Determination of the stability constants of uranyl complex with 8-hydroxyquinolinium sulfate

8-Hydroxyquinoline (8-HOQ) is known as an important chelating agent for several metal ions. This compound is practically insoluble in water. For this reason, in this study its water soluble sulfate salt has been used for complexing uranyl ions and the stability constants of the complex have been determined. The Irving-Rosotti method computing the Calvin-Bjerrum pH-titration data, was applied. Finally, the stability constants of the complex formed between (8-HOQN-H)₂SO₄ and uranyl ions were found to be lgK₁=8.25 and lgK₂=4.15, the overall stability constant being {ie55-1}.     

Random rotations of the Wiener path

Summary Let (W, H, ) be an abstract Wiener space and letR(w) be a strongly measurable random variable with values in the set of isometries onH. Suppose that Rh is smooth in the Sobolev sense and that it is a quasi-nilpotent operator onH for everyhH. It is shown that (R(w)h) is again a Gaussian (0, |h| _H ² )-random variable. Consequently, if (e _i ,i)W ^* is a complete, orthonormal basis ofH, then defines a measure preserving transformation, a rotation, onW. It is also shown that if for some strongly measurable, operator valued (onH) random variableR, (R(w+k)h) is (0, |h| _H ² )-Gaussian for allk, hH, thenR is an isometry and Rh is quasi-nilpotent for allHH. The relation between the stochastic calculi for these Wiener pathsw and , as well as the conditions of the inverbibility of the map are discussed and the problem of the absolute continuity of the image of the Wiener measure under Euclidean motion on the Wiener space (i.e. composed with a shift) is studied.The research of the second author was supported by the Fund for the Promotion of Research at the TechnionDedicated to the memory of Albert Badrikian     

Symmetric orbits of orthogonal veronese actions and their second order envelopes

The orbits of Lie groups acting in Euclidean spaces by isometries are extrinsically symmetric iff they are parallel, i.e. satisfy ${\overline \nabla} h =0 $ Submanifolds characterized by the integrability condition $ {\overline R}\o\ h =0 $ of this system ${\overline \nabla} h =0$ are called semi-parallel (or semi-symmetric, extrinsically); they are the 2nd order envelopes of the symmetric orbits. For the orthogonal Veronese action, corresponding to the map well-known from the algebraic geometry, all symmetric orbits will be determined, as well as their 2nd order envelopes. The results are essential for the classification of the semi-parallel submanifolds.     

Some results about the spectrum of commutative Banach algebras under the weak topology and applications

LetA be a commutative Banach algebra with a nonempty spectrum A. By weak we denote the relative weak topology induced on A by (A ^*,A ^**). In this note we study some properties of the topological space (A, weak) and present some applications of the results obtained and tools used to amenability, weakly compact homomorphisms, weakly compact subsets of the spectrum of the uniform algebras and to a characterization of the synthesizable ideals of the algebraA.     

Isolation of xylose reductase gene ofPichia stipitis and its expression inSaccharomyces cerevisiae

Applied Biochemistry and Biotechnology - A NADPH/NADH-dependent xylose reductase gene was isolated from the xylose-assimilating yeast,Pichia stipitis. DNA sequence analysis showed that the gene...     

Phase morphology of iPP/aPS/SEP blends

Supermolecular structure and phase morphology of the ternary isotactic polypropylene/atactic polystyrene/poly(styrene-b-ethylene-co-propylene) (iPP/aPS/SEP) compression molded blends with 100/0, 90/10, 70/30, and 50/50 iPP/aPS weight ratios and with different amounts of added SEP compatibilizer were studied by optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), small-angle X-ray scattering (SAXS) and wide-angle X-ray diffraction (WAXD). SEP significantly reduced the size of dispersed aPS particles that enabled better spherulitization in the iPP matrix. Furthermore, iPP spherulites in ternary blends with 90/10 iPP/aPS weight ratio became larger in comparison with the pure iPP. TEM revealed that the SEP formed continuous interface layer around the dispersed aPS particles even when only 2.5 wt.% of SEP was added. Particle size distribution was distinctly bimodal. When the SEP content was increased to 10 wt.%, joining together smaller and bigger aPS and SEP particles formed dispersed aggregates. Additionally, both amorphous components (aPS and SEP) influenced crystallization process of iPP matrix and so modified, to some extent, its final supermolecular structure. SEP compatibilizer did not significantly affect crystallite orientation. The increase of crystallite sizes, which was more affected by the addition of aPS than by the addition of SEP, seemed to be influenced by the solidification effect rather than by the phase morphology of the blends.     

Determination of iodide in drinking water by isotope dilution analysis

The most suitable way of determination iodine-deficiency is to measure iodine concentrations in water and urine. For this reason, a method that can determine iodide concentrations in drinking water and suitable for routine analysis, is developed. Water samples have been collected from four Aegean localities: Izmir, Salihli, Ödemis and Tire situated in the western Turkey. The method is based on substochiometric isotope dilution analysis. Iodile concentrations vary within 9.86–85.14 μg/l ranges in the analyzed samples. Mean value is 44.92±22.07 μg/l.     

Study on labeling conditions of125I-synkavit by the iodogen method

Labeling conditions of synkavit (2-methyl-1,4-naphthoquinol disodium phosphate) with iodine-125 have been studied. In this study, labeling temperature, reaction time, successive using of iodogen coated tubes, iodogen amount and synkavit concentrations have been determined to get optimum conditions for maximum labeling. Final results showed that when the labeling temperature, reaction time, synkavit concentration, and iodogen amount were, at room temperature, 15 min (in the case of successive using of three iodogen coated tubes), 2 mg ml^–1 and 5 mg, respectively; labeling yield was 90% and specific activities of the order of 555 GBq mmol^–1 (15 Ci mmol^–1) have been obtained.     

S-(2-Pyrimidinyl)- and S-(2-(4,6-dimethylpyrimidinyl))-1,1,3,3-tetramethylthiouronium hexafluorophosphates: novel reagents for in situ peptide coupling

Two new reagents for in situ peptide coupling based on the 2-mercaptopyrimidine core have been developed. The readily prepared thiouronium salts were found to promote both peptide and segment coupling efficiently with low racemization/epimerization levels.     

Vibrational Spectroscopic Studies on the Hofmann-dabn-Type Benzene Clathrates: M(1,4-diaminobutane)Ni(CN)4° 1.5C6H6 (M = Mn, Fe, Co, Ni or Cd)

IR spectra of M(1,4-diaminobutane)Ni(CN)4° 1.5C6H6 (M = Mn, Fe, or Co), and IR and Raman spectra of M(1,4-diaminobutane)Ni(CN)4° 1.5C6H6 (M = Ni or Cd) clathrates are reported. The spectral features suggest that the compounds are similar in structure to the Hofmann-dabn-type clathrates.