Temperature Dependence of the Mössbauer Effect on Prussian Blue Nanowires

Highly ordered Prussian blue nanowires with diameter of about 50 nm and length up to 4 m have been fabricated by an electrodepositing technology with two-step anodizing anodic aluminum oxide films. The Mössbauer spectra taken between 15 and 300 K indicate that the hyperfine parameters decrease as the temperature increases. The temperature dependence of the quadrupole splitting, the isomer shift and the spectra area are discussed. A decrease of Debye temperature for Prussian blue nanowires was found with respect to that of Prussian blue bulk.     

第Ⅱ种强度不等的非对称两态叠加多模叠加态光场的偶数阶等阶N次方Y压缩

本文构造了由多模复共轭相干态的相反态|{-Z_j^(a)*}>_q与多模虚共轭相干态的相反态|{-iZ_j^(b)*}>_q这两者的线性叠加所组成的第Ⅱ种强度不等的非对称两态叠加多模叠加态光场|Ψ_Ⅱ^(ab)>_q,利用多模压缩态理论研究了态|Ψ_Ⅱ^(ab)>_q的任意偶数阶等阶N次方Y压缩特性.结果发现:1)在压缩阶数N取偶数,即N=2p的条件下,无论p=2m(m=1,2,3,…,…),还是p=2m+1(m=0,1,2,3,…,…),只要构成态|Ψ_Ⅱ^(ab)>_q的两个不同的量子光场态中各对应模的强度(即平均光子数)和初始相位都不相等,亦即R_j^(a)≠R_j^(b)和φ_j^(a)≠φ_j^(b)(j=1,2,3,…,q),并且 ,则当满足一定的量子化条件(或者在一些闭区间内连续取值)时,态|Ψ_Ⅱ^(ab)>_q总可呈现出周期性变化的、任意偶数阶的等阶N次方Y压缩效应.2)在N=2p且p=2m+1(m=0,1,2,3,…,…)的条件下,若R_j^(a)=R_j^(b)和φ_j^(a)=φ_j^(b)(j=1,2,3,…,q),态|Ψ_Ⅱ^(ab)>_q则可呈现出等阶N次方Y压缩简并现象.     

第Ⅰ种非对称两态叠加多模叠加态光场的偶数阶等阶N次方Y压缩

本文利用多模压缩态理论,研究了第Ⅰ种非对称两态叠加多模叠加态光场|Ψ_Ⅰ^(ab)Ⅰ>_q的偶数阶等阶N次方Y压缩特性.结果发现:在压缩阶数N取偶数情况下,只要构成态|Ψ_Ⅰ^(ab)Ⅰ>_q的两个量子光场态的强度(即平均光子数)不相等,则当各模的初始相位φ_j^(a)、φ_j^(b)(j＝1,2,3,…,q)、态间的初始相位差(θ_pq^(bI)-θ_nq^(aR))以及与上述的两个量子光场态相对应的各单模相干态光场的光子干涉项之和 ＝[R_j^(a)R_j^(b)cos(φ_j^(a)-φ_j^(b))]等满足一定条件时,态|Ψ_Ⅰ^(ab)Ⅰ>_q可呈现出周期性变化的、任意偶数阶的等阶N次方Y压缩效应.这一结果与现有文献报道的结果截然不同.     

第Ⅱ种强度不等的两态叠加多模叠加态光场的等阶N次方H压缩——2腔模总数与压缩阶数两者之积取奇数的情形

构造了由多模复共轭相干态的相反态|{-Z_j^(a)*}〉q和多模虚共轭相干态的相反态|{-Z_j^(b)*}〉q的线性叠加所组成的第Ⅱ种强度不等的非对称两态叠加多模叠加态光场|Ψ(ab)Ⅱ〉q.利用多模压缩态理论,研究了态|Ψ(ab)Ⅱ〉q的等阶N次方H压缩特性.结果发现,在腔模总数与压缩阶数这两者之积取奇数,则当各对应模的初始相位、各对应模的初始相位差,态间的初始相位差、以及光子干涉项的幅度之和等分别满足一定的量子化条件时,态|Ψ(ab)Ⅱ〉q的第一及第二正交分量可分别呈现出周期性变化的等阶N次方H压缩效应.这与现有报道的结果截然不同.     

马氏定律与哈勃定律的辨析

本文从理论,实验上论证了“马氏（红移）定律”,同时指出所谓“退行速度Vr”或“星系红移”与“星系间的距离”无必须的关系,从这个意义上来说,哈勃定律是错误的。     

Prediction of programmed-temperature retention values of naphthas by artificial neural networks

It is proposed for the first time a method of prediction of the programmed-temperature retention times of components of naphthas in capillary gas chromatography using artificial neural networks. People are used to predict the programmed-temperature retention time using many formulas such as the integral formula, which requires that four parameters must be determined by calculation or experiments. However the results obtained by the formula are not so good to meet the demand of industry. In order to predict retention time accurately and conveniently, artificial neural networks using five-fold cross-validation and leave-20%-out methods have been applied. Only two parameters: density and isothermal retention index were used as input vectors. The average RMS error for predicted values of five different networks was 0.18, whereas the RMS error of predictions by the integral formula was 0.69. Obviously, the predictions by neural networks were much better than predictions by the formula, and neural networks need fewer parameters than the formula. So neural networks can successfully and conveniently solve the problem of predictions of programmed-temperature retention times, and provide useful data for analysis of naphthas in petrochemical industry.     

啤酒酵母中β-(1-3)葡聚糖的提取及其性能分析

本文采用Sevage脱蛋白法、酸溶液浸提法、碱溶液浸提法对啤酒废酵母细胞壁中的β-(1-3)葡聚糖作了提取试验,并对所获多糖进行生化特性分析,阐述了碱溶液浸提法是从啤酒酵母中回收高质量β-(1-3)葡聚糖的理想途径．     

光学系统时间畸变和色时间滞后的研究

本文对皮秒和飞秒技术中瞬态现象测量系统所用的特殊光学系统校正时间畸变和压缩色时间滞后的问题进行了讨论。实验证明用该方法设计研制的光学系统校正效果显着。