全文获取类型
收费全文 | 3220篇 |
免费 | 531篇 |
国内免费 | 335篇 |
专业分类
化学 | 2109篇 |
晶体学 | 34篇 |
力学 | 260篇 |
综合类 | 27篇 |
数学 | 386篇 |
物理学 | 1270篇 |
出版年
2024年 | 4篇 |
2023年 | 71篇 |
2022年 | 91篇 |
2021年 | 141篇 |
2020年 | 140篇 |
2019年 | 124篇 |
2018年 | 103篇 |
2017年 | 103篇 |
2016年 | 176篇 |
2015年 | 164篇 |
2014年 | 205篇 |
2013年 | 235篇 |
2012年 | 318篇 |
2011年 | 321篇 |
2010年 | 224篇 |
2009年 | 222篇 |
2008年 | 202篇 |
2007年 | 183篇 |
2006年 | 179篇 |
2005年 | 142篇 |
2004年 | 117篇 |
2003年 | 79篇 |
2002年 | 69篇 |
2001年 | 64篇 |
2000年 | 48篇 |
1999年 | 68篇 |
1998年 | 42篇 |
1997年 | 37篇 |
1996年 | 35篇 |
1995年 | 31篇 |
1994年 | 25篇 |
1993年 | 21篇 |
1992年 | 20篇 |
1991年 | 18篇 |
1990年 | 23篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 7篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1981年 | 3篇 |
1974年 | 1篇 |
1971年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有4086条查询结果,搜索用时 15 毫秒
61.
62.
63.
64.
Geng Xu 《Transactions of the American Mathematical Society》1996,348(7):2725-2736
Let be a generic complete intersection of hypersurfaces of degree in -dimensional projective space. We study the question when a divisor on is nonrational or of general type, and give an alternative proof of a result of Ein. We also give some improvement of Ein's result in the case .
65.
66.
67.
Adsorption enthalpy and desorption enthalpy during displacement of adsorbate to solvent in a liquid-solid system 总被引:6,自引:0,他引:6
Xinpeng Geng Tongshan Han Chen Cao 《Journal of Thermal Analysis and Calorimetry》1995,45(1-2):157-165
The adsorption heat of the stoichiometric displacement process for the adsorption of a solute in a liquid-solid system was
investigated. On the basis of the SDM-A and the rule of the additivity of energy, an expression which describes the dependence
of the adsorption enthalpy on the nature and concentration of the solute, and on the solvent and adsorbent, was derived. The
adsorption heat determined for the solute with the traditional method can be divided into two independent fractions, relating
to the adsorption of the solute and to the desorption of the solvent. Experimental data on both isotherms from the literatures
and precise calorimetry were used to test the adsorption heat and its fractions computed quantitatively via the equations
presented in this study, and a satisfactory degree of conformity between them was obtained.
Supported by the Natural Science Foundation of Shaanxi Province in China. 相似文献
68.
Jingfei Luan Zhigang Zou Minghui Lu Guoyou Luan Yanfeng Chen 《Research on Chemical Intermediates》2006,32(1):31-42
In2BiTaO7 was synthesized using the solid-state reaction method and its photocatalytic properties were investigated. The results of
powder X-ray diffraction (XRD) indicated that the compound crystallizes in the pyrochlore-type structure, cubic system with
space group Fd-3m. The lattice parameter is 10.6972(1) ?. In addition, the compound shows strong optical absorption in the
visible region (λ > 420 nm) and the band gap of In2BiTaO7 was estimated to be about 2.47 eV. For the photocatalytic reaction, H2 or O2 evolution was observed from CH3OH/H2O or AgNO3 solution respectively with In2BiTaO7 as the photocatalyst under visible light irradiation, indicating that In2BiTaO7 is responsive to visible light for splitting water. Furthermore, the catalyst remained photoactive in the wavelength range
up to 510 nm. Photocatalytic degradation of methylene blue (MB) dye over the compound was further investigated under visible
light irradiation. The results showed that complete removal of aqueous MB could be achieved after irradiation for 135 min
over In2BiTaO7. Furthermore, under visible light irradiation In2BiTaO7 showed markedly higher catalytic activity compared to P-25 for MB photocatalytic degradation. 相似文献
69.
以硝酸铽、苯乙酮酸(HL), 2, 2'-联吡啶(dipy)、 1, 10-菲啰啉(phen)和三苯基氧膦(TPPO)合成了TbL3dipy(H2O)2, TbL3phen(H2O)2和TbL2(TPPO)2NO3 3种新型固态配合物. 用元素分析、电导率、红外光谱和核磁共振谱对其进行了表征, 确定了配合物的组成. IR表明, 配合物中羧酸根可能以单齿方式配位. 1HNMR显示, 苯乙酮酸根配位后苯环上5个氢原子的化学位移移向高场. 室温下测定了配合物的荧光激发光谱, TbL3dipy(H2O)2, TbL3phen(H2O)2和TbL2(TPPO)2NO3最佳激发波长分别为361.0, 359.0和367.0 nm;分别以最佳激发波长测定了配合物的发射光谱, 配合物TbL3dipy(H2O)2, TbL3phen(H2O)2 和TbL2(TPPO)2NO3显示Tb3+离子的特征发射光谱, TbL3dipy(H2O)2和TbL3phen(H2O)2均产生四条谱带, 分别归属于^5D4-^7Fj(j= 6, 5,4,3)能级跃迁(TbL3dipy(H2O)2: 489.0, 545.0, 584.0, 620.0 nm;TbL3phen(H2O)2: 490.0, 544.0, 583.0, 620.0 nm);但在相同测定条件下, TbL2(TPPO)2NO3仅显示5D4-7F5(544.0 nm)能级跃迁光谱. 3种配合物中TbL3dipy(H2O)2发光强度最高. 相似文献
70.
Isolation and purification of honokiol and magnolol from cortex Magnoliae officinalis by high-speed counter-current chromatography 总被引:5,自引:0,他引:5
High-speed counter-current chromatography was used to isolate and purify honokiol and magnolol from cortex Magnoliae Officinalis (Magnolia officinalis Rehd. et Wils.), a plant used in the traditional Chinese medicine. A crude sample, 150 mg, was successfully separated with a two-phase solvent system composed of n-hexane-ethyl acetate-methanol-water (1:0.4:1:0.4, v/v), and the fractions were analyzed by high-performance liquid chromatography. The separation produced 80 and 45 mg of honokiol and magnolol with purities of 99.2 and 98.2%, respectively, in 2.5 h. 相似文献