Bianchi type-V model with a perfect fluid and A-term

A self-consistent system of gravitational field with a binary mixture of perfect fluid and dark energy given by a cosmological constant has been considered in Bianchi Type-V universe. The perfect fluid is chosen to be obeying either the equation of state p=γρ with γ ε |0,1| or a van der Waals equation of state. The role of A-term in the evolution of the Bianchi Type-V universe has been studied.     

Mössbauer hyperfine interactions in natural wolframites

Powdered samples of Indian Natural Wolframites, (Fe_xMn_1?x) WO₄ with x=0.95 to 0.41, obtained from seven different locations of two quartz-wolframite deposits of Degana and Sirohi in Rajasthan, have been investigated by Mössbauer spectroscopy down to 20K and magnetic susceptibility down to 77K. The Mössbauer spectra from 300K to 30K clearly indicate multiple sites which is at variance with the reported work. Below 50K a weak magnetic interaction with H_int～45Koe is observed. The spectra above transition temperature are resolved in three doublets and explained on the basis of reported crystal structure. The values of isomer shift, quadrupole splitting and magnetic hyperfine field have been attributed to high spin ferrous ions with octahedral symmetry. Relatively small value of Q.S. (～1.5 mm/sec. at 300K) indicate a strong contribution of the lattice term to the electric field gradient.     

Why chaos is rarely observed in natural populations

An attempt has been made to understand why chaotic dynamics have received poor evidential support from field studies. Our study opens up the possibility that the cause of failure might not be poor quality of data, as pointed out by earlier authors, but an ecological reality. We have designed two model food chains to examine whether there is a biological basis for the crisis. This investigation is effected with the help of a new method which we introduce at an appropriate place in the text. The fact that chaos exists in a narrow range of parametric values in both the model systems suggests that the crisis indeed has a biological origin.     

A highly selective and sensitive thorium(IV) PVC membrane electrode based on a dithio-tetraaza macrocyclic compound.

A poly(vinyl chloride)-based membrane composed of dithio-tetraaza macrocyclic compound as a neutral carrier with sodium tetraphenylborate (NaTPB) as an anion excluder and nitrobenzene (NB) as plasticizer was prepared and investigated as a Th(IV)-selective electrode. The electrode exhibits a Nernstian slope of 14.2 +/- 0.3 mV per decade over a wide concentration range (1.0 x 10(-6) to 1.0 x 10(-1) M) with a detection limit of 8.0 x 10(-7) M between pH 3.5 and 9.5. The response time of the sensor is about 10 s and it can be used over a period of 5 months without any divergence in potential. The proposed membrane sensor revealed a good selectivity for Th(IV) over a wide variety of other metal ions and proved to be a better electrode in many respects than those reported in the literature. It was successfully applied as an electrode indicator as well as in the direct determination of thorium ions in standard and real samples.     

A high spin isomer in 153Eu

A search for new isomers of nanosecond lifetimes were carried out in ¹⁵³Eu via the ¹⁵⁰Nd(⁷Li,xnγ) reaction. The single particle angular momentum alignment and dynamical moment of inertia estimated from the experimental data indicate a configuration change at rotational energy ħω∼ 0.30 MeV. A decrease of B(E2) values is also observed at the same frequency. An isomeric level is identified at an excitation energy of 3100 keV (J^π=35/2⁻) which corresponds to this frequency. The lifetime of the level is found to be 8.6 ± 1.3 nanosecond. Received: 22 April 1997 / Revised version: 26 September 1997     

PIC simulation of effect of energy-dependent foil transparency in an axially-extracted vircator

We have performed two-dimensional, relativistic, electromagnetic, particle-in-cell simulations for an axially extracted vircator. With a copper foil anode, the output frequency of the vircator is found to be strongly dependent upon the variation of foil transparency with electron energy. Using an average transparency for all electron energies yields results that are markedly different from those obtained using the actual variation. However, the output power shows only mild sensitivity. Using the full energy-dependent form of the transparency, we get fairly good agreement with published experimental results. Increasing the energy resolution for the calculation of foil transparency increases the accuracy of calculation of the dominant frequency, although the frequency tends to saturate beyond a certain resolution. However, an increase in the resolution must necessarily be accompanied by an increase in the number of simulation particles, in order to limit statistical fluctuations to an acceptable level. A physical explanation has also been provided for these trends.     

Study of interactions of various ionic species with solvents toward the design of receptors

In earlier studies, the interactions of isolated ionic species with various solvents were investigated using ab initio calculations. The ionic species investigated included cations (proton, hydronium, ammonium, and metal cations) and anions (single electron, hydroxide, and halide anions). However in the present study, we investigate the interactions of these ionic species with the solvent in the presence of other competing ionic species. We also elaborate on how the information obtained from these extensive studies have been employed in designing and synthesizing various kinds of novel ionophores and receptors.     

Superconductivity and normal state resistivity of Ba0.6K0.4BiO3: an optical phonon approach

We discuss the nature of the pairing mechanism and the physical properties associated with the normal as well as the superconducting state of cubic perovskites Ba_0.6K_0.4BiO₃using the strong coupling theory. An interaction potential which includes the Coulomb, electron–optical phonon and electron–plasmon interactions is developed to elucidate the superconducting state. A model dielectric function is constructed with these interactions fulfilling thef-sum rule. The screening parameter (μ^* = 0.26) infers the poor screening of charge carriers. The electron–optical phonon strength (λ) estimated as 0.98 is consistent with an attractive electron–electron interaction and supports the moderate to strong coupling theory. The superconducting transition temperature of Ba_0.6K_0.4BiO₃is then estimated as 32 K. Ziman's formula of resistivity is employed to analyse and compare this with the temperature-dependent resistivity of a single crystal. The estimated contribution from the electron–optical phonon together with the residual resistivity clearly infers a difference when a comparison is made with experimental data. The subtracted data infer a quadratic temperature dependence in the temperature domain (30 ≤ T ≤ 200 K). The quadratic temperature dependence of ρ [ = ρ_exp − (ρ₀ + ρ_e–ph)] is understood in terms of 3D electron–electron inelastic scattering. The presence of these el–el and el–ph interactions allows a coherent interpretation of the physical properties. Analysis reveals that a moderate to strong coupling exists in the Ba_0.6K_0.4BiO₃system and the coupling of electrons with the high-energy optical phonons of the oxygen breathing mode will be a reason for superconductivity. The implications of the above analysis are discussed.     

Antimicorbial effects of newly synthesized organotin(IV) and organolead(IV) derivatives

Triorganotin(IV) and triorganolead(IV) derivatives of the types Me₃Sn(SCZ) and Ph₃Pb(SCZ) (where SCZ^? is the anion of a semicarbanzone ligand) have been synthesized by substitution reactions of trimethyltin chloride and triphenyl-lead chloride with semicarbazones derived from heterocyclic ketones. The resulting complexes have been characterized by elemental analyses, molecualr weight determinations and conductivity measurements. The mode of bonding has been established on the basis of infrared and ¹H, ¹³C and ¹¹⁹Sn NMR spectroscopic studies. Some respresentative complexes have also been evaluated for their antimicrobial effects on different species of pathogenic fungi and bacteria; the results of these investigations have been reported in the present paper.     

Radiating viscous universes coupled with zero-mass scalar field: Exact solutions

The dynamics of a radiating viscous fluid universe coupled with zero-mass scalar field is investigated in the Einstein formalism and two exact solutions are obtained. Both the solutions give expanding models. Their many physical and geometrical properties are studied. The model universe corresponding to the first solution turns out to be a big bang model. The second model shows an interesting feature of absorbing radiation rather than emitting it under certain conditions.