A Simple Design to Realize Micro-column Separation by Conventional Analytical HPLC

The conventional analytical HPLC was successfully developed for micro‐column separation by using a simple eluate splitting system, self‐preparation of packing column and on‐capillary column detector in our laboratory. Porous inlet frit in fused silica capillary was rapidly prepared by sintering stainless steel powders under 500 meshes for about 20 s. The use of such frits or metal meshes in capillary to retain C₁₈ particles of chromatographic packing was demonstrated to be stable and specially robust with continuous packing and long chromatographic runs. Furthermore, the chromatographic behavior was detailedly evaluated by changing the flow rate and the percentage of mobile phase using the prepared capillary column. Under the optimal experimental conditions, baseline separation of the model analytes including thiourea, benzene, toluene, ethylbenzene was obtained with a high column efficiency near 70000N (plates/m) by the developed capillary‐HPLC.     

Determination of Average Wall Thickness of Mesoporous Silica

Mesoporous silica formed by the condensation of silica oligomers around self-assembled surfactant micelle templates has recently attracted much interest owing to its potential for use in catalytic or adsorbent applications1. Much attention has been focused on characterization of its pore structure by transmission electron microscopy (TEM), high-resolution TEM (HRTEM), N2 adsorption, small angle X-ray scattering (SAXS) et al., but seldom concerning its average wall thickness2-7. This shor…     

Synthesis and Antiproliferative Activity of Novel [1,2,4]Triazolo[1,5-a]pyrimidine-7-amine Derivatives

A series of novel N-anilino-2-substituted-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidine-7-amine derivatives was prepared and evaluated for their in vitro antiproliferative activity against two cancer cell lines,Bel-7402 and HT-1080.Most of the compounds inhibited the cell proliferation at a low concentration.Seven compounds,VI5,VI7,VI10,and VI12―VI15,possessed marked antiproliferative activity superior to that of cisplatin.Of these seven initial hits,compound VI10 was the most active.     

A Simple Loop for Simultaneous OTDM Demultiplexing and Clock Recovery

A simple and stable loop consisting of a pair of concatenated electroabsorption modulators （EAMs） and 10 GHz clock recovery module is presented and demonstrated experimentally for simultaneous demultiplexing and clock recovery for OTDM networks. The 10 Gb/s demultiplexed signal and 10 GHz recovered clock are successfully implemented from 80 Gbit/s and 160 Gbit/s OTDM signals utilizing the loop. The loop based on EAM-PLL can provide excellent tolerance range （〉 5 dB） of the OSCR of the source laser, and the recovered clock signal exhibits low rms jitter over a dynamic input optical power range of 15 dB.     

新型制冷剂的研究现状及应用前景

本文提出近自然工质的定义.发达国家环境日益恶化,美国率先研发用以替代汽车空调常用的R134a的新型制冷剂,并已在多个国家进行了替代测试实验.文章简述了一种制备此制冷剂的方法.通过对比分析几种常用汽车空调制冷剂的系统循环性能,指出在新旧制冷剂的替代过程中,我国应采用适合的过渡替代工质,并鼓励自主研发适用于我国的新型制冷剂.新型制冷剂的发展方向将是近自然工质和直接采用自然工质.     

高压下TATB压缩性质的LDA和GGA比较研究

本文采用第一性原理密度泛函理论,结合平面波赝势方法,采用局域密度近似(LDA)和广义梯度近似(GGA)两种方法计算了TATB晶体在高压(0~7 GPa)压缩下的结构和物理性质,并与实验数据进行了比较.详细讨论了TATB晶体的晶体结构和分子构型随压力的变化.     

超高速摄影中弹性支撑转镜的模态分析

 提出了超高速摄影仪中弹性支撑转镜模态分析方法，利用有限元法对三面体铝合金转镜刚性支撑和弹性支撑情况下的一、二阶模态进行模拟，结果表明：电驱动转镜在转速工作范围内只有2个临界点，分别位于2.5×10⁵~2.6×⁵ r/min和2.6×10⁵~2.7×10⁵ r/min处， 并且均为一阶弯曲振动，一阶模态振动发生在垂直平面内，二阶发生在水平平面内。将模拟结果与实测值进行了比较，发现假设转镜为弹性支撑与实测值吻合得较好。     

顽火辉石(Mg0.92,Fe0.08)SiO3的冲击相变和高压状态方程及其地球物理意义

 用阻抗匹配法和电探针技术在48~140 GPa冲击压力范围内对化学组分为(Mg_0.92, Fe_0.08)SiO₃、初始密度为3.06 g/cm³的天然顽火辉石进行了冲击压缩实验。根据本工作13发实验数据，结合McQueen等人的数据可以看出，(Mg_0.92, Fe_0.08)SiO₃顽火辉石在冲击压缩过程中，大约经历三个明显区域：低压相区，压力范围为0~40 GPa；混合相区，压力范围为40～67 GPa；高压相区，压力范围为68～140 GPa。在低压相区，D-u关系已由McQueen给出；而在高压相区（68～140 GPa），可由本实验数据得到。由叠加原理计算得到的混合物(Mg_0.92, Fe_0.08)O(Mw)+SiO₂(St)的D-u关系及p-ρ关系曲线明显偏离了实验数据的拟合曲线，从而排除了在高达140 GPa冲击压力下，钙钛矿结构的(Mg_0.92, Fe_0.08)SiO₃发生向氧化物化学分解相变的可能性。对高压相区的实验数据进行拟合，可以得到(Mg_0.92, Fe_0.08)SiO₃钙钛矿的Grüneisen参数γ。通过三阶Birch-Murnaghan有限应变状态方程，由冲击波实验数据得到了零压等熵体积模量K_0S=259.6(9) GPa及其对压力的一阶偏导数K′_0S=4.20(5)，其ρ₀=4.19 g/cm³。(Mg_0.92, Fe_0.08)SiO₃钙钛矿冲击压缩下的密度数据与PREM密度剖面吻合很好，支持钙钛矿为主要成分的下地幔模型。