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81.
Using ab initio calculations, we have studied Sc2AC with A=Al, Ga, In and Tl. We show that C 2p and Sc 3d as well as A p and Sc 3d states are hybridized, but the antibonding states in the vicinity of the Fermi level weaken the overall bonding. In terms of the chemical bonding, the influence of the size of the A element is minute. Furthermore, the bulk modulus of the corresponding binary transition metal carbide is not conserved in these phases. Therefore, Sc2AC can be classified as weakly coupled MAX phases according to Sun and co-workers [Z. Sun, D. Music, R. Ahuja, S. Li, J.M. Schneider, Phys. Rev. B 70 (2004) 092102]. It is our ambition that these calculations will stimulate experimental research on these compounds. 相似文献
82.
83.
Š. Jakševičius 《Lithuanian Mathematical Journal》1992,32(2):174-180
Kaunas Academy of Agriculture, 4324 Noreikiškés, Lithuania. Translated from Lietuvos Matematikos Rinkinys, Vol. 32, No. 2,
pp. 221–228, April–June, 1992. 相似文献
84.
On the numerical solution of axisymmetric domain optimization problems by dual finite element method
Shape optimization of an axisymmetric three-dimensional domain with an elliptic boundary value state problem is solved. Since the cost functional is given in terms of the cogradient of the solution, a dual finite element method based on the minimum of complementary energy principle is used. © 1994 John Wiley & Sons, Inc. 相似文献
85.
Adducts of the conjugate addition of benzylamine to enantiopure amides of aroylacrylic acid possess high enantiomeric and diastereomeric purity. A high degree of stereoselectivity has been achieved by means of crystallization-induced asymmetric transformation. A practical synthesis leading to dipeptides containing homophenylalanine is depicted. 相似文献
86.
Denis Prat Françoise Benedetti Lahlou Nait Bouda Gilles Franc Girard 《Tetrahedron letters》2004,45(4):765-768
An industrial synthesis of 11β-aryl-estrone derivatives is described, based on the 1,4-addition of the aryl side-chain, as a cuprate, on to a mixture of allylic 5(10) alpha and beta epoxides, followed by hydrolysis and subsequent aromatization. 相似文献
87.
František Toman Ludvík Beneš 《Journal of inclusion phenomena and macrocyclic chemistry》2007,59(3-4):231-236
Differential molar adsorption enthalpies (DMAE) were determined by gas chromatographic measurements of specific retention
volume of vapors on the surface of two forms of Mg–Al hydrotalcite. A linear dependence of the DMAE on the number of the carbon
atoms in hydrocarbons was observed for both form of hydrotalcite. The dependence of the differential molar adsorption enthalpies
on the number of chlorine atoms in organic molecules is discussed. A linear dependence of DMAE on the molecular weight of
chloroderivatives of methane and ethylene on the basic form in an order monochloromethane < dichloromethane < trichloromethane
or vinylidene chloride < 1,1-dichloroethylene < trichloroethylene was found. 相似文献
88.
89.
The paper is devoted to the research of large deviation probabilities in the approximation by compound Poisson law. 相似文献
90.
Oriňák Andrej Arlinghaus Heinrich Frank Vering Guido Justinová Martina Oriňáková Renáta Turčániová L’udmila Halama Maroš 《平面色谱法杂志一现代薄层色谱法》2003,16(1):23-27
JPC – Journal of Planar Chromatography – Modern TLC - Two interfaces have been tested for coupling thin-layer chromatography (TLC) with time-of-flight secondary-ion mass spectrometry... 相似文献