锌对动物免疫功能的影响

锌是机体必需的微量元素,它对动物免疫系统的正常发育和功能方面有重要作用。综述了微量元素锌对动物免疫器官、免疫细胞和免疫分子等的可能作用机制和对免疫功能的影响。     

Effect of compressed CO2 on the properties of lecithin reverse micelles

Lecithin is a very useful biosurfactant. In this work, the effects of compressed CO 2 on the critical micelle concentration (cmc) of lecithin in cyclohexane and solubilization of water, lysozyme, and PdCl 2 in the lecithin reverse micelles were studied. The micropolarity and pH value of the polar cores of the reverse micelles with and without CO 2 were also investigated. It was found that CO 2 could reduce the cmc of the micellar solution and enhance the capacity of the reverse micelles to solubilize water, the biomolecule, and the inorganic salt significantly. Moreover, the water pools could not be formed in the reverse micelles in the absence of CO 2 because of the limited amount of water solubilized. However, the water pools could be formed in the presence of CO 2 because large amounts of water could be solubilized. All of these provide more opportunity for effective utilization of this green surfactant. The possible mechanism for tuning the properties of the reverse micelles by CO 2 is discussed.     

车载系统主被动联合振动控制研究

针对车载系统行进过程中产生的结构振动,提出被动隔振和主动减振相结合的方法对结构弹性振动和刚体振动进行抑制．一方面,针对结构弹性振动,在车载结构和车体之间安装隔振装置,选择合适的隔振器参数,对车载结构的弹性振动进行隔离．另一方面,结合刚体振动抑制的需求,进一步研究小阻尼隔振器带来的结构低频刚体振动．对隔振器和车载结构形成的新系统采用主动控制方法设计最优控制器,对这一类过驱动控制系统进行主动控制研究．通过主被动控制结合,实现车载结构全频段范围内的振动抑制,能够将系统刚体振动的位移均方根值抑制到无控制时的5%以下．     

Preparation of 3,6-dibenzoylacenapthene in the presence of Lewis acidic ionic liquids

The reactivity of Lewis acidic ionic liquids for the acylation of acenaphthene to 3,6-dibenzoylacenaphthene was investigated. Ionic liquids of different alkyl chain length and metal chloride were synthesized and tested for the reaction to discuss the effects of Lewis acidity of the ionic liquid on the alkylation. Pure 3,6-dibenzoylacenaphthene was obtained and the structure of 3,6-dibenzoylacenaphthene was identified by GC/MS, FT-IR and ¹H NMR spectra. [Emim]C1/A1C1₃ ionic liquid was found to be the most active catalyst in the acylation. The yield of 3,6-dibenzoylacenaphthene was up to 89.6% and the selectivity towards 3,6-dibenzoylacenaphthene was up to 92.2%. The experiment shows that [Emim]Cl/AlCl₃ can be used as both catalyst and solvent, it is reusable and environmentally friendly for the preparation of 3,6-dibenzoylacenaphthene.     

Hydrogen production via autothermal reforming of ethanol over noble metal catalysts supported on oxides

Hydrogen was produced over noble metal (Ir, Ru, Rh, Pd) catalysts supported on various oxides, including γ-Al2O3, CeO2, ZrO2 and La2O3, via the autothermai reforming reaction of ethanol (ATRE) and oxidative reforming reaction of ethanol (OSRE). The conversion of ethanol and selectivites for hydrogen and byproducts such as methane, ethylene and acetaldehyde were studied. It was found that lanthana alone possessed considerable activity for the ATRE reaction, which could be used as a functional support for ATRE catalysts. It was demonstrated that Ir/La2O3 prevented the formation of methane, and Rh/La2O3 encumbered the production of ethylene and acetaldehyde. ATRE reaction was carried out over La2O3-supported catalysts (Ir/La2O3) with good stability on stream, high conversion, and excellent hydrogen selectivity approaching thermodynamic limit under autothermal condition. Typically, 3.4 H2 molecules can be extracted from a pair of ethanol and water molecules over Ir(5wt%)/La2O3. The results presented in this paper indicate that Ir/La2O3 can be used as a promising catalyst for hydrogen production via ATRE reaction from renewable ethanol.     

