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单分散交联聚(4—乙烯吡啶/丙烯酸丁酯)无皂正电性共聚乳胶 总被引:2,自引:0,他引:2
以偶氮二异丙基脒盐酸盐(V50)为引发剂,采用4-乙烯吡啶(4-VP)/丙烯酸丁酯(BA)为混合单体,分别以二乙烯苯(DVB)或双甲基丙烯酸乙二醇酯(EGDMA)为交联剂,用无皂乳液聚合的方法合成了一系列正电性共聚乳液,并用扫描电镜(SEM)、Zeta电位测定仪详细研究了单体配比、交联剂种类和交联度对粒径大小及其分布、粒子形态和乳液电性能的影响,并探讨了该三元无皂乳液聚合的成核机理。结果表明:4VP/BA的无皂乳液聚合遵循均相成核机理。当BA含量低或者微球交联度较小时,高分子亲水性强,临界链长度大,生成粒子数目少,所以粒径大;随着BA含量的增加或者交联度的增大,高分子疏水性增强,临界链长度沽小,生成粒子数目增多,粒径变小,当BA/4VP=1/4(g/g)时,得到单分散共聚乳胶,少量BA与4VP共聚可以明显提高乳液的稳定性。 相似文献
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胶束电动毛细管色谱检测鱼肉中的七种生物胺 总被引:4,自引:1,他引:3
建立了一种利用胶束电动毛细管色谱同时检测鱼肉中组胺、腐胺、2-苯乙基胺、尸胺、色胺、亚精胺及精胺7种生物胺的方法。样品经6%过氯酸萃取后,由苯甲酰氯衍生化,以含0.06 mol/L脱氧胆酸钠的0.02 mol/L硼酸(pH 9.2)-甲醇(体积比为95∶5)混合液为电泳介质,电泳电压25 kV,温度25 ℃,检测波长214 nm,在12 min内实现了7种生物胺的完全分离。7种生物胺的浓度与其峰面积在一定的范围呈良好的线性关系,检出限除组胺为15 μg/g外,其余均为5 μg/g。迁移时间和峰面积的日内、日间相对标准偏差均小于5%。该法用于海鱼中7种胺类物质含量的测定,结果令人满意。 相似文献
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类科尔介质中受激辐射场的量子统计性质 总被引:3,自引:1,他引:2
本文讨论类科尔介质腔中场模与三能级原子相互作用时辐射场的量子统计性质。结果表明,介质与场模的相互作用使场模与原子的相互作用减弱,光子一般不表现反聚束性质,辐射场服从超亚泊松统计分布。 相似文献
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Chengqian Yuan Mengyao Yang Xiaokang Ren Qianli Zou Xuehai Yan 《Angewandte Chemie (International ed. in English)》2020,59(40):17456-17460
Understanding and controlling multicomponent co‐assembly is of primary importance in different fields, such as materials fabrication, pharmaceutical polymorphism, and supramolecular polymerization, but these aspects have been a long‐standing challenge. Herein, we discover that liquid–liquid phase separation (LLPS) into ion‐cluster‐rich and ion‐cluster‐poor liquid phases is the first step prior to co‐assembly nucleation based on a model system of water‐soluble porphyrin and ionic liquids. The LLPS‐formed droplets serve as the nucleation precursors, which determine the resulting structures and properties of co‐assemblies. Co‐assembly polymorphism and tunable supramolecular phase transition behaviors can be achieved by regulating the intermolecular interactions at the LLPS stage. These findings elucidate the key role of LLPS in multicomponent co‐assembly evolution and enable it to be an effective strategy to control co‐assembly polymorphism as well as supramolecular phase transitions. 相似文献
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Yang F Long Y Shen R Chen C Pan D Zhang Q Cai Q Yao S 《Journal of separation science》2011,34(6):716-723
C18-functionalized magnetic microspheres synthesized in a three-stage system and characterized by Fourier transform infrared (FTIR) spectroscopy and SEM were applied for clean-up and enrichment of polycyclic aromatic hydrocarbons (PAHs) in soil samples combined with ultrasonication extraction. Magnetic solid-phase extraction (MSPE) parameters, such as elution solvents, amounts of sorbents, enrichment time and organic modifier, were optimized together with ultrasonication time and extraction solvents. Under the optimal conditions, the developed method provided spiked recoveries of 63.2-92.8% with RSDs of less than 6.4% and limits of detection were 0.5-1.0 ng/g. This new method provides several advantages, such as high extraction efficiency, convenient extraction procedure and short analysis times. Finally, the method was successfully applied to the determination of polycyclic aromatic hydrocarbons in soil samples. 相似文献
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Shizheng Zhu Guoling Xu Chaoyue Qin Xu Yong Chu Qianli Darryl D. DesMarteau 《Heteroatom Chemistry》1999,10(2):147-151
Halogenation of the potassium or silver salts of bis((trifluoromethyl)sulfonyl)methane(CF3SO2)2CH2 and its cyclo analogues (CF2)nSO2‐CH2SO2CF2 with N‐fluoro‐bis((trifluoromethyl)sul‐fonyl)imine (CF3SO2)2NF, chlorine or bromine gave good yields of the corresponding α‐halo disulfones (CF3SO2)2CHX and (CF2)nSO2CHXSO2CF2 (X: F, Cl, Br; n = 1,2). Some chemical transformations of these fluorinated α‐halo‐disulfones are described. © 1999 John Wiley & Sons, Inc. Heteroatom Chem 10: 147–151, 1999 相似文献
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Ethylenediamine reacted readily with 4‐ethoxy‐1,1,1‐trifluoro‐3‐butene‐2‐one to form 5‐trifliuoromethyl‐2,3‐dihydro‐1,4‐diazepine in good yield. Under the same reaction conditions, o‐phenylenediamine gave 2‐trifluoromethylbenzimidazole and benzimidazole. © 2000 John Wiley & Sons, Inc. Heteroatom Chem 11:27–30, 2000 相似文献