有机电致发光材料噁二唑衍生物的合成

由酰氯与各种酰肼反应得到中间体4，进而用三氯氧磷脱水闭环，合成了一系 列1，3，4-噁二唑衍生物5，用~1H NMR，IR，MS和元素分析对其结构进行了确证。     

芳并呋喃类化合物的—锅化合成法

本文报道用KF/Al_2O_3作为碱催化剂,由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4,4’-二氯甲基联苯和1,5-二氯甲基萘等进行一锅化缩合反应,以38～89％的产率合成了14种芳并呋喃化合物。     

铜胺络合物作用下取代2-萘酚的交叉偶合反应

在铜(II)-胺络合物作用下, 取代2-萘酚化合物进行交叉偶合反应, 得到几种结构新颖的取代1,1'-联-2-萘酚化合物, 产率44%～90%. 化合物的结构经过核磁、红外光谱及质谱进行确证.     

Synthesis of Chiral 1,3-Bis(oxazolinyl)benzene

In recent years, C₂-symmetric chiral bis (oxazoline) ligand-metal complexes have received a great of attention through their use in various catalytic processes^[1-2]. Since the early 1990s, many impressive enantioselective carbon-carbon bond forming reactions, aziridination reactions, hydrosilylations, oxidations and reductions have been recorded using bis (oxazoline)-metal complexes with wide structural diversity^[3-4]. The latest review is intended to focus on the recent developments of bis(oxazoline) ligand-metal catalyzed asymmetric reactions and their applications in organic synthesis. Herein we intend to report the synthesis of a new type of chiral bis(oxazoline), 1,3-bis(oxazolinyl)benzene. Application of their asymmetric catalysis is under working.     

取代1,1'-联-2-萘酚在铜胺络合物催化作用下的氧化反应

用CuCl₂•2H₂O与小分子的有机胺形成络合物, 模拟氧化还原酶对多米诺式反应(Domino reaction)进行催化反应, 在氧气存在条件下, 取代1,1'-联-2-萘酚化合物被氧化为二苯并呫吨类化合物, 产物的结构经核磁共振、红外光谱及质谱进行确证.     

二苯并呫吨类化合物的环氧化反应研究

研究了二苯并呫吨类化合物的环氧化反应条件, 在室温、碱性条件下, 用廉价的H₂O₂作为环氧化剂对二苯并呫吨类化合物进行环氧化, 产率高达91%～98%, 是一种简便合成环氧二苯并呫吨类化合物的方法.     

Synthesis of Chiral 2,5—Bis（oxazolinyl） thiophenes and Their Application as Chiral Shift Reagents for 1,1′—Bi—2—naphthol

A series of C2-symmetrical chiral 2,5-bis (4′-alkyloxazolin-2-yl) thiophenes (thiobox) have been synthesized from thiophene-2,5-dicarboxylic acid by sequential amidation with a chiral ethanolamine,conversion of hydroxyl to chloro group, and base-promoted oxazoline ring formation.As demonstrated by (-)-2,5-bis[4′-(S)-isopropyloxazolin-2′-yl] thiophene,these thiobox systems exhibited remarkable chirality recognition of 1,1′-bi-2-naphthol giving rise to pronounced shifts in the ^1H NMR signals of the latter axial chiral compound at the positions of C-3,C-4,C-5,and C-8.     

3,4-二羟基-2,5-双[2′-(4′-取代噁唑啉)]呋喃的合成及其应用

3;4-二羟基-2;5-双[2′-(4′-取代噁唑啉)]呋喃的合成及其应用;二羟基双 [(取代噁唑啉)]呋喃;双噁唑啉;手性试剂;不对称还原;合成