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131.
Simon J. Coles David B. Davies Michael B. Hursthouse Hanıfe İbişoğlu Adem Kılıç Robert A. Shaw 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(1):o51-o54
The reaction of spermidine with 2,2,4,4-tetrachloro-6,6-diphenylcyclotriphosphazene produces a mixture of products of which one of the fractions is a spiro-cis-ansa derivative, namely 12-chloro-14,14-diphenyl-2,6,11,13,15,16-hexaaza-1,12-diphosphatricyclo[10.3.1.01,6]hexadeca-12,14-diene, C19H26ClN6P3. Recrystallization of this fraction from different solvents results in the formation of two different crystalline forms. The rod morphology formed in dichloromethane–n-hexane (1:1) produces a triclinic structure with three molecules in the asymmetric unit. These three molecules adopt different conformations as a result of two NH groups flipping in an ansa-bridged ring system. The plate morphology crystals, grown in dichloromethane–n-hexane–ethyl acetate (1:1:1), produce a C-centred monoclinic structure that adopts a conformation that is essentially the same as one of the forms in the triclinic structure. 相似文献
132.
Alejandro Adem 《Inventiones Mathematicae》1993,114(1):489-514
133.
Adem Zengin Ertan Yildirim Tuncer Caykara 《Journal of polymer science. Part A, Polymer chemistry》2013,51(4):954-962
Well‐defined, high‐density poly(2‐(2‐methoxyethoxy)ethyl methacrylate) [poly(MEO2MA)] brushes were fabricated through a reliable strategy by the combination of self‐assembly of a monolayer of 3‐aminopropyltrimethoxy silane on silicon surface to immobilize 4‐cyano‐4‐(dodecylsulfanylthiocarbonyl)sulfanyl pentanoic acid chain transfer agent and reversible addition‐fragmentation chain transfer‐mediated polymerization of MEO2MA. The whole fabrication process of the poly(MEO2MA) brushes was followed by water contact angle, grazing angle‐Fourier transform infrared spectroscopy, X‐ray photoelectron spectroscopy, and atomic force microscopy. Characterization of the poly(MEO2MA) brushes, such as molecular weight and thickness determination, were measured by gel permeation chromatography and ellipsometry, and the grafting density was estimated. The temperature‐responsive property of the poly(MEO2MA) brushes was further investigated and the result verified the brush‐to‐mushroom phase transition of the poly(MEO2MA) chains from low to high temperature. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
134.
E. Adem M. Avalos-Borja D. Carrillo M. Vazquez E. Sanchez M. P. Carreon G. Burillo 《Radiation Physics and Chemistry》1998,52(1-6):171-176
Recycling of polymeric materials is usually accompanied by degradation and deleterious properties. Irradiation crosslinking of recycling low density polyethylene by electron beam and gamma rays could be the solution to improve their properties. This paper presents a comparison on the effects of gamma and electron irradiation on virgin and recycled polyethylene. Their mechanical, thermal and chemical properties were analyzed. VPE samples shown higher crosslinking percentages than RPE samples in all range of doses studied, unirradiated RPE samples had higher values on their tensile properties than VPE. Percentage crystallinity was similar in all range of doses studied. 相似文献
135.
In this paper, we shall continue the study of bitopological separation axioms begun by Kelly and obtained some results. Furthermore, we introduce two concepts of pairwise Lindelöf bitopological spaces and the properties for them are established. We also show that a pairwise Lindelöf space is not hereditary property. 相似文献
136.
Tuncer Hkelek Nurcan Akduran Saliha Bege Adem Kl Zeynel Kl 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(11):1404-1406
The title compound, C45H55NO6P2, consists of an acyclic P=N—P(O) monophosphazene chain and five bulky 2,4,6‐trimethylphenoxy side groups which predominantly determine the molecular shape. Although the P—N single [1.586 (3) Å] and P=N double [1.517 (3) Å] bonds are significantly different from each other, both are substantially shorter than the ideal P—N single bond. The P—N—P angle [146.0 (2)°] corresponds to the upper limit reported for acyclic phosphazene derivatives in the literature. 相似文献
137.
