Two 1-substituted 4-nitro­imidazoles

Crystalline 4-nitro-1-phenyl­imidazole, C₉H₇N₃O₂, (I), and 4′-­nitro-1-phenyl-4,1′-bii­imidazole, C₁₂H₉N₅O₂, (II), contain C—H⃛O and C—H⃛N hydrogen bonds, connecting the mol­ecules into infinite chains. The aromatic fragments in both compounds are nearly planar. The dihedral angles between the benzene and imidazole rings are 26.78 (5)° in (I) and 29.36 (8)° in (II).     

Normality of orbit closures for Dynkin quivers¶of type ?n

It is known that the orbit closures for the representations of the equioriented Dynkin quivers ? _n are normal and Cohen–Macaulay varieties with rational singularities. In the paper we prove the same for the Dynkin quivers ? _n with arbitrary orientation. Received: 25 October 2000 / Revised version: 28 February 2001     

Caesium and hydrated lead chlorates studied by35Cl NQR spectroscopy

Molecular dynamics of caesium and lead chlorates (hydrated form) has been studied by³⁵Cl nuclear quadrupole resonance (NQR) spectroscopy. The occurrence of only one resonance line for the two compounds in the whole temperature range studied testifies to the crystallographically equivalent positions of their molecules in elementary cells. The relaxation processes in the two chlorates have been found to be analogous to those in the other chlorates not undergoing phase transitions. Analysis of the temperature dependence of the spin-lattice relaxation time has indicated that at low temperatures the dominant relaxation mechanism consists of torsion vibrations (ClO₃⁻ anion libration), whereas at 260 K the hindered rotation of the chlorate ion about the threefold axis sets on and its activation energy is 50.0 kJ/mol. The temperature dependence of the resonance frequency for the two chlorates studied is best described by the Brown model extended over the low-temperature range, which indicates large anharmonicity of the vibrations.     

Formally smooth bimodules

The notion of a formally smooth bimodule is introduced and its basic properties are analyzed. In particular it is proven that a B-A bimodule M which is a generator left B-module is formally smooth if and only if the M-Hochschild dimension of B is at most one. It is also shown that modules M which are generators in the category σ[M] of M-subgenerated modules provide natural examples of formally smooth bimodules.     

Elastic scattering of acoustic phonons on point mass defects

The problem of eigenvalues of the collision operator for a gas of acoustic phonons scattered by point mass defects of small concentration embedded in transversely isotropic media is considered. For this purpose the properties of solution of the Boltzmann-Peierls kinetic equation for spatially homogeneous states are studied. An analytic formula for the Laplace transform of the distribution function is obtained. The singularities of this Laplace transform and the initial distribution function determine the dependence of this distribution function on time. For several hexagonal materials characteristics of the singularity set are calculated. Usually the singularity set consists of a continuous part and four discrete points. However, there exist elastic hexagonal materials (⁴He, Cd, Ta, Zn) for which some of discrete points are absent. For some materials (e.g. Zr) the continuous part is very narrow.