利用慢度曲面研究立方晶系晶体的铁弹相变

讨论了慢度曲面与声学模软化之间的关系.立方晶系晶体声学模的软化即对应其在某一方向上的最大慢度,软模的本征矢的方向即为与最大慢度相对应的声学模的偏振化方向.通过求解Christoffel方程可找到某些方向上的最大慢度和与它们对应的声学模的偏振化方向.从而晶体在本征铁弹相变前后结构对称性的变化可以通过分析Christoffel方程的解及利用居里原理来确定.     

用粉煤灰和高岭土混合原料合成β-Sialon粉体

以粉煤灰、高岭土混合物为原料,采用碳热还原氮化法制备了不同z值的β-Sialon粉体.研究了原料组成(Si/Al值)、活性炭配量以及反应温度对合成产物物相的影响.利用X射线衍射仪分析产物物相的组成,用扫描电子显微镜对产物的显微形貌进行分析.结果表明,当原料中Si/Al值为1.5,配炭量过量100;时,在1450℃保温6h条件下,可以合成主要物相为Si3Al3O3N5(β-Sialon,z=3)的粉体,粉体的显微形貌呈现纤维状;当原料中Si/Al值为1.7,配炭量过量150;时,在1450℃保温6h条件下,可以制备主要物相为Si4Al2O2N6(β-Sialon,z=2)的粉体,粉体的显微形貌呈现纤维状和板状.     

Spiral Cyclization of a-Carbonyl Radicals

α-Carbonyl radicals cyclization reactions have been applied successfully toward total synthesis of several natural products,such as modhephene,¹ (-)-dendrobine,² and (-)-5-oxosiphiperfol-6-ene.³     

Periodic interstellar scintillation variations of PSRs J0613-0200 and J0636+5128 associated with the Local Bubble shell

Annual variations of interstellar scintillation can be modelled to constrain parameters of the ionized interstellar medium. If a pulsar is in a binary system, then investigating the orbital parameters is possible through analysis of the orbital variation of scintillation. In observations carried out from 2011 to 2020 by the European Pulsar Timing Array radio telescopes, PSRs J0613-0200and J0636+5128 show strong annual variations in their scintillation velocity, while the former additionally exhi...     

Best practices for electrochemical characterization of supercapacitors

We discuss here essential aspects of the experimental supercapacitors characterization by a series of well-known electrochemical methods. We are motivated by a considerable number of publications that misreport procedures and results. Authors often conceal or neglect essential information about the electrochemical analytical apparatus used and its configuration. The lack of such information may lead researchers, especially inexperienced ones, to misunderstand the procedures and results. Eventual...     

The development of machine learning-based remaining useful life prediction for lithium-ion batteries

Lithium-ion batteries are the most widely used energy storage devices, for which the accurate prediction of the remaining useful life(RUL) is crucial to their reliable operation and accident prevention. This work thoroughly investigates the developmental trend of RUL prediction with machine learning(ML) algorithms based on the objective screening and statistics of related papers over the past decade to analyze the research core and find future improvement directions. The possibility of extending...     

Ion dynamics into different pore size distributions in supercapacitors under compression

Compressing supercapacitor(SCs) electrode is essential for improving the energy storage characteristics and minimizing ions’ distance travel, faradaic reactions, and overall ohmic resistance. Studies comprising the ion dynamics in SC electrodes under compression are still rare. So, the ionic dynamics of five aqueous electrolytes in electrodes under compression were studied in this work for tracking electrochemical and structural changes under mechanical stress. A superionic state is formed when ...     

光深对大质量恒星形成团块化学性质研究的影响

本文使用文献中的N₂H⁺(1-0)、H¹³CO⁺(1-0)、HCN(1-0)和HN¹³C(1-0)谱线数据研究大质量恒星形成团块的化学性质和演化,发现H¹³CO⁺和HN¹³C的丰度受H₂柱密度的影响. 由于从A阶段到B阶段这两个丰度的中值增加了近10倍,H¹³CO⁺和HN¹³C适合追踪大质量恒星形成团块的演化. 从A到B阶段四种分子丰度增长速度从高到低依次为H¹³CO⁺、HCN、HN¹³C、N₂H⁺. 结果表明进行光学薄分子谱线的高分辨率观测对于研究大质量恒星形成团块的化学演化是必要的.