Direct synthesis of hyperbranched ethene oligomers and ethene-MA co-oligomers using iminopyridyl systems with weak neighboring group interactions

The synthesis of hyper-branched ethene oligomers through catalytic insertion reactions with late transition metal catalysts is unique in its synthetic and practical scope. In this study, a series of iminopyridyl Ni(II) and Pd(II) complexes with electron-rich distal aryl motifs were synthesized and characterized. These complexes were very efficient in ethene oligomerization and co-oligomerization with methyl acrylate (MA). Hyperbranched ethene oligomers with different microstructures were generated using different metal species in ethene oligomerization. More importantly, hyperbranched ethene-MA co-oligomers with varying incorporation ratios were generated via ethene and MA co-oligomerization using the Pd(II) complexes. Most notably, weak neighboring group interactions of distal aryl motifs in the nickel system are more effective in influencing the microstructure of ethene oligomers than the corresponding palladium system.     

Termination of a pinned spiral wave by the wave train with a free defect

Nonlinear Dynamics - Spiral waves in the cardiac tissue may cause life-threatening arrhythmia. Such waves can be anchored to a local heterogeneity and form stable pinned waves, which are difficult...     

β-取代接酸的不对称合成

本文提出了一种合成光活性户取代按酸的新方法.本法利用芳醛和(一)丙二酸亚-(5,一甲基·2'一异丙基)环己醋(3)进行Knoevenagel缩合,生成(+)-5一亚怒基丙二酸亚(5'一甲基·2'·异丙基)环已醋(4).继而与Grignard试剂发生共扼加成,水解后即得光活性的刀·取代趁酸(6).     

多层复合壳体三维振动分析的谱——微分求积混合法

对于较厚的多层复合壳体,其振动位移沿厚度方向呈锯齿形变化且层间剪切和拉、压应力呈三维耦合状态,采用传统的等效单层理论分析已不能满足精度要求. 建立不受结构厚度、铺层材料性质和铺层方式限制的三维分析方法具有重要的研究价值. 本文以独立铺层为建模对象,结合广义谱方法与微分求积技术建立了一种适用一般边界条件和铺层方式的多层复合壳体三维分析新方法——谱--微分求积混合法. 该方法应用三维弹性理论对独立铺层进行精确建模,有效克服了二维简化理论对横向变形以及层间应力估计不确切的缺点;引入微分求积技术对铺层进行数值离散,将三维偏微分问题转化为二维偏微分问题,降低了求解维度和难度;应用广义谱方法近似地表述离散计算面上的场变量,将获取的二维偏微分方程转化为以场变量谱展开系数为未知量的线性代数方程组,避免了对超越方程的求解. 数值验证结果表明该方法收敛性好,计算精度高.      

Dynamics of spiral waves driven by a dichotomous periodic signal

We study the effects of a dichotomous periodic force on meandering and rigidly rotating spiral waves. For a meandering state, the periodic forcing induces more modulating frequencies according to the rules of frequency-locked relations and linear combinations. It can also generate some unique closed tip orbits. On the modulating period T-axis, there exist all kinds of resonant entrainment bands. Arnold tongues exist in the period-amplitude space. The width of entrainment bands is affected by the symmetry of positive and negative parts in each signal unit. In addition, appropriate choices of T-value can be used to eliminate spiral waves. For a rigidly rotating state, the periodic forcing can induce a transition toward meandering spiral waves via generating a transitive bidirectional spiral wave. It is very interesting that, after the transition, the meandering spiral wave has the same primary rotating period as the free meandering states.     

Quantification of glucose diffusion in human lung tissues by using Fourier domain optical coherence tomography

In this study, we report permeability coefficients of 30% glucose diffusion by the optical coherence tomography signal slope (OCTSS) method in four kinds of human lung tissue in vitro: normal lung tissue, benign granulomatosis lung tissue, squamous cell carcinoma and adenocarcinoma tumor. To quantify the permeability coefficient of the agent, the monitored region was 80 μm thickness at a tissue depth of ca 230 μm from the surface. The permeability coefficients of 30% glucose from 10 independent experiments were averaged and found to be (1.35 ± 0.13) × 10(-5) cm s(-1) from the normal lung tissue, (1.78 ± 0.21) × 10(-5) cm s(-1) from the benign granulomatosis lung tissue, (2.88 ± 0.19) × 10(-5) cm s(-1) from the adenocarcinoma tumor and (3.53 ± 0.25) × 10(-5) cm s(-1) from the squamous cell carcinoma, respectively. It could be clearly seen that the permeability coefficients of 30% glucose increase ca 32%, 113% and 162% in the benign granulomatosis, adenocarcinoma tumor and squamous cell carcinoma of human lung tissue compared with that from the normal lung tissue, respectively. Therefore, we inferred from this pilot study that the OCT imaging is a feasible method to distinguish normal and cancer lung tissue.     

