排序方式: 共有38条查询结果,搜索用时 15 毫秒
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珠心算的发现、发展乃至在国内外推广,经过了中国专家学者们几十年的发现、研究、实验、发展过程,也包括无数默默无闻的一线教师、教练们倾其心血、殚其精思、接踵接力的教学实践。这里刊登了尽瘁于珠心算教学讲坛上的山西平陆实验小学教学教师、著名珠心算专家陈子镜的得力助手王玉玲(传记载本期珠坛春秋栏目)的遗作节选,以飨读者…… 相似文献
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降解水中有机毒物的新型反应体系研究 总被引:6,自引:0,他引:6
利用空气中的氧电化学合成H2O2,制备具有较高电流效率的空气电极.将空气电极用于构成降解有机毒物的新型反应体系电化学氧化体系、光激发氧化剂氧化体系和光电-Fenton氧化体系.实验测量了H2O2在不同体系不同条件下的分解速率,并与相应的传统式体系作了比较.实验测量了苯胺在新型体系中的矿化反应速率,发现H2O2的分解速率与苯胺的矿化速率有良好的平行关系,其中H2O2分解速率最快的光电-Fenton体系是氧化降解有机分子的最佳体系.通过光电-Fenton体系和光-Fenton体系的比较,揭示了空气电极/溶液界面在光电-Fenton体系中所起的重要作用.初步讨论了苯胺分子在光电-Fenton体系中矿化反应的机制. 相似文献
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通过乙炔在Al2O3上的分解制备碳纳米管-氧化铝(Al2O3-CNTs)载体.采用浸渍法,分别制备了Pt/Ba/Al2O3-CNTs和Pt/Ba/Al2O3催化剂.利用XRD,SEM,TEM,低温N2物理吸附,XPS和in-situ DRIFTS等手段对催化剂的物化性质进行了表征.结果表明,在SO2存在下的NOx还原反应中,Pt/Ba/Al2O3-CNTs比Pt/Ba/Al2O3具有更高的抗SO2性能和再生性能.In-situ DRIFTS表明SO2的存在对NOx储存还原的途径没有影响. 相似文献
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A coordination polymer of [Tb(ntb)]n(1) based on 4,4’,4’’-nitrilotribenzoate ligand(ntb3–) was synthesized. Compound 1 crystallizes in monoclinic system, space group C2/c with a = 13.7318(4), b = 27.5628(9), c = 5.4046(2) ?, β = 111.142(3)°, V = 1907.88(12) ?3, Z = 4, C21H12NO6Tb, Mr = 533.24, Dc = 1.856 g/cm3, μ = 3.745 mm–1, F(000) = 1032, the final R = 0.0184 and wR = 0.0456 for 1883 observed reflections with Ⅰ > 2s(Ⅰ). In compound 1, the eight-coordinated Tb(III) atoms are bridged by carboxylate groups of ntb3– ligands to generate a one-dimensional Tb-carboxylate chain, which is further linked by the ntb3– ligands to form a three-dimensional structure. Compound 1 exhibits characteristic Tb(Ⅲ) luminescent emissions in the solid state. 相似文献
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Two coordination polymers based on the mixed ligands of biphenyl-3,3?-disul-fonyl-4,4?-dicarboxylate(BPDSDC4–)and 2,2?-bipyridine(2,2?-bpy),{[Cd(BPDSDC)0.5(2,2?-bpy)(H2O)]·(H2O)}n(1)and{[Cd(BPDSDC)0.5(2,2?-bpy)2]·(H2O)}n(2)were synthesized.Both compounds crystallize in the monoclinic system,space group P21/n.For 1,a=7.5737(2),b=17.4284(5),c=13.5982(5)?,β=90.788(3)°,V=1794.76(10)?^3,Z=4,C17H15N2O7SCd,Mr=503.77,Dc=1.864 g/cm^3,μ=1.378 mm^?1,F(000)=1004,the final R=0.0299 and wR=0.0644 for 3137 observed reflections with I>2s(I).For 2,a=13.3097(2),b=10.66240(10),c=17.6583(3)?,β=91.779(2)°,V=2504.74(6)?^3,Z=4,C27H21N4O6SCd,Mr=641.94,Dc=1.702 g/cm^3,μ=1.008 mm^?1,F(000)=1292,the final R=0.0244 and wR=0.0583 for 4594 observed reflections with I>2s(I).The Cd(II)atoms in both compounds are six-coordinated.In 1,the Cd(2,2?-bpy)units are connected by BPDSDC4–ligands to generate a one-dimensional(1D)ribbon structure.The 1D ribbons are linked by the hydrogen bonds and π···π interactions to give a three-dimensional(3D)structure.In compound 2,the Cd(2,2?-bpy)2 units are linked by the BPDSDC^4–ligands to form a 1D chain.Compounds 1 and 2 show luminescent emissions. 相似文献
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为了改进工程用电池建模精度低(5%以内),五参量模型参数多且难获取的缺点,提出一种新的太阳能电池组件参数确定方法.首先通过LambertW函数求解出太阳能电池组件参数解析式,其次采用多项式拟合法,获取太阳能电池组件电压电流关系式,最后结合分段积分法求得了太阳能电池组件的参数值.实验表明,该方法的精度在0.5%以内:与主流电导简化法和模式优化算法相比,该方法不仅具有直观性,利于掌握和计算,同时求出的电池组件参数具有更小的误差值(0.1%以内). 相似文献
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The mononuclear complex, Cu(H2SIP-O)(bpy)(H2O) (H4SIP-O = 4-hydroxyl- 5-sulfoisophthalic acid and bpy = 2,2'-dipyridyl), has been synthesized by the hydrothermal reaction of Cu(OH)2 with NaH2SIP and bpy at 160 ℃, and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectrum. The new ligand 4-hydroxyl-5-sulfoisophthalic acid derived from 5-sulfoisophthalic acid ligand under an in situ hydrothermal condition. The crystal of the complex crystallizes in a triclinic system, space group P1, with a = 7.757(4), b = 10.663(6), c = 11.727(7)A, α = 94.272(4), β = 104.067(7), γ = 97.400(7)°, V= 927.4(9)A^3, Z = 2, C18H14N2O9SCu, Mr= 497.93, Dc= 1.783 g/cm^3,μ = 1.350 mm^-1, F(000) = 506, the final R = 0.0518 and wR = 0.1513 for 4180 observed reflections with I 〉 2σ(I). The central Cu(II) ion is five-coordinated by two oxygen atoms from the H2SIP-O^2- ligand and two nitrogen atoms of bpy ligand in a distorted square-planar geometry as well as a water oxygen atom in the apical position to complete a distorted square-pyramidal coordination geometry. The mononuclear copper molecules are linked by hydrogen bonds between coordinated water molecules and sulfonate groups to form a one-dimensional double-chain structure. The chains are further held together through extensive π-π stacking interactions between the aromatic rings to form a three- dimensional supramolecular structure. 相似文献
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新型双功能复合忆极的制备及其加速水中有机污染物降解作用的研究 总被引:2,自引:0,他引:2
介绍了新型复合电极的制备方法、其双功能特性以及在提高水中有机污染物(如苯胺)降解速度所起的作用,并对其作用机制进行了讨论。实验结果表明,由空气电极和TiO2光催化剂组成的复合电极,当其工作电位控制在0.05V(vs.SCE)左右时,既具有良好的光电效应,又 具有以较高效率合成H2O2的特性,使溶液中的有机分子获得来自光催化氧化与光化学氧化两方面的联合降解作用,从而显著地提高了有机分子的氧化降解速度。 相似文献
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