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Controlled release formulation of pesticides is highly desirable for attaining the most effective utilization of the pesticide as well as reducing environmental pollution. Nano-sized controlled release formulations can provide better penetration through cuticle and deliver the active ingredients efficiently to the targeted tissue. In this study, a novel strategy for the preparation of a nanoconjugate derived from kasugamycin with amino-modified silica was developed. The kasugamycin was connected with amino-modified silica matrix by an amide bond, which could avoid the initial burst release effectively and prolong the duration remarkably. The results showed the kasuga-silica can protect kasugamycin against photo-degradation effectively and the release rate of the active ingredient of nanoconjugate was related to the temperature, pH value, and the particle size (52.5–315.4 nm). With reduced particle size as well as increased temperature and acidity, the release of the active ingredient was faster. This amide linkage of kasuga-silica could be degraded by amidase effectively. This nanoconjugate displayed a better and a sustained bactericidal efficacy against E. coli than kasugamycin technical, which makes it a potential candidate as a controlled release conjugate for kasugamycin in the future. 相似文献
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A hierarchical structural model for liquid-crystalline polyester reinforced with short glass fibers has been determined by using injection-molded bars. The gradient structure showed similar orientations between the glass fibers and the molecular orientation of the matrix. In the fiber-reinforced composites, the core failed prior to the skin by matrix cracking and transverse fiber pull-out as evidenced by the initial growth of parabolic cracks in the core. In the 30 wt% composite this was followed by complex cooperative phenomena involving fiber breakage, debonding, pull-out, and matrix deformation in the skin. The 50 wt% composite failed prematurely due to inadequate fiber/matrix interactions in the skin structure. Acoustic emission coupled with microscopy provided mechanistic insight throughout this work into the amount and intensity of specific failure mechanisms. 相似文献
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Direct condensation of carboxylic acids and alcohols with electronic, steric, and functional group variations was carried out using the environmentally benign, moisture-stable, inexpensive, and recoverable iron(III) acetylacetonate [Fe(acac)3] as catalyst (5 mol%). This iron salt efficiently catalyzed the esterification of several primary and secondary alcohols in refluxing xylene, without the need for a dehydration reagent. The chemoselectivity of the proposed protocol was demonstrated by the selective esterification of primary alcohol functionality in racemic 1-phenylethane-1,2-diol with benzoic acid. The esterification was also applicable to unmasked α -hydroxyacid, guasiaromatic, heterocyclic, and N-protected amino acids. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file. 相似文献