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11.
Wenyue?Gao Pan?Hui Liming?Qi Zhongyuan?Liu Wei?ZhangEmail author Guobao?XuEmail author 《Mikrochimica acta》2017,184(3):693-697
A simple method is described for the determination of copper(II) ions based on the cathodic electrochemiluminescence (ECL) of lucigenin which is quenched by Cu(II). The blue ECL is best induced at ?0.45 V (vs. Ag/AgCl) at a scan rate of 50 mV·s?1. Under optimum conditions, the calibration plot is linear in the 3.0 to 1000 nM Cu(II) concentration range. The limit of detection is 2.1 nM at a signal-to-noise ratio of 3. Compared to other analytical methods, the one presented here is simple, fast, selective and cost-effective. It has been successfully applied in the analysis of copper ions in spiked tap water samples with recoveries ranging from 93.0% (at 50 nM concentration) to 105.7% (at 150 nM). 相似文献
12.
以三芳基六氟磷酸硫鎓盐为引发剂,钛酸四异丙酯(TIP)为无机前驱体,3,4-环氧环己基甲基3,4-环氧环己基甲酸酯为单体,制备了含TiO2纳米结构的紫外光固化阳离子复合胶粘剂。通过原子力显微镜对复合胶粘剂形貌进行表征,研究了TIP含量对胶粘剂折射率和光透过率的影响。结果表明:TiO2无机相均匀地分散在胶粘剂的聚合物基体中,平均粒径约为20 nm;随着体系中TIP质量分数的变化,复合胶粘剂折射率为1.510 3~1.540 9可调;胶粘剂的光透过率随TIP质量分数增加略有减低,但当TIP含量高达40%时,光透过率维持在90%左右。 相似文献
13.
Jianxin Chen Dr. Chunyang Yu Dr. Zengqian Shi Songrui Yu Prof. Zhongyuan Lu Wengfeng Jiang Meng Zhang Prof. Wei He Prof. Yongfeng Zhou Prof. Deyue Yan 《Angewandte Chemie (International ed. in English)》2015,54(12):3621-3625
Well‐defined ultrathin nanotubes (30 nm in diameter and of micrometer‐scale length) were generated through the self‐assembly of a novel alternative copolymer synthesized using an epoxy–thiol click‐chemistry reaction. The self‐assembly mechanism was investigated both by experiments and using dissipative particle dynamics (DPD) simulations. The obtained nanotubes can be readily functionalized with carboxy groups, amino groups, peptides, or other groups by simple modular click copolymerization. 相似文献
14.
Experimental Investigation on Binary Phase Diagram of the Thermotropic Phase Transitions Compounds (n‐CnH2n+1R3)2ZnCl4 下载免费PDF全文
The thermotropic phase transitions compounds (n‐CnH2n+1R3)2ZnCl4 as well as a series of their binary mixtures were prepared by a solution reflux method from their ethanol solutions. The experimental subsolidus binary phase diagram of [n‐C18H37N(CH3)3]2ZnCl4‐[n‐(C18H37)2N(CH3)2]2ZnCl4 is constructed over the entire composition range by differential scanning calorimetry(DSC) and X‐ray. Experi‐ mental results indicate one stable intermediate phase [n‐C18H37N(CH3)3] [n‐(C18H37)2N(CH3)2]ZnCl4 at WC18C3Zn %=59.75 %, and two invariant three phase equilibria, which shows two eutectoid temperatures: Te1 at 310±1 K for eutectoid point WC18C3Zn %=36.24 %, Te2 at 313±1 K for eutectoid point WC18C3Zn %=80.17 %. These three noticeable solid‐solution ranges are α‐phase at the left, ?‐phase at the right, and ψ‐phase in the middle of the phase diagram. It is (n‐CnH2n+1R3)2ZnCl4 systems as phase change materials that are characterized the phase transition temperatures T in the range of 310 to 340 K, the transition enthalpies ΔH in the range of 38.40 and 168.72 J/g between two polymorphic forms. 相似文献
15.
Xianyue Han Zhongyuan Liu Dongli Yu Shengwei Xin Julong He Bo Xu Yongjun Tian 《Solid State Communications》2010,150(29-30):1317-1320
The temperature-dependent resistivity of a pure CaB4 single crystal has been observed to demonstrate metal-conducting behavior. The normal Hall-coefficient measurement is indicative of the electrons as the conducting carriers with a room-temperature density of 4.7×1021 cm?3. The observed metal-conducting behavior can be understood using a simple model, in which the Ca ions are treated as independent Einstein harmonic oscillators embedded in a Debye rigid boron network. The ab initio calculations of band structure and density of states corroborate the experimentally observed metal-conducting behavior of CaB4, showing that it originates mainly from the p orbital of B atom and the hybridized d orbital of Ca atom. 相似文献
16.
Zhongyuan Che 《Czechoslovak Mathematical Journal》2010,60(2):489-494
We give a necessary and sufficient condition for the existence of perfect matchings in a plane bipartite graph in terms of
elementary edge-cut, which extends the result for the existence of perfect matchings in a hexagonal system given in the paper
of F. Zhang, R. Chen and X. Guo (1985). 相似文献
17.
在二重极限存在的情况下给出累次极限的一个刻画,探讨两者之间的内在联系,并将这种方法应用于处理二重积分与累次积分以及其它一些问题. 相似文献
18.
Liang Jingshuang Yang Yulin Gao Jian Zhou Lei Gao Ming Zhang Zhongyuan Yang Wenfei Javid Muhammad Jung Youngguan Dong Xinglong Cao Guozhong 《Journal of Solid State Electrochemistry》2019,23(3):735-748
Journal of Solid State Electrochemistry - Polymorphic Si-Cu nanocomposites of Si@Cu3Si nanowires, Si@Cu3Si nanorods, and Si@Cu3Si(Cu) nanocapsules are synthesized via the high-energy arc-discharge... 相似文献
19.
Zhongyuan Liu 《Mathematical Methods in the Applied Sciences》2016,39(12):3461-3477
In this paper, we study the following biharmonic equation where , K(1) > 0,K′(1) > 0, B1(0) is the unit ball in (N≥6). We show that the aforementioned problem has infinitely many peak solutions, whose energy can be made arbitrarily large. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
20.
本文提出计算芘系芳烃共振能的苯环计数(BRC)公式,并结合母子加和(PPC)公式共计算了34个芘系烃的共振能。结果表明,芘系的BRC公式对省系的BRC公式有继承性。包括芘系在内的91个芳烃的REPEBRC,和REPEBRC-PPC与第一电离势能IP1之间仍保持较好的线性关系,r=0.9405(91),S=0.1 相似文献