全文获取类型
收费全文 | 520篇 |
免费 | 54篇 |
国内免费 | 86篇 |
专业分类
化学 | 547篇 |
晶体学 | 1篇 |
力学 | 14篇 |
综合类 | 5篇 |
数学 | 20篇 |
物理学 | 73篇 |
出版年
2023年 | 2篇 |
2021年 | 1篇 |
2020年 | 3篇 |
2019年 | 1篇 |
2018年 | 2篇 |
2016年 | 1篇 |
2014年 | 29篇 |
2013年 | 49篇 |
2012年 | 44篇 |
2011年 | 7篇 |
2010年 | 3篇 |
2009年 | 4篇 |
2008年 | 21篇 |
2007年 | 19篇 |
2006年 | 17篇 |
2005年 | 18篇 |
2004年 | 31篇 |
2003年 | 38篇 |
2002年 | 85篇 |
2001年 | 198篇 |
2000年 | 31篇 |
1999年 | 20篇 |
1998年 | 11篇 |
1997年 | 9篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1987年 | 1篇 |
排序方式: 共有660条查询结果,搜索用时 16 毫秒
51.
1 INTRODUCTIONOrganophosphorus compounds are ubiquitous in nature and they have broad applications in the fields of agriculture and medicine. During the past two decades, (-ketophosphonates and their derivatives have attracted considerable attention because these compounds are endowed with special physical, chemical and pharmacological properties due to the proximity of the carbonyl and the phosphoryl groups[1~6]. For example, it is well known that phosphonoformic acid (PFA) is effectiv… 相似文献
52.
Wei Li YANG Jun TIAN Qiang ZHANG Shu Lin PENG Li Sheng DING* Chengdu Institute of Biology Chinese Academy of Sciences Chengdu School of Pharmacy West China University of Medical Sciences Chengdu 《中国化学快报》2001,(2)
There are only three species in the genus Diuranthera (Liliaceae), which is endemic in the southwest of China1. Four steroidal saponins, diuranthosides A-C and chloromalo-side A were isolated from the fresh roots of D. major. This paper deals with the structure elucidation of two new steroidal saponins, diuranthosides D and E, which were isolated from the methanolic extract of whole plant of D. inarticulata Wang et K. Y. Lang.Diuranthoside D (1), [(]-38 (c 0.08, pyridine), afforded galac… 相似文献
53.
Zhang Jing CHANG Wu Xiang YANG Cao Wei LIANG* Faculty of Science Beijing University of Chemical Technology Beijing 《中国化学快报》2001,(9)
Recently, the application of supercritical fluid technology is very interested, and it is applied in many areas for its special properties. The performance of supercritical fluid (SCF) as a solvent can be greatly affected by addition of an entrainer to the system. An entrainer can be added to a supercritical fluid to enhance its solvent strength and/or selectivity. Critical point data for these dilute supercritical fluid-cosolvent systems are imperative for the design of efficient separation … 相似文献
54.
Hong Ping HE Yun ZOU Yue Mao SHEN Xiao Yan HAO Guo Yin ZUO Xiao Jiang HAO * Laboratory of Phytochemistry Kunming Institute of Botany Chinese Academy of Sciences Kunming . Department of Medicinal Chemistry Guiyang Medical College 《中国化学快报》2001,(7)
Micromelum integerrimum (Rutaceae) is a shrub growing in Yunnan Province. Leaves and barks of this plant have been used for the treatment of dysentery, and arthritis1. Previous researches revealed that this plant contained coumarins2-8. Micromelin, the main chemical constituent of this plant, showed significant inhibition against leukaemia P-388 cell line (T/C 149% at 10 mg/kg) but was inactive in lower doses, and also showed significant activity (T/C 228% at 1.25 mg/kg) against Lewis lung… 相似文献
55.
You Zhi WAN Ying Hua LIU Ping XIE Rong Ben ZHANG* Department of Applied Chemistry School of Science Beijing University of Chemical Technology Beijing State Key Laboratory of Polymer Physics Chemistry Joint Laboratory of Polymer Science Materials Institute of Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2006,17(10):1361-1364
Ladder polysiloxanes (LPS) including both oxygen-bridged ladder polysilsesquioxanes (LPSQ) and organo-bridged ladder polysiloxanes (OLPS) are very important materials because of their excellent properties1. Adrianov et al. in 1960 attempted to prepare 1, … 相似文献
56.
Qingchun Li 《高等学校计算数学学报(英文版)》2007,16(4):341-347
In this paper,a compound-type inclusion interval of basic coneigenvalues of(com- plex)matrix is obtained.The corresponding boundary theorem and isolating theorem are given. 相似文献
57.
CHEN SHUXING * 《数学年刊B辑(英文版)》1997,(3)
CONSTRUCTIONOFSOLUTIONSTOM-DRIEMANNPROBLEMSFORA2×2QUASILINEARHYPERBOLICSYSTEMCHENSHUXINGManuscriptreceivedDecember26,1994.... 相似文献
58.
Li Jing FANG Jin Chun CHEN Guo Jun ZHENG Yu Kun GUAN Yu Lin LI* State Key Laboratory of Applied Organic Chemistry Institute of organic chemistry Lanzhou University Lanzhou 《中国化学快报》2004,(11)
The eudesmane derivative, (-)-10-epi-α-cyperone 1, is widely used as a chiral starting material for the synthesis of other fused-ring sesquiterpenes1. The first synthetic work was reported by Howe and co-workers via condensation of (+)-dihydrocarvone 2 with 1-diethylaminopentan-3-one methiodide in 32% yield2. Previously, our group reported the synthesis of compound 1 by treating ketone 2 with ethyl vinyl ketone (EVK) directly under different conditions1a, but the yields were not satisfacto… 相似文献
59.
Ling Tian TANG Yi WANG Xin Qi LIU Shao Wen HU Tai Wei CHU Xiang Yun WANG* College of Chemistry Molecular Engineering Peking University Beijing 《中国化学快报》2005,16(3):345-348
Benzimidazole compounds have attracted a renewed interest recently owing to theirpotential applications in high-performance composite materials, electronic chemicals,photosensitive materials, and their special potentials in biological and/or medicinalapplication1,2. Typically, aromatic compounds with near planar structures and contain-ing hydrogen-donor groups or groups, which are capable of being protonated, havespecial interactions with DNA via intercalation, hydrogen-bonding, and so on3.Me… 相似文献
60.
Hong Zhu * Patrick Phelan Tianhua Duan Gregory Raupp H. J. S. Fernando Beijing Institute of Microbiology Epidemiology Beijing P. R. China Department of Mechanical Aerospace Engineering Arizona State University Tempe Department of Chemical Materials Engineering Arizona State University Tempe *Author to whom correspondence should be addressed. Tel: -- E-mail: zhuhong@hotmail.com 《中国颗粒学报》2003,1(3):119-123
1.IntroductionBioaerosolsaremicroorganismsorparticles,gases,vapors,orfragmentsofbiologicalorigin(i.e.,aliveorreleasedfromalivingorganism)thatexistintheair.Bioaerosolsareeverywhereintheenvironment.Underfavorableconditions,bioaerosolsareabletogrowandpropagateonavarietyofbuildingmaterialsandindoorsurfaces,causingindoorairpollution.Therefore,owingtotheirubiquitouspresenceinnature,bioaerosolsasapollutionsourcearealmostinevitableinarangeofenclosedenvironmentsandincommunityair(Kodama&McGee,1986;Lig… 相似文献