用于铁电体复杂畴结构模拟的布朗方程

铁电材料在室温下具有可以在外加电场作用下改变方向的自发极化,不同方向的极化在材料内部形成畴结构,会对其物理特性和实际应用具有显著影响.本文将最初用于微磁模拟的布朗方程引入铁电材料的大尺度模拟中,研究其中可能出现的重要畴结构.在以有效哈密顿量方法为基础推导出铁电材料中关于电偶极子的布朗方程后,以BaTiO₃,PbTiO₃块体和SrTiO₃/PbTiO₃/SrTiO₃夹心结构等钙钛矿铁电材料为研究对象,验证了布朗方程的有效性并讨论了其中的多种畴结构,如周期性条带状畴、涡旋型拓扑畴结构等,并与相关实验结果进行了对比分析.     

Cu-Fe基催化剂上合成气直接制取低碳烯烃的研究

我们采用浸渍法制备了γ-Al2O3负载的Cu-Fe基催化剂,并结合其反应性能和XRD、H2-TPR和XPS等表征结果研究了其催化合成气直接制低碳烯烃的反应行为.结果表明,合成气直接制低碳烯烃Cu-Fe基催化剂的活性组分Cu和Fe之间存在明显的协同效应,Cu-Fe基催化剂表现出优异的合成气直接制低碳烯烃反应性能;Cu基催化剂中引入少量Fe组分明显提高了活性组分Cu的分散度,促进了Cu活性组分的还原,进而有利于催化剂反应性能的改进.初步推断Cu-Fe基催化剂上合成气转化生成低碳烯烃的主要反应历程为CO加氢生成含氧化合物(醇醚等)后再脱水生成低碳烯烃.     

ROLE OF CALCIUM IN ELECTRO-ACUPUNCTURE ANALGESIA AND THE DEVELOPMENTS OF ANALGESIC TOLERANCE TO ELECTROACUPUNTURE AND MORPHINE

Role of brain Ca~(2+) in electro-acupuncture analgesia and the development of analgesic tolerance to electro-acupuncture and morphine were studied. At the same time, the inhibition by protein synthesis inhibiturs of the development of analgesic tolerance to electro-acupuncture was observed. The results showed that like morphine tolerance, the brain Ca~(2+) and cAMP levels in mice were enhanced with the development of analgesic tolerance to electro-acupuncture. After treatment with protein synthesis inhibitors anisomycin, actinomycin or cycloheximide the development of analgesic tolerance to electro-acupuncture was inhibited, and concurrently, the brain Ca~(2+) and cAMP levels in the animals greatly reduced. From the changes of brain Ca~(2+) and cAMP levels, the analgesic effects by electro-acupuncture, morphine and lanthanides seem to be very similar and share a mutual ion basis and the mechanism of action. So does the development of analgesic tolerance to electro-acupuncture and morphine. These finding     

LDPE／iPP复合膜的附生结晶研究

附生结晶(epitaxy)是指结晶物质在结晶基质上的取向成核和生长。聚合物-聚合物的附生结晶揭示了聚合物间新的结构关系,在高分子物理领域引起了极大兴趣和广泛关注。根据结构关系,聚合物附生结晶主要分为两类,即均相附生结晶(homoepitaxy)和异相附生结晶(het-eroepitaxy)。在异相附生体系中,大多数研究工作集中在全同立构聚丙烯(iPP)与一些锯齿链     

新生态二氧化锰对水中碱性染料的脱色作用

以新生态二氧化锰作吸附剂,对水中碱性染料——碱性紫和碱性橙进行吸附脱色。介绍实验原理、实验方法,并对影响吸附的因素进行了较详细探讨。     

一种有效的变步长的自适应独立分量分析算法

步长因子的优选是自适应算法中的一个重要问题,本文建立了步长因子与互相关性测度之间的一种非线性函数关系,以此为基础,提出了一种新的变步长的自适应独立分量分析算法,分析了算法收敛性能和稳态性能.该算法根据互相关性测度所反映的信号分离状态自适应地调节步长因子,克服了传统算法在稳态步长调整过程中的不足.仿真实验结果表明了算法的有效性.     

Cn(0,1)的Hilbert边值问题

通过引进算子,对（１）和（２）中Ｓｃｈｗａｒｚ问题的证明作了有效的改进,并得到了Ｃｎ（０,１）中的解析函数的Ｓｃｈｗａｒｚ积分公式,进而讨论了这个区域Ｈｉｌｂｅｒｔ边值问题可解性的条件和解的表达式。     

Fractional Fourier transform for partially coherent beam in spatial-frequency domain

By using Fourier transform and the tensor analysis method, the fractional Fourier transform (FRT) in the spatial-frequency domain for partially coherent beams is derived. Based on the FRT in the spatial-frequency domain, an analytical transform formula is derived for a partially coherent twisted anisotropic Gaussian－Schell model (GSM) beam passing through the FRT system. The connections between the FRT formula and the generalized diffraction integral formulae for partially coherent beams through an aligned optical system and a misaligned optical system in the spatial-frequency domain are discussed, separately. By using the derived formula, the intensity distribution of partially coherent twisted anisotropic GSM beams in the FRT plane are studied in detail. The formula derived provide a convenient tool for analysing and calculating the FRTs of the partially coherent beams in spatial-frequency domain.     

椭圆平顶高斯光束及其传输特性

 用张量光学方法定义了三维不可分离变量的椭圆平顶高斯光束(EFGB),导出了这种光束经过非轴对称光学系统的传输公式及相应的张量ABCD定律, 并对EFGB经过自由空间的传输作了数值计算。结果表明, EFGB的传输特性依赖于阶次, 而且耦合EFGB的光强分布在传输过程中会发生旋转。     

维多利亚艳蓝及其缔合物可见光谱研究

研究维多利亚艳蓝(VPB)及其缔合物的可见光谱。研究了VPB与阴离子的显色反应;用作图法测定了VPB在水溶液中的质子传递常数;用等摩尔法和连续变化法测定了缔合物的组成和稳定常数。VPB 在酸性水溶液中呈浅黄色而缔合物呈艳蓝色。VPB BO,VPB R,VPB B和NB的pK_h分别为2.16,1.32,0.82和0.73。VPB BO与DBS,[CdI₄]2-分别形成1∶1和2∶1离子对缔合物,K_f(稳定常数)分别为1.5×106,6.0×1012,表观摩尔吸光系数分别为4.7×104 L·mol-1·cm-1,2.8×105 L·mol-1·cm-1。VPB是一种分析性能优良的高灵敏显色剂。