石榴石磁泡膜中3类硬磁畴的形成方法

研究石榴石磁泡膜中硬磁畴畴壁中垂直布洛赫线的稳定性可为研制布洛赫线存储器提供有益的帮助 .3类硬磁畴的形成是研究硬磁畴稳定性的前提 .本文综述了在石榴石磁泡膜上形成硬磁畴的 2类方法———“脉冲偏场法”和“低直流偏场法” .结合文献中的典型样品 ,对用“脉冲偏场法”和“低直流偏场法”形成 3类硬磁畴的过程进行了简单介绍 .     

The influence of cation additives on the NIR luminescence intensity of Er³⁺-doped borate glasses

Er3+-doped 25BaO-(25-x)SiO2-xAl2O3-25B2O3 transparent glasses are prepared with x = 0,12.5 and 25 by a solid-state reaction.The Er-related NIR luminescence intensity,which corresponds to the transition of 4I15/2-4I13/2,is obviously altered with different silicon/aluminum ratios.The Judd-Ofelt parameters of the Er3+ ions are adopted to explain the intensity change in the NIR fluorescence,and the Raman scattering intensity versus the amount of Al and/or Si components are discussed.The spectra of the three samples are quite similar in the peak positions,but different in intensity.The maximal phonon density of state for the samples is calculated from the Raman spectra and is correlated to the NIR luminescence efficiency.     

模拟含双锌核的甲烷单加氧酶催化甲烷和乙烷羟基化理论研究

采用密度泛函B3LYP方法,研究含双锌核的甲烷单加氧酶催化底物CH3X (X=H,CH3) 羟基化的反应机理.用cis-(HCOO)(C3N2H4)Zn2(μ-O)2(COOH)(C3N2H4)(其中C3N2H4＝咪唑)模拟双锌核甲烷单加氧酶中的关键化合物Q.研究表明,反应通过自由基回弹机理发生.首先,底物CH3X (X=H,CH3)与Q中的一个桥形氧发生相互作用生成分子复合物QCH3X.然后,Q中的一个桥形氧进一步夺取底物中的氢原子,生成QH和XCH2双自由基.这两种双自由基很容易结合生成醇类分子复合物PXCH2OH,其中P= cis-(HCOO)(C3N2H4)Zn(μ-O)Zn(COOH)(C3N2H4).最后,分子复合物PXCH2OH脱去羟基化合物XCH2OH生成P.在298.15K和1atm的条件下,含双锌核甲烷单加氧酶Q催化CH4和CH3CH3羟基化反应在蛋白质溶液中的速率常数分别为6.414×10-19和1.542×10-6 dm3·mol-1·s-1.     

Ca@C88和Ca@C90的合成、分离和表征

利用直流电弧法,合成了含钙的富勒烯金属包合物.通过多步高效液相色谱（HPLC）法,首次分离出含钙的富勒烯金属包合物Ca@C88和Ca@C90 (I,II),用激光解析飞行时间质谱(MAL-DI-TOF MS)和紫外-可见-近红外（UV-Vis-NIR） 光谱进行了表征,并对其分子对称性和电子结构进行了讨论.     

注重特色与创新,建设具有海洋院校特色的物理实验室

实验室在建设与管理的过程中,仅注重设备的先进性和功能室的数量是不够的,还要注重建设与管理理念的准确定位。我校物理实验室以正确合理的理念为指导,注重特色,敢于创新,使实验室的建设与管理与我校具体实际情况相适应,取得了突出的成绩。     

单晶Pb纳米线及纳米粒子的溶液法制备

采用溶液法制备了较高长径比(～100)的铅的均匀纳米线及纳米粒子,并对产物进行了XRD,SEM和TEM表征.探讨了反应温度、反应物浓度及还原剂种类对产物成相及形貌的影响,初步讨论了铅钠米线的形成机制.     

Long-Time Asymptotics for the Nonlocal MKdV Equation

In this paper, we study the Cauchy problem with decaying initial data for the nonlocal modified Korteweg-de Vries equation(nonlocal mKdV) qt(x, t)+qxxx(x, t)-6 q(x, t)q(-x,-t)qx(x, t) = 0, which can be viewed as a generalization of the local classical mKdV equation. We first formulate the Riemann-Hilbert problem associated with the Cauchy problem of the nonlocal mKdV equation. Then we apply the Deift-Zhou nonlinear steepest-descent method to analyze the long-time asymptotics for the solution of the nonlocal m KdV equation. In contrast with the classical mKdV equation,we find some new and different results on long-time asymptotics for the nonlocal mKdV equation and some additional assumptions about the scattering data are made in our main results.     

Room-Temperature Ferromagnetic ZnMnO Thin Films Synthesized by Plasma Enhanced Chemical Vapour Deposition Method

Room-temperature ferromagnetic Mn-doped ZnO films are grown on Si （001） substrates by plasma enhanced chemical vapour deposition （PECVD）. X-ray diffraction measurements reveal that the Znl-xMn.O films have the single-phase wurtzite structure. X-ray photoelectron spectroscopy indicates the existence of Mn^2＋ ions in Mndoped ZnO films. Furthermore, the decreasing additional Raman peak with increasing Mn-doping is considered to relate to the substitution of Mn ions for the Zn ions in ZnO lattice. Superconducting quantum interference device （SQUID） measurements demonstrate that Mn-doped ZnO films have ferromagnetic behaviour at room temperature.     

CdSe/CdS核壳纳米晶微波水热法一步合成与发光光谱分析

采用微波水热法一步合成了核壳结构的CdSe/CdS纳米晶,讨论了巯基丙酸中S^2-的释放过程对纳米晶生长的影响。XRD和Raman光谱结果表明,140℃合成温度下获得了CdSe/CdS核壳结构的纳米晶。FTIR光谱结果表明,巯基丙酸随时间的分解有助于CdS壳层的形成。PL光谱呈现出CdSe纳米晶的带间发射和缺陷发射,随着核壳结构的形成,CdSe纳米晶的表面缺陷被抑制,相关的荧光发射减弱。