CO_2 Reforming of CH_4 over Ni/CeO_2-ZrO_2-Al_2O_3 Prepared by Hydrothermal Synthesis Method

The Ni/CeO2-ZrO2-Al2O3 catalyst with different Al2O3 and NiO contents were prepared by hydrothermal synthesis method. The catalytic performance for CO2 reforming of CH4 reaction, the interaction among components and the relation between Ni content and catalyst surface basicity were investigated. Results show that the interaction between NiO and Al2O3 is stronger than that between NiO and CeO2-ZrO2.The addition of Al2O3 can prevent the formation of large metallic Ni ensembles, increase the dispersion of Ni, and improve catalytic activity, but excess Al2O3 causes the catalyst to deactivate easily. The interaction between NiO and CeO2 results in more facile reduction of surface CeO2. The existence of a small amount of metallic Ni can increase the number of basic sites. As metallic Ni may preferentially reside on the strong basic sites, increasing Ni content can weaken the catalyst basicity.     

Coriolis耦合对Cl+H2→H+HCl非绝热反应的影响

使用含时波包方法 ,在Capecchi和Werner拟合的非绝热耦合势能面上 ,研究了Cl处在自旋轨道基态以及自旋轨道激发态时与H2 反应的活性 ,并且讨论了Coriolis耦合的影响 .计算了某些角动量时的反应几率 .计算结果显示 ,当Cl原子处在自旋轨道激发态与处在基态的H2 的反应活性很小 ,Coriolis耦合在这个反应中起了很小的作用 .     

Influence of relaxation effects on probabilities of the 2s2p35S2－2s22p2 3P1，2 intercombination transitions in NII

Transition probabilities of the 2s2p^3 {}^5S_2－2s^22p^2 {}^3P_{1,2} intercombination transitions in NII have been calculated by using a large-scale multiconfiguration Dirac－Fock method. In the calculation the most important effects of relativity, correlation, and relaxation are considered. From the calculated transition probabilities, the lifetime of the 2s2p^3 {}^5S_2 metastable state is derived. The result is in excellent agreement with the latest experimental result. In the meantime the influence of anomalously strong relaxation effects on probabilities of the 2s2p^3 {}^5S_2－2s^22p^2 {}^3P_{1,2} lines in NII have been found.     

On the asymptotic behaviour of elliptic problems with periodic data

We study the asymptotic behaviour of the solution of elliptic problems with periodic data when the size of the domain on which the problem is set becomes unbounded. To cite this article: M. Chipot, Y. Xie, C. R. Acad. Sci. Paris, Ser. I 339 (2004).     

解非线性二阶双曲型方程的一种新数值方法

本文建立了解二阶双曲型方程的一种新数值方法一再生核函数法．利用再生核函数，直接给出每个离散时间层上近似解的显式表达式．此方法的优点是：计算格式绝对稳定，且可显式求解；利用显式表达式，可实现完全并行计算等文中对近似解的收敛性和稳定性进行了理论分析，并给出数值算例．     

一类非线性积分,微分方程的逼近解

在不主紧型条件和耗散型条件的情形下，得到了Ｂａｎａｃｈ空间中一类非线性积分，微分方程的逼近解。     

Development and applications of an on-line thermal neutron prompt-gamma element analysis system

This paper introduces the principles, instrumentation, implementation, and industrial applications of an on-line thermal neutron prompt-gamma element analysis system (using a²⁵²Cf neutron source, Am–Be neutron source, or neutron generator). The energy resolution of the system at the H prompt-gamma full-energy photopeak (2.22325 MeV) is 3.6 keV. The concentration measurement error of Al₂O₃, FeO₃, CaO, and SiO₂ is ±0.3%, ±0.1%, ±0.4%, and ±0.4%, respectively. The system has been tested on-site at both the Shandong and the Zhengzhou Aluminium Works. Our preliminary on-site measurements confirm that the stability, reliability, measurement range, and accuracy of the system can meet the requirements of the aluminium production process. Facilitation of this measurement at aluminium plants is expected to reduce plant costs by over 3 million dollars annually through reduced energy consumption, more rapid qualification of pulps being mixed during the production process, and in reduced labor costs.Other participants of Shandong and Zhenghou Aluminium Works are: Wang Aili, Zengshen, Dei Jianguo and Lu Jinnan, Wang Deyu, Jin Hequan.     

The layered compound poly[μ2‐4,4′‐bipyridyl‐di‐μ2‐chlorido‐mercury(II)]

The title compound, [HgCl₂(C₁₀H₈N₂)]_n, features two‐dimensional [HgCl₂(4,4′‐bipy)]_n neutral networks (4,4′‐bipy is 4,4′‐bipyridine), based on an octahedral Hg atom coordinated by four μ₂‐Cl atoms and two μ₂‐4,4′‐bipy ligands in trans positions, yielding a HgCl₄N₂ octahedron. The structure has mmm symmetry about the Hg atoms, with most of the atoms on at least one mirror plane, but the unsubstituted C atoms of the 4,4′‐bipy rings are disordered across a mirror plane. Photoluminescent investigations reveal that the title compound displays a strong emission in the green region, which probably originates from a ligand‐to‐ligand charge‐transfer transition.