Li1+2xTi2-xMgxP3O12固溶体系统结构31P NMR研究

本文应用固体高分辨³¹P NMR技术,以P原子作为结构探针,对以LiTi2P₃O₁₂为基质的Mg掺杂固溶体系统快离子导体的结构进行了研究。并利用P原子第二配位层阳离子场强与其化学位移的关系,确定了不同化学位移³¹P NMR谱线与固溶体结构中P原子局部结构单元Q°之间的关系,解释了Mg的掺入所引起的晶体结构的变化。     

聚环氧氯丙烷γ辐射效应的NMR研究

用~（１３）Ｃ和~１ＨＮＭＲ波谱，探讨了聚环氧氯丙烷（ＰＥＰＣＨ）的辐射效应，结果表明随着辐射剂量的增加，本体聚合物的~（１３）ＣＮＭＲ谱中各基团的分辨率得以提高，~１ＨＮＭＲ谱中出现了裂解产物共振峰，Ｔ~１变短，表明ＰＥＰＣＨ在限量空气氛中的辐射效应以大分子裂解反应为主，并通过特性粘度的测定，得到了证实。     

Dehn Twists and Products of Mapping Classes of Riemann Surfaces with One Puncture

Let S be a Riemann surface that contains one puncture x. Let ℐ be the collection of simple closed geodesics on S, and let ℱ denote the set of mapping classes on S isotopic to the identity on S ∪ {x}. Denote by t _c the positive Dehn twist about a curve c ∈ ℐ. In this paper, the author studies the products of forms (t _b ^−m ∘ t _a ⁿ ) ∘ f ^k , where a, b ∈ ℐ and f ∈ ℱ. It is easy to see that if a = b or a, b are boundary components of an x-punctured cylinder on S, then one may find an element f ∈ ℱ such that the sequence (t _b ^−m ∘ t _n ^a ) ∘ f ^k contains infinitely many powers of Dehn twists. The author shows that the converse statement remains true, that is, if the sequence (t _b ^−m ∘ t _a ⁿ ) ∘ f ^k contains infinitely many powers of Dehn twists, then a, b must be the boundary components of an x-punctured cylinder on S and f is a power of the spin map t _b ⁻¹ ∘ t _a .     

Facile Synthesis of Single‐Phase Mesoporous Gd2O3:Eu Nanorods and Their Application for Drug Delivery and Multimodal Imaging

In this work, a new and facile strategy is developed to synthesize a single‐phase Eu³⁺‐doped mesoporous gadolinium oxide nanorods (MS‐Gd₂O₃:Eu@PEG) by incorporating a facile wet‐chemical route, which includes an induced silica layer being coated onto the nanorods, and evolution of pores and formation of channels, as well as a surface‐modified process for multimodal imaging and anti‐cancer drug delivery. The properties of these as‐prepared Gd₂O₃:Eu nanorods are characterized by transmission electron microscopy (TEM), X‐ray diffraction (XRD), N₂ adsorption/desorption, and photoluminescence (PL). The in vitro cytotoxicity test, drug loading, and drug release experiments reveal that the MS‐Gd₂O₃:Eu@PEG nanorods have good biocompatibility, efficient loading capacity, and pH‐sensitive releasing behavior, suggesting the nanorods could be an ideal candidate as drug delivery vehicles for cancer therapy. Furthermore, the MS‐Gd₂O₃:Eu@PEG nanorods show clearly dose‐dependent contrast enhancement in T₁‐weighted magnetic resonance images and can potentially be used as a T₁‐positive contrast agent. These results indicate our prepared multifunctional mesoporous gadolinium oxide nanorods can serve as a promising platform for simultaneous anti‐cancer drug delivery and multimodal imaging.     

