全文获取类型
收费全文 | 7823篇 |
免费 | 1163篇 |
国内免费 | 905篇 |
专业分类
化学 | 5453篇 |
晶体学 | 75篇 |
力学 | 530篇 |
综合类 | 75篇 |
数学 | 910篇 |
物理学 | 2848篇 |
出版年
2024年 | 18篇 |
2023年 | 150篇 |
2022年 | 182篇 |
2021年 | 248篇 |
2020年 | 284篇 |
2019年 | 314篇 |
2018年 | 248篇 |
2017年 | 223篇 |
2016年 | 349篇 |
2015年 | 374篇 |
2014年 | 407篇 |
2013年 | 487篇 |
2012年 | 661篇 |
2011年 | 724篇 |
2010年 | 458篇 |
2009年 | 411篇 |
2008年 | 468篇 |
2007年 | 440篇 |
2006年 | 447篇 |
2005年 | 354篇 |
2004年 | 279篇 |
2003年 | 258篇 |
2002年 | 197篇 |
2001年 | 186篇 |
2000年 | 200篇 |
1999年 | 227篇 |
1998年 | 191篇 |
1997年 | 157篇 |
1996年 | 158篇 |
1995年 | 137篇 |
1994年 | 131篇 |
1993年 | 84篇 |
1992年 | 87篇 |
1991年 | 94篇 |
1990年 | 64篇 |
1989年 | 38篇 |
1988年 | 37篇 |
1987年 | 33篇 |
1986年 | 22篇 |
1985年 | 24篇 |
1984年 | 10篇 |
1983年 | 19篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1977年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有9891条查询结果,搜索用时 703 毫秒
81.
Zhigang Zhang Jianping Deng Weiguo Zhao Jianmin Wang Wantai Yang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):500-508
A novel chiral N‐propargylsulfamide monomer ( 1a ) and its enantiomer ( 1b ) were synthesized and polymerized with (nbd)Rh+B?(C6H5)4 as a catalyst providing poly(1) (poly( 1a ) and poly( 1b )) in high yields (≥99%). Poly(1) could take stable helices in less polar solvents (chloroform and THF), demonstrated by strong circular dichroism signals and UV–vis absorption peaks at about 415 nm and the large specific rotations; but in more polar solvents including DMF and DMSO, poly(1) failed to form helix. Quantitative evaluation with anisotropy factor showed that the helical screw sense had a relatively high thermal stability. These results together with the IR spectra measured in solvents showed that hydrogen bonding between the neighboring sulfamide groups is one of the main driving forces for poly(1) to adopt stable helices. In addition, copolymerization of monomer 1a and monomer 2 was conducted, the solubility of poly(1) was improved drastically. However, the copolymerization had adverse effects on the formation of stable helices in the copolymers. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 500–508, 2007 相似文献
82.
在本文中,严实Hilbert环得到了更进一步的刻划.本文的主要结果是:一个环A是严实Hilbert环,当且仅当多项式环A[X]的每个实极大理想在A上的局限是A的一个极大理想,当且仅当A是实Hilbert环,且A[X]的每个实极大理想是极大的. 相似文献
83.
本文讨论定义于Banach空间的多目标数学规划,得到一些ε-最优解和(弱)有效解的必要条件,充分条件和必要充分条件。 相似文献
84.
A simple and rapid method is developed to determine the high acidity and the basicity of solutions by chronopotentiometry with a platinum working electrode. The acidity range from 5.0 mol/l H+ to 1.0 mol/l OH− can be measured by the adjustment of deposition potential and time. The response mechanism to acidity and basicity has been explored. The transition potential plateau in chronopotentiograms is caused from the oxidation of hydrogen adsorbed on electrode surface. 相似文献
85.
Ye Lin Feng Zeng‐Guo Zhao Yu‐Mei Wu Feng Chen Shi Wang Guo‐Qing 《Journal of polymer science. Part A, Polymer chemistry》2006,44(11):3650-3665
A novel cyclic ether monomer 3‐{2‐[2‐(2‐hydroxyethoxy)ethoxy]ethoxy‐methyl}‐3′‐methyloxetane (HEMO) was prepared from the reaction of 3‐hydroxymethyl‐3′‐methyloxetane tosylate with triethylene glycol. The corresponding hyperbranched polyether (PHEMO) was synthesized using BF3·Et2O as initiator through cationic ring‐opening polymerization. The evidence from 1H and 13C NMR analyses revealed that the hyperbranched structure is constructed by the competition between two chain propagation mechanisms, i.e. active chain end and activated monomer mechanism. The terminal structure of PHEMO with a cyclic fragment was definitely detected by MALDI‐TOF measurement. A DSC test implied that the resulting polyether has excellent segment motion performance potentially beneficial for the ion transport of polymer electrolytes. Moreover, a TGA assay showed that this hyperbranched polymer possesses high thermostability as compared to its liquid counterpart. The ion conductivity was measured to reach 5.6 × 10?5 S/cm at room temperature and 6.3 × 10?4 S/cm at 80 °C after doped with LiTFSI at a ratio of Li:O = 0.05, presenting the promise to meet the practical requirement of lithium ion batteries for polymer electrolytes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3650–3665, 2006 相似文献
86.
A cobalt(II) tetrakisphenylporphyrin (Co(II)TPP) film modified glassy carbon electrode (Co(II)TPP-GCE) was prepared by just coating Co(II)TPP solution on the surface of the electrode. It can be used for the simultaneous determination of ascorbic acid and uric acid. The anodic peaks of AA and UA can be separated well. Owing to the strongly hydrophobic property of porphyrin, the modified electrode has good stability and long life. The linear range for UA and AA were 2.0 x 10(-6)-1.0 x 10(-4) M and 9.0 x 10(-6)-2.0 x 10(-3) M with detection limits of 5.0 x 10(-7) and 5.0 x 10(-6) M, respectively. Furthermore, metalloporphyrins of other kinds were also used to construct modified electrodes. Their performances were inferior compared with that of the Co(II)TPP modified electrode. 相似文献
87.
88.
89.
90.
7-Hydroxyderivativesofcholesteroldisplayawidevarietyofbiologicalactivities'-',mostofwhicharerelatedtothephysiologicalcontrolofcholesterolbiosynthesisandantitumoractivity.Inearlyreports',the7-hydroxycholesterolswerepreparedbythesequenceofacetylation,allylicchromicoxidation,andhydridereduction.Generally,theproductisamixtureof7a-and76-epimerswhichisdifficulttobeseparated.V.Kumaretal5improvedthisprocedurebyusingstereospecificreducingreagentsinsteadofthesimplehydride.7a-and7o-epimerscouldbeobtained… 相似文献