一步乳液聚合法制备高溶解性导电聚苯胺

报道了一种高溶解性导电聚苯胺(PANI)的制备方法,以聚2-丙烯酰胺-2-甲基丙磺酸(PAMPS)作为掺杂酸和乳化剂,利用其特有的长链、亲水性及强酸性基团效应,通过乳液聚合法一步合成出具有较高溶解性的导电聚苯胺。利用核磁共振光谱仪(NMR)、傅里叶红外光谱仪(FT-IR)和扫描电子显微镜(SEM)等技术手段对产物结构和性能进行了表征分析。结果表明,在m(苯胺)∶m(AMPS)∶m(APS)=1∶2∶1.5;AMPS质量分数为20%;APS质量分数为30%;反应时间为5 h;反应温度为5℃的条件下,聚苯胺的产率高达86%,在有机溶剂二甲基甲酰胺(DMF)中的溶解度可达0.3814 g/g,在水中的溶解度可达0.2123 g/g,电导率达5.9 S/cm。     

多金属氧酸盐催化烯烃环氧化研究进展

综述了以过氧化氢为氧源,多金属氧酸盐催化烯烃环氧化的研究进展,尤其是针对基于多金属氧酸盐的反应控制相转移催化体系近年来的研究进展进行了详细阐述.     

Approximation Technique for Fractional Evolution Equations with Nonlocal Integral Conditions

We consider a class of fractional evolution equations with nonlocal integral conditions in Banach spaces. New existence of mild solutions to such a problem are established using Schauder fixed-point theorem, diagonal argument and approximation techniques under the hypotheses that the nonlinear term is Carathéodory continuous and satisfies some weak growth condition, the nonlocal term depends on all the value of independent variable on the whole interval and satisfies some weak growth condition. This work may be viewed as an attempt to develop a general existence theory for fractional evolution equations with general nonlocal integral conditions. Finally, as a sample of application, the results are applied to a fractional parabolic partial differential equation with nonlocal integral condition. The results obtained in this paper essentially extend some existing results in this area.     

Mixed monotone iterative technique for a class of semilinear impulsive evolution equations in Banach spaces

This paper deals with the existence of mild L-quasi-solutions to the initial value problem for a class of semilinear impulsive evolution equations in an ordered Banach space E. Under a new concept of upper and lower solutions, a new monotone iterative technique on the initial value problem of impulsive evolution equations has been established. The results improve and extend some relevant results in ordinary differential equations and partial differential equations. An example is also given.     

Simultaneous Determination of Four Sudan Dyes in Egg Yolks by Molecularly Imprinted SPE Coupled with LC-UV Detection

A highly selective molecularly imprinted solid-phase extraction (MISPE) combined with liquid chromatography-ultraviolet detection was developed for the simultaneous isolation and determination of four Sudan dyes (I, II, III and IV) in egg-yolk products. The imprinted microspheres synthesized by suspension polymerization using phenylamine?Cnaphthol as mimic template show high selectivity and affinity to the four kinds of Sudan dyes and were successfully applied as selective sorbents of solid-phase extraction for the simultaneous determination of the four Sudans from egg-yolk samples. Good linearity was obtained in a range of 0.062?C10 ??g g^?1 and the average recoveries of the four Sudans at three spiked levels ranged from 94.1 to 102.5% with the relative standard deviations less than 5.8%. The developed extraction protocol eliminated the effect of template leakage on quantitative analysis and could be applied for the determination of Sudans in complicated food samples.     

随机Bregman ADMM及其在训练具有离散结构的支持向量机中的应用

针对具有多块可分结构的非凸优化问题提出了一类新的随机Bregman交替方向乘子法,在周期更新规则下, 证明了该算法的渐进收敛性; 在随机更新的规则下, 几乎确定的渐进收敛性得以证明。数值实验结果表明, 该算法可有效训练具有离散结构的支持向量机。     

以商圈为中心的O2O动态外卖配送路径优化模型与算法

针对线上到线下(Online to Offline,O2O) 外卖路径优化问题,综合考虑其动态配送需求、货物区分等特点以及时间窗、载货量等约束条件,将商圈看作配送中心,将快递员数量与快递员总行驶时间作为最小化目标,提出了以商圈为中心的O2O动态外卖配送路径优化模型。采用周期性处理新订单的方法将相应的快递员路径的动态调整问题转化为一系列静态TSP子问题,设计了一种分阶段启发式实时配送路径优化算法框架,并给出了一个具体算法和一个数值计算实例。在VRP通用算例的基础上,以商圈为中心生成测试算例,对本文算法进行仿真实验,并与其他算法比较。结果表明：本文算法能充分利用新订单附近的快递员进行配送,并优化其配送路径,有效减少了快递员数量与快递员总行驶时间。     

商科型高校理工类研究生创新能力的培养

目前,研究生教育处于我国高等教育的最高层次,肩负着为国家发展培养高技术专业型人才的重要任务.尤其是在各国竞争愈发激烈的今天,理工类研究生更是在未来国家现代化建设、科技创新中发挥着重要作用.但是,由于近几年研究生招生规模的逐渐扩大,研究生的培养模式、培养质量等方面出现了许多亟待解决的问题.从商科型高校理工类研究生的培养现状出发,通过运用文献法和归纳法,本文对当前研究生培养过程中存在的问题进行分析,并针对学生创新能力的培养,从学校、导师和学生自身三方面给出了相应的解决措施,着重强调了数学建模在理工类研究生创新能力培养过程中所发挥的重要作用.最后,以湖南工商大学近几年在理工类研究生创新能力培养实践中所采取的主要举措以及取得的成效来进一步论证本文所提出措施的有效性.     

Determination of trace water in gas samples by an improved Karl Fischer coulometer.

The determination of trace water in gas samples, such as isobutene, chloromethane (polymeric staple gases) and SF6 by a conventional Karl Fischer coulometer is very difficult, because of the adsorption of trace water on the surface of sample pipe, the gasification of the liquefied samples, and the migration of moisture into the measuring cell from the surroundings. To solve these problems, we improved a device for coulometric determination of water by Karl Fischer method. The improved coulometer was used to determine the trace water in isobutene, chloromethane and SF6; RSD was less than 5%, and recoveries ranged from 94.1 to 109.1%, which is adequate for the analysis of industry.     

Gd2（WO4）3∶Eu3+,Sm3+纳米晶的制备及Sm3+对Eu3+特征发射的敏化作用

采用共沉淀法分别制备了Eu3+、Sm3+单掺和共掺Gd2(WO4)3纳米发光材料,对所制备的纳米发光材料的结构和发光特性进行了研究。结果表明:所得样品为Gd2(WO4)3的底心单斜结构,Eu3+的摩尔分数为20%时,Gd2(WO4)3∶20%Eu3+的发光最强。Sm3+对Eu3+有敏化作用,使Eu3+的5D0→7F2发射明显增强。用464 nm的光激发时,Sm3+对Eu3+的敏化作用强于用395 nm的光激发。Sm3+的摩尔分数为5%时,样品Gd2(WO4)3∶20%Eu3+,5%Sm3+的5D0→7F2发射强度最大。Sm3+的掺入使监测Eu3+的5D0→7F2跃迁的激发光谱强度明显增大,且拓宽了可被LED有效激发的波长范围。在405 nm和440 nm波长的光激发下,也可以明显观察到样品Gd2(WO4)3∶20%Eu3+,5%Sm3+中Eu3+的5D0→7F2跃迁。