Effect of compressed CO2 on the critical micelle concentration and aggregation number of AOT reverse micelles in isooctane

The effect of compressed CO2 on the critical micelle concentration (cmc) and aggregation number of sodium bis-2-ethylhexylsulfosuccinate (AOT) reverse micelles in isooctane solution was studied by UV/Vis and fluorescence spectroscopy methods in the temperature range of 303.2-318.2 K and at different pressures or mole fractions of CO2 (X(CO2)). The capacity of the reverse micelles to solubilize water was also determined by direct observation. The standard Gibbs free energy (DeltaGo(m)), standard enthalpy (DeltaHo(m)), and standard entropy (DeltaSo(m)) for the formation of the reverse micelles were calculated by using the cmc data determined. It was discovered that the cmc versus X(CO2) curve and the DeltaGo(m) versus X(CO2) curve for a fixed temperature have a minimum, and the aggregation number and water-solubilization capacity of the reverse micelles reach a maximum at the X(CO2) value corresponding to that minimum. These results indicate that CO2 at a suitable concentration favors the formation of and can stabilize AOT reverse micelles. A detailed thermodynamic study showed that the driving force for the formation of the reverse micelles is entropy.     

Quasi-square-shaped cadmium hydroxide nanocatalysts for electrochemical CO2 reduction with high efficiency

Powered by a renewable electricity source, electrochemical CO₂ reduction reaction is a promising solution to facilitate the carbon balance. However, it is still a challenge to achieve a desired product with commercial current density and high efficiency. Herein we designed quasi-square-shaped cadmium hydroxide nanocatalysts for CO₂ electroreduction to CO. It was discovered that the catalyst is very active and selective for the reaction. The current density could be as high as 200 mA cm⁻² with a nearly 100% selectivity in a commonly used H-type cell using the ionic liquid-based electrolyte. In addition, the faradaic efficiency of CO could reach 90% at a very low overpotential of 100 mV. Density functional theory studies and control experiments reveal that the outstanding performance of the catalyst was attributed to its unique structure. It not only provides low Cd–O coordination, but also exposes high activity (002) facet, which requires lower energy for the formation of CO. Besides, the high concentration of CO can be achieved from the low concentration CO₂via an adsorption-electrolysis device.

Quasi-square cadmium hydroxide nanocrystals (Cdhy-QS) showed outstanding performance for electroreduction CO₂ to CO.     

Influence of uniaxial plastic deformation on surface magnetic field in steel

Under geomagnetic field, surface magnetization measurements were made on 1045 and a3 steels samples uniaxially deformed to differing magnitudes of plastic strain, to study the dependence of surface magnetic field and its distribution on plastic deformation. The results indicated initial increase in surface magnetic field with increasing plastic strain followed by a decrease at higher plastic deformation. At still higher plastic deformation, the surface magnetic field was found to be almost independent of plastic strain. In the middle part of the sample, the uneven plastic deformation interrupted the linear distribution of surface magnetic field. The behavior of surface magnetic field and its distribution with plastic deformation were largely controlled by the different mechanisms of interaction of domain walls with isolated dislocation, dislocation tangles and dislocation cellular structures.     

New Approaches to the Synthesis of Metal Carbenes

Metal carbenes usually possess versatile reactivities that are controlled by the presence of both the metals and the ligands. Diazo compounds are commonly used for the generation of such species through elimination of nitrogen. However, they are often unstable, explosive, and toxic, which limits their applications in large‐scale syntheses. Thus, identifying sustainable and safe surrogates for the generation of metal carbenes has attracted great attention. In this Review, we summarize some of the most important breakthroughs in the generation, catalytic reactions, and selectivity control of metal carbenes from non‐diazo starting compounds.     

聚合物注塑残余应力研究进展

综述了聚合物注塑残余应力的研究进展,详细介绍计算残余应力所用的理论模型及其基本概念,注塑制品残余应力由两部分组成,并且有不同的测试方法,这些应力是造成制品曲变形的原因,对于残余流动应力,重点分析本构模型的发展和注塑控制方程的建立;对于残余热应力,则讨论了冷却过程中的相变问题,以及热粘弹性模型在应力分析中的应用;最后介绍测量残余应力的几种实验方法。