某软土深基坑工程时间效应有限元分析

软土地区的深基坑因土体的固结作用和流变性而具有了时间效应。本文以Biot固结有限元法为基础,用三元件模型中的第一个线性弹簧模拟固结作用,弹性模量考虑了开挖应力路径和应力历史的影响;另外一部分(KELVIN模型)来模拟土体的流变性,以实际变形的反演来得到两个参数的大致取值,再对基坑的变形情况以及进一步开挖进行分析。假定为正常固结饱和粘土,平面应变问题。通过对某饱和软粘土地基深基坑开挖工程实例的分析,得到的挡墙水平位移曲线与实测曲线很吻合,表明程序较好地反映出基坑的时间效应。     

基于自动磁珠转运的转基因蛋白Cry1Ab检测

基于自动磁珠转运,建立了转基因蛋白Cry1Ab免疫检测的新方法.利用水热法制备了粒径约400 nm的纳米磁球,并进行电镜表征,通过溶胶法对磁球表面进行氨基修饰,采用戊二醛偶联对磁珠实现抗体包被,在核酸提取仪中进行酶联免疫反应,采用分光光度法进行检测.本方法对转基因蛋白Cry1Ab的检出限低于1 μg/L,与商品化酶联免...     

基于吡啶多羧酸和N，N′-桥联混合配体的钴配合物的合成及结构分析

将吡啶-2,4,6-三羧酸(2,4,6-pytaH3),4-氨基-3,5-二(4-吡啶基)-1,2,4-三氮唑(4,4′-abpt)和CoCl2在不同的pH条件下发生水热反应,得到2个新的配位聚合物[Co(2,4,6-pytaH)(4,4′-abpt)(H2O)](1)和[Co1.5(2,4,6-pyta)(4,4′-abpt)(H2O)3].3.5H2O(2)。配合物1是在吡啶-2,4,6-三羧酸酸性环境下产生的,吡啶-2,4,6-三羧酸在水热条件下只脱去2个羧基上的质子变成2,4,6-pytaH2-,而配合物2是在NaOH碱性溶液下反应得到的,其中吡啶-2,4,6-三羧酸完全脱去3个羧基上的质子变成2,4,6-pyta3-。配合物1中包含一维Co-羧酸链,2中存在具有(4,4)拓扑网络的二维层。1和2中的一维链和二维层通过π-π堆积和丰富的氢键作用分别拓展成三维超分子网络。单晶结构分析表明,配合物1结晶于单斜晶系,P21/n空间群,a=0.961 30(10)nm,b=0.632 09(6)nm,c=3.372 9(4)nm,β=95.104(2)°,V=2.041 3(4)nm3,Z=4。而配合物2结晶于单斜晶系,P21/c空间群,a=1.795 2(2)nm,b=0.729 62(8)nm,c=2.078 7(2)nm,β=112.323(2)°,V=2.518 6(5)nm3,Z=4。     

高灵敏度分光光度法测定茶叶中锌的含量

研究了在聚乙烯醇(PVA)存在下,Zn2+ - SCN—- RhB高灵敏度显色反应体系,采用分光光度法测定茶叶中微量锌的新方法.结果表明,络合物的最大吸收峰在605 nm处,摩尔吸光系数为1.59×106 L·mol—1·cm—1,Zn2+的质量浓度在0.0~0.04 μg/mL范围内服从比尔定律.该法用于测定茶叶中锌...     

固相微萃取-气相色谱/质谱联用快速鉴定香稻香味特征化合物2-乙酰基吡咯啉

建立了固相微萃取-气相色谱/质谱(SPME-GC/MS)联用快速鉴定香稻香味特征化舍物2-乙酰基吡咯啉的方法.香米加入内标物2,4,6-三甲基吡啶,密封,在80℃水浴条件下经固相微萃取(萃取纤维头为100 μm聚二甲基硅氧烷)提取2 h,提取物经毛细管气相色谱柱HP-5MS(30 mx0.25mm×0.25μm)分离,...     

Hydrophobic/hydrophilic solvation: inferences from Monte Carlo simulations and experiments

In this study Monte Carlo simulations are used to determine the solvation properties of model hydrophobic (xenon and hard sphere) and hydrophilic (dimethyl ether) solutes in SPC/E water. Various contributions to the experimental solvation entropy, including the solvent reorganization entropy, have been determined. The main conclusion drawn, which is in accord with solubility data, is that poor solubility correlates with poor solute-water interaction. At room temperature, energy dominates the aqueous solubility of both hydrophobic and hydrophilic solutes, rather than entropy. However, at higher temperatures the solubility can pass through a minimum, and then entropy becomes dominant. Another interesting finding is the presence of larger than expected cavities in water. Two different simulation results support this finding. This unexpected hollow structure in water explains why a hard sphere solute is more soluble in water than in a comparable hard sphere or Lennard-Jones solvent. Hydrogen bonding causes water to aggregate into clusters that produce a few large cavities rather than many smaller cavities. The propensity for clustering also explains why water gives the illusion of being a low density liquid. Sufficient theoretical apparatus is developed to connect theoretical solvation properties to those measured by simulation and experiment. Finally, based on gas solubility, an intuitive hydrophobic/hydrophilic scale is developed.     

Theoretical research of multiphoton transition of HF in static electric and laser fields

A ‘modulated potential model’ is presented to describe the potential of diatomic molecules in static electric fields, and investigate the static electric effect on the multiphoton process. The multiphoton transition of HF in static electric and intense laser fields has been investigated using the Lie algebra approach. Multiphoton transition information is obtained by solving the time-evolution operator. This method makes the solving of the Schrödinger equation easier and makes the computation time shorter.     

液体中的声处理应用和声空化工程

1引言 声波在好几个方面有它广泛不可替代的用途，像声通讯、声检测、控制声、声控制等。在几个方面的用途中有声处理一项，这时利用了声的能量。本文只讨论液体中的声处理应用。在长时期的实验室试验中它显示了，并且继续在显示，强大的潜力，但比较奇特的是，这么大量的实验室成果，只有很少数转化为生产力。本文强调转化为生产力的有利性和紧迫性。本文并且指出，液体中声处理的基本机理多是声空化，因此，分析研究在液体中大规模或生产化声处理时声空化的特征和行为，     

量子自旋系统的块自旋方案及其簇团Monte Carlo模拟方法

本文提出了一种关于一维和二维量子自旋系统的Monte Carlo模拟新算法。具体给出了对于一维和二维Heisenberg模型的计算方案。在s=1/2的铁磁和反铁磁链情况下的计算结果证实了此方法有效地克服了“临界慢化(CSD)”效应和能够达到更低的温度区域进行计算。该方法可推广到各向异性和高自旋(s=1,3/2,…)量子系统、二维经典8-顶角格点模型和低维费密系统。 关键词：     

MgB2/Fe带材Jc的各向异性及MgB2芯织构和成分不均一性的研究

本文研究了在不同磁场方向和温度下非原位Fe包套MgB2单芯带Jc的各向异性,通过对各种工艺条件下带材中MgB2芯的X-ray衍射图进行拟合分析和计算,比较了MgB2芯在Fe-MgB2界面和中心处的织构度和成份不均一性.研究发现带材Jc的各向异性受初始粉末颗粒尺寸的影响.由于受套管材料强度和形变加工工艺的影响,MgB2芯在Fe-MgB2界面处比在中心处有较强的织构.在MgB2-Fe的界面处,700℃淬火样品的X-ray衍射图中发现了由中间相Fe23B6生成的金属间化合物Fe2B.另外还研究了MgB4和MgO等主要杂质相的形成原因.