CHAOTIC MOTIONS AND LIMIT CYCLE FLUTTER OF TWO-DIMENSIONAL WING IN SUPERSONIC FLOW

Based on the piston theory of supersonic flow and the energy method, the flutter motion equations of a two-dimensional wing with cubic stiffness in the pitching direction are established. The aeroelastic system contains both structural and aerodynamic nonlinearities. Hopf bifurcation theory is used to analyze the flutter speed of the system. The effects of system parameters on the flutter speed are studied. The 4th order Runge-Kutta method is used to calculate the stable limit cycle responses and chaotic motions of the aeroelastic system. Results show that the number and the stability of equilibrium points of the system vary with the increase of flow speed. Besides the simple limit cycle response of period 1, there are also period-doubling responses and chaotic motions in the flutter system. The route leading to chaos in the aeroelastic model used here is the period-doubling bifurcation. The chaotic motions in the system occur only when the flow speed is higher than the linear divergent speed and the initial condition is very small. Moreover, the flow speed regions in which the system behaves chaos axe very narrow.     

基于分布式体积速度传感的结构声辐射有源控制实验研究

以简支矩形薄板为研究对象,首先在波数域内对结构振动体积速度与辐射声功率的关系进行分析,推导出反映结构模态对体积速度贡献规律的数学表达式。在此基础上,结合PVDF (Polyvinylidene Fluoride)压电薄膜的电荷输出方程,利用三角函数的正交性,给出一种方法来设计体积速度传感器,并针对具体模型进行了结构体积速度测量实验。结果表明,所设计的分布式体积速度传感器具有较好的传感精度。在此基础上,利用所设计的传感器进行了结构声辐射有源控制实验研究,分别针对单频和带宽信号激励情况下的有源控制实验取得了满意的控制效果,从而验证了本文PVDF体积速度传感器设计方法的正确性以及通过PVDF膜传感结构声辐射并作为误差传感器进行有源控制的有效性。      

温度和流速对齐口裂腹鱼幼鱼呼吸代谢的影响

通过流水式呼吸仪研究了齐口裂腹鱼(Schizothorax prenanti)幼鱼在不同水温(11,15,20,23℃)和流速(0.00,0.10,0.30,0.50m/s)环境下的呼吸代谢.研究发现,齐口裂腹鱼幼鱼呼吸代谢率(MR)和单位体重呼吸代谢率(MR′)都随着温度的升高而增大.在11～23℃之间,代谢率的变幅为0.85～7.21mg/h,单位体重代谢率的变幅为350.81～1858.16mg/(kg·h).回归方程MR=a.mb能够较好的描述4个温度水平的幼鱼代谢率与体重之间的关系(p<0.05),体重指数b随着温度的升高而降低.并且在11～23℃之间,幼鱼的代谢率与温度、体重间的关系可通过模型MR=0.525m0.788.e0.033T(R2=0.907,p<0.05,n=32)较好地表征.在0.00,0.10,0.30,0.50m/s4个流速下裂腹鱼幼鱼呼吸代谢率的波动范围为0.59～2.35mg/h,单位体重代谢率波动范围为469.93～1281.56mg/(kg.h).各流速平均代谢率的大小顺序为0.937mg/h(0.10m/s)<1.089mg/h(0.00m/s)<1.104mg/h(...     

环域反馈下复Ginzburg-Landau系统的螺旋波动力学行为

针对自激振荡系统的复金兹伯格-朗道(Complex Ginzbury-Landau, 简称CGL)方程, 研究圆形环域与方形环域两种反馈控制下的螺旋波动力学。结果表明: 圆形环域反馈控制下, 螺旋波波头通常经过一段过渡漂移后进入圆形吸引子, 圆形吸引子的半径以及反馈刚启动时波头的漂移方向随环域参数呈周期性变化, 过渡漂移阶段波头轨道的平缓程度与复反馈信号模的时间函数中钟形部分的陡度有关, 且反馈增益的正负与大小也会影响受控螺旋波的动力学行为。方形环域反馈控制下的螺旋波波头的吸引子更为丰富, 主要包括方形吸引子、小的极限环吸引子、菱形吸引子以及点吸引子, 点吸引子通常位于方形环域的两条对角线上, 且波头运动随环域控制参数呈现规律性变换。