Hopf bifurcation in the Lorenz-type chaotic system

In this paper, we analyze dynamical behaviors of the Lorenz-type system via the complementary-cluster energy-barrier criterion. Moreover the Hopf bifurcation of this system is also investigated by means of the first Lyapunov coefficient. As a consequence, it is proved that this system has three Hopf bifurcation points, at which these Hopf bifurcations are nondegenerate and supercritical.     

Interpretation of the Role of Composition on the Inclusion Efficiency of Monovalent Cations into Cobalt Hexacyanoferrate

Cobalt hexacyanoferrate of various compositions was prepared in flow mode and the role of the vacancy on the structure, thermogravimetric (TG) properties, and the adsorption efficiency was studied. The material, Na_yCo[Fe(CN)₆]_1−x ⋅ z H₂O, with a minimum vacancy of x=0.014 to the highest x=0.47, was obtained. The TG-differential scanning calorimetry (DSC) profile showed a distinct influence of the vacancy on the water release temperature. Materials with x>0.35 showed a smooth release of water at a relatively lower temperature. However, for the materials with x<0.35, water release took place in multiple steps, suggesting the existence of various forms of water. The FTIR profiles supported the existence of free and bonded water molecules. However, the materials with multiple water peaks in the FTIR spectra showed a shift of the major XRD peaks when heated at 285 °C in N₂ atmosphere. Regarding the effect of the vacancy on the adsorption behavior, for NH₄, the adsorption was found to be proportional to the number of Na atoms in the material, confirming the ion-exchange process. On the contrary, the materials with low vacancy and high Na content showed nominal Cs adsorption capacity. Interestingly, the K adsorption capacity was found to be in between that of the other two ions. This means the ionic size decides the rate of placement into the interstitial sites. For larger ions like Cs, the ease of percolation via the vacancy decides the overall adsorption efficiency.     

An effective multi-channel fault diagnosis approach for rotating machinery based on multivariate generalized refined composite multi-scale sample entropy

Nonlinear Dynamics - Fault diagnosis of critical rotating machinery components is necessary to ensure safe operation. However, the commonly used rotating machinery fault diagnosis methods are...     

The Derivative Nonlinear Schrödinger Equation with Zero/Nonzero Boundary Conditions: Inverse Scattering Transforms and N-Double-Pole Solutions

In this paper, we report a rigorous theory of the inverse scattering transforms (ISTs) for the derivative nonlinear Schrödinger (DNLS) equation with both zero boundary conditions (ZBCs) and nonzero boundary conditions (NZBCs) at infinity and double zeros of analytical scattering coefficients. The scattering theories for both ZBCs and NZBCs are addressed. The direct scattering problem establishes the analyticity, symmetries, and asymptotic behaviors of the Jost solutions and scattering matrix, and properties of discrete spectra. The inverse scattering problems are formulated and solved with the aid of the matrix Riemann–Hilbert problems, and the reconstruction formulae, trace formulae and theta conditions are also posed. In particular, the IST with NZBCs at infinity is proposed by a suitable uniformization variable, which allows the scattering problem to be solved on a standard complex plane instead of a two-sheeted Riemann surface. The reflectionless potentials with double poles for the ZBCs and NZBCs are both carried out explicitly by means of determinants. Some representative semi-rational bright–bright soliton, dark–bright soliton, and breather–breather solutions are examined in detail. These results and idea can also be extended to other types of DNLS equations such as the Chen–Lee–Liu-type DNLS equation, Gerdjikov–Ivanov-type DNLS equation, and Kundu-type DNLS equation and will be useful to further explore and apply the related nonlinear wave phenomena.

     

A型沸石中Lwenstein规则的能学研究

通过模拟退火方法,使用协合分子力学场对Ｓｉ,Ａｌ分布分别为４：０序列,两种３：１序和随机分布的ＮａＡ型沸石结构进行了能量最小化计算,获得了不同结构的位能及其生成热大小,计算结果表明,４：０序结构的位能和生成热在所讨论的几种序结构中最低,从而在理论上证实了Ｌｏｅｗｅｎｓｔｅｉｎ规则是分子筛结构中能量最小化的自然结果。     

低乙烯基聚丁二烯橡胶的合成和表征

以钴催化体系为催化剂,用两步聚合法合成了1,2-链节含量范围在7—16%的低乙烯基聚了二烯橡胶。对聚合产物的表征结果表明,聚合物中存在着间同1,2-聚丁二烯的微晶,这些微晶起晶种的作用,能促进产物在低温下的结晶;当胶中1,2-链节含量小于10%时,不溶于CS₂的级分较少,加入1,2-聚合催化剂后主要生成顺1,4-间同1,2-丁二烯嵌段共聚物;当1,2-链节含量高于10%时,CS₂不溶物量较多,这时除上述嵌段物外尚可能生成少量间同1,2-聚了二烯均聚物。     

Enantioselective pinacol coupling reaction of aromatic aldehydes catalyzed by chiral vanadium complexes

The asymmetric pinacol coupling of aromatic aldehydes by chiral salan–vanadium complexes as effective catalysts is reported. Chiral 1,2-diols were obtained with high diastereoselectivities (up to 90/10) and moderate to high enantioselectivities (up to 82% ee). The possible mechanism of the pinacol coupling reaction is also discussed.     

The influence of magnetic field on the physical explosion of a heavy gas cloud

Richtmyer–Meshkov (RM) instability arises during the eruption of heavy gas cloud. In this study, we numerically study the effects of magnetic fields on the RM instability induced by the ionised cylindrical and spherical heavy gas cloud eruption using corner transport upwind + constrained transport algorithm. Our numerical results show that magnetic fields can suppress the formation of spike and bubble structures induced by the eruption in both cylindrical and spherical cases. The magnetic pressure of the interface along the perpendicular direction of magnetic field is the main factor to control the distortion of the interface. Even weak magnetic fields can drastically alter the evolution of the cloud and result in different distributions and amplifications of the magnetic pressure, which will affect further transformation of RM instability during the ionised gas eruption. Meanwhile, the magnetic pressure on the interface decreases gradually when the initial magnetic field is relatively large; when the initial magnetic field is small enough, the opposite results will occur.     

Vector semi-rational rogon-solitons and asymptotic analysis for any multi-component Hirota equations with mixed backgrounds

The Hirota equation can be used to describe the wave propagation of an ultrashort optical field. In this paper, the multi-component Hirota (alias n-Hirota, i.e. n-component third-order nonlinear Schrödinger) equations with mixed non-zero and zero boundary conditions are explored. We employ the multiple roots of the characteristic polynomial related to the Lax pair and modified Darboux transform to find vector semi-rational rogon-soliton solutions (i.e. nonlinear combinations of rogon and soliton solutions). The semi-rational rogon-soliton features can be modulated by the polynomial degree. For the larger solution parameters, the first m (m < n) components with non-zero backgrounds can be decomposed into rational rogons and grey-like solitons, and the last n − m components with zero backgrounds can approach bright-like solitons. Moreover, we analyze the accelerations and curvatures of the quasi-characteristic curves, as well as the variations of accelerations with the distances to judge the interaction intensities between rogons and grey-like solitons. We also find the semi-rational rogon-soliton solutions with ultra-high amplitudes. In particular, we can also deduce vector semi-rational solitons of the n-component complex mKdV equation. These results will be useful to further study the related nonlinear wave phenomena of multi-component physical models with mixed background, and even design the related physical experiments.