmercialproductoforganicgreenELdispla}'usingSma1lm0lecules1.AsOTFELDhasmanyadvantagessuchasactiveemission-highbrightness.l0wdrivingv0ltage,wideviewingangle,Iightweight,andpotentiall0wcost,itisat-tractingmuchattenti0nasacandidatef0rnewflatpaneldisplay.However.therearemanysubjectst0realizethefullcol0rdisplays.The0rganicredandbIueELdisplaysarethebasicessentialt0reaIizefull…