Redistribution of Li-ions using covalent organic frameworks towards dendrite-free lithium anodes: a mechanism based on a Galton Board

Because of its high theoretical specific capacity and low reduction potential, Li metal is considered to be key to reaching high energy density in rechargeable batteries. In this context, most of the research has focused on suppressing dendrite formation during Li deposition to improve the cycling reversibility and safety of the batteries. Here, covalent organic framework(COF)film coating on a commercial polypropylene separator is applied as an ion redistributor to eliminate Li dendrites. The COF crystallites consist of ordered nanochannels that hinder the movement of anions while allowing Li-ions to transport across,leading to a high Li-ion transference number of 0.77±0.01. The transport of Li-ions across the COF film can be considered to be analogous to beads passing through a Galton Board, a model that demonstrates a statistical concept of a normal distribution.Thus, an even distribution of Li-ions is obtained at the COF/Li metal interface. The controlled Li-ion flux yields a smooth Li metal surface after 1,000 h(500 times) of cycling, leading to a significantly improved cycling stability and reversibility, as demonstrated by Cu||Li half cells, Li||Li symmetric cells, and Li Fe PO_4||Li full cells. These results suggest that, following the principle of a Galton Board, nanopore insulators such as COF-based materials are effective ion distributors for the different energy storage or conversion systems.     

Robust Microporous Metal–Organic Frameworks for Highly Efficient and Simultaneous Removal of Propyne and Propadiene from Propylene

Simultaneous removal of trace amounts of propyne and propadiene from propylene is an important but challenging industrial process. We report herein a class of microporous metal–organic frameworks ( NKMOF‐1‐M ) with exceptional water stability and remarkably high uptakes for both propyne and propadiene at low pressures. NKMOF‐1‐M separated a ternary propyne/propadiene/propylene (0.5 : 0.5 : 99.0) mixture with the highest reported selectivity for the production of polymer‐grade propylene (99.996 %) at ambient temperature, as attributed to its strong binding affinity for propyne and propadiene over propylene. Moreover, we were able to visualize propyne and propadiene molecules in the single‐crystal structure of NKMOF‐1‐M through a convenient approach under ambient conditions, which helped to precisely understand the binding sites and affinity for propyne and propadiene. These results provide important guidance on using ultramicroporous MOFs as physisorbent materials.     

One- and two-dimensional solid-state magic angle spinning NMR studies on the hydration process of layered sodium disilicate SKS-6

Three different kinds of silanols, which include isolated silanol, silanol I (with the hydroxyl proton bonded to an oxygen atom in the adjacent layer) and silanol II (with the hydroxyl proton bonded to the non-bridging oxygen at the same silicon atom), are generated during the hydration process of SKS-6 (δ-Na₂Si₂O₅). ¹H–¹H nuclear Overhauser enhancement spectroscopy reveals that the proton of silanol I has an effective chemical exchange or spin diffusion with the proton of hydrogen-bonded water, while the proton of silanol II is likely far away from the other proton-containing species. ²⁹Si magic angle spinning, ¹H→²⁹Si CP/MAS NMR and ¹H–²⁹Si phase-modulated Lee–Goldburg decoupled correlation experiments demonstrate that the local environments of the silicon sites in the final hydrated sample are mainly composed of Q² [(SiO)₂Si(OH)O⁻Na⁺], Q³ [(SiO)₃Si(OH) and (SiO)₃SiO⁻Na⁺] and Q⁴ [Si(OSi)₄] groups.     

Solid state NMR study of acid sites formed by adsorption of SO3 onto gamma-Al2O3

Detailed structure of Br?nsted acid sites on the surface of SO3/Al2O3 catalyst has been proposed based on 1H/27Al TRAPDOR NMR results and the acidity of the catalyst has also been characterized by NMR probe molecules.     

薄膜润滑中的微极流体效应

利用考虑微结构与微旋效应的微极流体理论来研究薄膜润滑的特性。微极效应将引起等效黏度的增加,从而影响油膜厚度。它对压力分布和膜厚形状的影响很小。数值模拟结果表明,等效黏度的增加效应与实验值有很好的类似性。     

Hyperbolic Mapping Classes and Their Lifts on the Bers Fiber Space

Let S be a Riemann surface with genus p and n punctures. Assume that 3p - 3 n ＞ 0 and n ≥ 1. Let a be a puncture of S and let (～S) = S ∪ {a}. Then all mapping classes in the mapping class group Mods that fixes the puncture a can be projected to mapping classes of Mod(～S) under the forgetful map. In this paper the author studies the mapping classes in Mods that can be projected to a given hyperbolic mapping class in Mod(～S).