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151.
Fluorescence microscopy has been utilized to investigate the effects of UV irradiation on the organization of keratin intermediate filaments in normal human epidermal keratinocytes. Sun lamp irradiation induced the condensation of keratin intermediate filaments into the perinuclear region and inhibited the reorganization of keratin filaments normally induced by Ca2+. Exposure to UVC appeared to disrupt keratin filaments similarly, whereas UVA had no discernible effect. 相似文献
152.
微分电位溶出分析法应用于金膜电极的研究 总被引:1,自引:0,他引:1
本文介绍将微分电位溶出分析法应用于金膜电极,建立了相应的理论体系和应用条件。可使用的金膜厚度在1.8×10~(-7)~4.3×10~(-7)cm范围。检测限较原法降低近两个数量极。用本法测定花生乳中的铜,回收率在94~102%间。 相似文献
153.
A new analytical method for phenylpropanolamine based on micellar electrokinetic chromatographic separation and laser‐induced fluorescence detection has been developed. Naphthalene‐2,3‐dicarboxaldehyde was used for precolumn derivatization of the nonfluorescent drug. Optimal separation and detection were obtained with an electrophoretic buffer of 50 mM sodium borate (pH 9.5) containing 15 mM sodium dodecyl sulfate and a He‐Cd laser (Δex: 442 nm, Δem: 500 nm). Linearity (r ≥ 0.99) of two orders of magnitude was generally obtained and the concentration limit of detection was in the ng/mL level. Coupled with a simple cleanup procedure, the method can be applied to the analysis of phenylpropanolamine in human plasma, with a limit of detection at 15 ng/mL. Recovery of phenylpropanolamine from plasma samples was about 90%. 相似文献
154.
TIAN CHOU 《高校应用数学学报(英文版)》1994,9(4):319-324
SYMMETRIESANDGROUP-INVARIANTSOLUTIONSOFDIFFERENTIALEQUATIONSTIANCHOUAbstract:Foradifferentialequation,atheoreticalproofofther... 相似文献
155.
Experiments were made for the flow over two side-by-side normal plates for which the gap ratios are in the range 1.4–2.1 and the Teynolds numbers are at 6.6 × 103 and 1.8 × 104. At low gap ratios, i.e., 1.4–1.6. the gap flow appears always to be biased and flip-flops to the preferred side non-periodically with respect to time. As the gap ratio becomes larger, the percentage of time occupied by the gap flow in the biased state decreases and the non-biased state of the gap flow becomes prevalent. A comparison of the experimental results obtained under five free stream turbulence conditions further shows that the addition of artificial disturbance into the free stream promotes gap flow flopping at low gap ratios. 相似文献
156.
ZnO‐Coated Carbon Nanotubes: Inter‐Diffusion of Carboxyl Groups and Enhanced Photocurrent Generation 下载免费PDF全文
Chia‐I Hung Dr. Hua‐Chiang Wen Yao‐Cheng Lai Dr. Shih‐Hsin Chang Prof. Dr. Wu‐Ching Chou Prof. Dr. Wen‐Kuang Hsu 《Chemphyschem》2015,16(4):812-816
ZnO is a defect‐governed oxide and emits light at both visible and UV regimes. This work employs atomic layer deposition to produce oxide particles on oxygenated carbon nanotubes, and the composites only show emission profiles at short wavelengths. The quenching of defect‐related emissions at long wavelengths is verified, owing to carboxyl diffusion into oxygen vacancies, and doping is supported by ZnCO3 formation in oxide lattice. Fully coated tubes display an increased photocurrent and the quantum efficiency increases by 22 % relative to the bare nanotubes. 相似文献
157.
Chih-Ming Chou Shunpei Nobusue Shohei Saito Daishi Inoue Daisuke Hashizume Shigehiro Yamaguchi 《Chemical science》2015,6(4):2354-2359
A reproducible formation of strongly bent crystals was accomplished by structurally restraining macrocyclic π-conjugated molecules. The model π-units consist of two 9,10-bis(2-thienylethynyl)anthracenes with a strong propensity for stacking, which are connected in a macrocyclic fashion via two alkylene linkers. The correlation between the crystalline morphology and the macrocyclic structures restrained by a variety of flexible alkylene linker combinations was systematically studied. Bent crystals were obtained only with specific alkylene linkers of appropriate chain length. The alkylene linkers can adopt different conformations in the crystal packing, so as to fill voids within the macrocycle. The ability to form several similar molecular structures with different alkylene conformations gives rise to contaminations of different crystalline phases within a single crystal, and it is these phase contaminations which are responsible for the bending of the crystals. 相似文献
158.
Dale McMorrow Michon Irons Wyche Pi Tai Chou Michael Kasha 《Photochemistry and photobiology》2015,91(3):576-585
Trace quantities of hydrogen‐bonding impurities in otherwise highly purified and dried glassy hydrocarbon matrices at 77 K can modify the relative triplet state energy levels, and hence the photophysical properties of two aromatic ketones, xanthone and chromone, to the extent that the intrinsic spectroscopic properties are obscured. The intrinsic spectroscopic properties of each are revealed in multicrystalline n‐alkane Shpol'skii matrices, and also can be observed in rigorously purified and dried hydrocarbon glasses at 77 K. The extreme sensitivity to stoichiometric, and even substoichiometric quantities of hydrogen‐bonding impurities arises from the near‐degeneracy of the two lowest‐lying triplet states, and the sensitive nature of the n→π* blueshift phenomena to specific hydrogen‐bonding interactions. 相似文献
159.
Chia‐Chun Chou 《International journal of quantum chemistry》2015,115(7):419-425
A simple and easy‐to‐implement method is presented for the study of time‐dependent reaction dynamics by propagating an ensemble of transmitted quantum trajectories. During the trajectory evolution, reflected trajectories are gradually removed and all the remaining trajectories represent the transmitted subensemble. The removal process of reflected trajectories avoids numerical instabilities arising from node formation in the reactant region, and allows stable long‐time propagation of transmitted trajectories. This method is applied to a two‐dimensional model chemical reaction. Excellent computational results are obtained for the time‐dependent reaction probabilities evaluated by the time integration of the probability flux. © 2014 Wiley Periodicals, Inc. 相似文献
160.
In this paper, experiments involving interior impacts on soft, lead targets are described. The term “interior impact” refers to the impact of a projectile at the bottom of a predrilled hole in the target. It is known that impact of low-velocity projectiles into such soft targets results in plastic flow and cavities similar to those obtained in high-velocity impact of hard targets. Therefore, comparatively simple rifle-propelled projectile impacts on soft targets may yield useful information for high-speed hard-target impacts. Double impacts with a short-time interval, on the order of microseconds, between projectile arrivals were conducted. The leading projectile creates a plastic flow in the target which partially seals the entrance hole. The trailing projectile must first force open the passage hole before achieving additional penetration. The total penetration was measured for different time intervals between the projectiles. A method was developed to obtain double impacts at the same point. The method utilizes a duplex round, which is made up of two separate projectiles fired from the same cartridge. With this round, a series of impact experiments was conducted. It was learned that occlusion, or the close up of the hole, is negligible for nearly simultaneous projectiles (less than 10 μs between impacts), and greatest with about 80 to 100 μs between impacts. The projectile velocity was measured by the use of properly placed photodiodes. 相似文献