Adem Donmez M. Burak Coban Cagdas Kocak Gorkem Oylumluoglu Ulrich Baisch 《Molecular Crystals and Liquid Crystals》2017,652(1):213-222
In the current work, a new coordination complex, [Cu(HL)2], 1 [H2L = 2–((E)–(2–hydroxypropylimino)methyl)–4–nitrophenol] was successfully synthesized and characterized by IR, UV-vis and photoluminescence spectroscopic techniques, single crystal and powder X-ray diffraction measurements. In the crystalline structure of complex 1, the aliphatic –OH group of the ligand is not coordinated and points away from the metal coordination zone, and also actively participates in intermolecular bifurcated O?H···O hydrogen bonds which link the molecules to form hydrogen-bonded linear chains. C?H···π and π···π contacts also connect the molecules in the structure which form to 3D structure. This hydrogen bonded polymeric networks lie in the bc-plane and stacks along to the a-axis. Furthermore, complex 1 and its ligand H2L display an intense navy-blue emission and blue emission in the solid state at room temperature, respectively, when they are excited under UV light. 相似文献
138.
Nonlinear Dynamics - In this study, we consider three model equations of shallow water waves. Shallow water equations model the propagation of strongly nonlinear waves up to breaking and run-up in... 相似文献
139.
Esvet Akbas Adem Ruzgar Ertan Sahin Erdem Ergan 《Journal of heterocyclic chemistry》2019,56(3):1003-1011
In this research, 5‐benzoyl‐6‐phenyl‐4‐(4‐trifluoromethylphenyl)‐2‐{oxo and thioxo}‐3,4‐dihydro‐1H‐pyrimidines ( 1 , 2 ) were synthesized by using multicomponent cyclocondensation reaction under microwave irradiation and classical heating. Compounds 3 , 4 , 6 , 7 , and 8 obtained reactions of 5‐benzoyl‐6‐phenyl‐4‐(4‐trifluoromethylphenyl)‐2‐thioxo‐3,4‐dihydro‐1H‐pyrimidine ( 1 ) and acetic anhydride, diethyl 2‐bromomalonate, bromoacetic acid, 3‐bromopropionic acid, methyl iodide, respectively. Compound 4 was both acetylated and hydrolyzed in acetic acid to give compound 5 . The structures of all compounds were determined by using spectroscopic techniques like FT‐IR, 1H/13C NMR, and elemental analyses, and the structures of compounds 1 and 3 were analyzed by X‐ray crystal analysis. In addition, the quantum chemical parameters and full geometry optimizations for all compounds were computed using density functional theory based on B3LYP and the 6‐31G (d, p) basis set. 相似文献
140.
Sakram Boda Ravi Dharavath Madhavi Madhavaram Kurumanna Adem Madhu Palithapu Govan Maloth 《合成通讯》2019,49(1):1-11
An effective, practical, and simple approach toward the preparation of highly-substituted 6-arylbenzo[4, 5]imidazo[1,2-a][1,8]naphthyridin-10-ols 6(a-h) by the reaction of 3-aryl-1,8-naphthyridin-2-amines 3(a-h) with benzoquinone 4 in acid catalyzed cyclization under solid-state method, as well as conventional conditions, has been described. The products are obtained in good yields and in a solid of high purity. The major advantages of solid states are easy workup, low costs, short reaction time, good efficacy, and environment-friendly procedure. The newly synthesized compounds were thoroughly characterized using spectral data and elemental analyses. All compounds were screened for their biological evaluation. Predominantly 6b and 6c compounds showed the highest antibacterial activity. Moreover, all the synthesized compounds were docked against topoisomerase II DNA gyrase enzyme. 相似文献