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991.
Toshio Kaneko Miki Takahashi Masahiro Hirama 《Angewandte Chemie (International ed. in English)》1999,38(9):1267-1268
An efficient photo-Bergman reaction of aliphatic enediynes has been realized. Photolysis of 1 results in the formation of 4 in good yields along with [D2] 3 . Enediyne 4 , which has never been isolated in the thermal reaction of 1 , arises here by a retro-Bergman reaction of the diradical intermediate 2 . 相似文献
992.
Atsushi Kaneko 《Journal of Graph Theory》1998,27(1):7-9
We prove that if s and t are positive integers and if G is a triangle-free graph with minimum degree s + t, then the vertex set of G has a decomposition into two sets which induce subgraphs of minimum degree at least s and t, respectively. © 1998 John Wiley & Sons, Inc. J Graph Theory 27: 7–9, 1998 相似文献
993.
994.
Norio Kashiwa Shin-ichi Kojoh Nobuo Kawahara Shingo Matsuo Hideyuki Kaneko Tomoaki Matsugi 《Macromolecular Symposia》2003,201(1):319-326
This paper describes a new synthetic route for polyolefinic graft block copolymers by adopting coupling reaction between terminally hydroxylated polyolefins and maleic anhydride grafted polyolefins. Terminally hydroxylated polypropylene (PP-OH) was coupled with maleic anhydride modified polyethylene (PE-g-MAH) and such ethylene-propylene random copolymer (EPR-g-MAH) to give polyolefinic graft block copolymers (PE-g-PP and EPR-g-PP, respectively). The formation of PE-g-PP was confirmed by enhancement on molecular weight and it brought about distinctive decrease in size of dispersed domain in its phase separation morphology. Occurrence of coupling reaction to give EPR-g-PP was indicated by extreme decrease in its solubility to n-decane and it led to unique morphology demonstrating lamella microstructure that had never been reported for a comparable polyolefin composite. 相似文献
995.
Hideyuki Kaneko Shin-ichi Kojoh Nobuo Kawahara Shingo Matsuo Tomoaki Matsugi Norio Kashiwa 《Macromolecular Symposia》2004,213(1):335-346
Polymacromonomers with polyolefin branches were successfully synthesized by free-radical homopolymerization of polyolefin macromonomer with a methacryloyl end group. Propylene-ethylene random copolymer (PER) with a vinylidene end group was prepared by polymerization using a metallocene catalyst. Then, the unsaturated end group was converted to a hydroxy end group via hydroalumination and oxidation. The PER with the hydroxy end group was easily reacted with methacryloyl chloride to produce methacryloyl-terminated PER (PER macromonomer; PERM). The free-radical polymerization of thus-obtained PERM was done using 2,2′-azobis(isobutyronitorile) (AIBN) as a free-radical initiator. From NMR analyses, the obtained polymers were identified as poly(PERM). Based on gel permeation chromatography (GPC), the estimated degree of polymerization (Dp) of these polymers were about 30. Thus, new class of polymacromonomers with polyolefin branches was synthesized. 相似文献
996.
Dieter Whrle Olga Suvorova M. Kaneko Nicola Trombach Robert Gerdes Oliver Bartels Günter Schnurpfeil 《Macromolecular Symposia》2000,156(1):109-116
Based on low molecular and macromolecular phthalocyanines as light absorbing compounds different light driven reactions are shortly discussed. These processes include under irradiation with visible light energy transfer in photooxidation reactions and electron transfer in photosensibilisation cells or photovoltaic cells. Catalytic oxidation reactions are also mentioned to compare the different mechanisms of dark and light oxidations. 相似文献
997.
Solar cells comprised of nanoparticulate TiO2 porous film photosensitized with an adsorbing dye have been utilized as photoinduced charge separation systems in aqueous media with the view to forming future artificial photosynthetic systems able to create fuels from solar energy and water. The photoinduced charge separation of the sensitized TiO2 cell in a quasi‐solid, made from agarose or κ‐carrageenan, was investigated.
998.
999.
Hideyuki Kaneko Shingo Matsuo Nobuo Kawahara Junji Saito Tomoaki Matsugi Norio Kashiwa 《Macromolecular Symposia》2007,260(1):9-14
Isotactic polypropylene-based graft copolymers linking poly(methyl methacrylate), poly(n-butyl acrylate) and polystyrene were successfully synthesized by a controlled radical polymerization with isotactic polypropylene (iPP) macroinitiator. The hydroxylated iPP, prepared by propylene/10-undecen-1-ol copolymerization with a metallocene/methyl-aluminoxane/triisobutylaluminum catalyst system, was treated with 2-bromoisobutyryl bromide to produce a Br-group containing iPP (PP-g-Br). The resulting PP-g-Br could initiate controlled radical polymerization of methyl methacrylate, n-butyl acrylate and styrene by using a copper catalyst system, leading to a variety of iPP-based graft copolymers with a different content of the corresponding polar segment. These graft copolymers demonstrated unique mechanical properties dependent upon the kind and content of the grafted polar segment. 相似文献
1000.
Tatsuo Kaneko Ayako Ichikawa Jian Ping Gong Yoshihito Osada 《Macromolecular rapid communications》2003,24(13):789-792
The complexation of bile acids with various solvated polycations was studied. A one‐to‐one complex was precipitated when an aqueous solution of cholic acid sodium salt (CA) was mixed with aqueous solutions of 3,3‐ionene and grew to form crystals with needle‐like morphology, 3 millimeters in length. Hydrogen bonding of hydroxyls at the steroid face and the spacing between cationic sites of polycations were crucial for the formation of the giant needle.