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151.
Iron polymethacrylate was synthesized by free radical solution polymerization of methacrylic acid, followed by replacement of the carboxylic proton with iron. Thermal volatilization analysis and thermogravimetry were used to study its thermal stability from ambient temperature up to 500oC. The results reveal that ferric oxide is left as residue at the end of the thermal degradation experiments.The authors dedicate this paper to the memory of the late Dr. Mohammad Zulfiqar of Quaid i Azam University, Islamabad, Pakistan. 相似文献
152.
We investigate the effects of temperature and density on the single-particle and many-particle coefficients as well as on
the structures of homogenous systems in which the particles are assumed to interact via a continuous soft sphere potential
in the microcanonical ensemble. The pair distribution function and therefore the structures of the systems studied are affected
by temperature close to and above the melting point through migrations of atoms from the first shell in the pair distribution
function.
The dynamics of atomic pairs in the short-time regime in liquid aluminium may be said to be governed by the potential of mean
force, which depends on the static structure of liquid Al at all investigated temperatures. A polynomial dependence ofD on density and temperature was observed in contradiction to Arrhenius law. The shear viscosities of the systems studied are
largely nonlinear. It was observed that the soft sphere potential used in our calculations overestimates the Stoke-Einstein
relation. 相似文献
153.
J. N. Spencer Travis F. Ganunis Abrahim I. Zafar Shaym Puppala James L. Ealy Larry J. Fenton Sunita Gupta C. H. Yoder J. E. Mihalick 《Journal of solution chemistry》1992,21(9):1005-1012
Equilibrium constants and enthalpies of hydrogen-bond formation of mcresol to various cyclic (crown) and acyclic polyethers have been determined in benzene solvent. Equilibrium constants indicated no evidence for an operative macrocyclic effect; the relationship between the increasing size of the equilibrium constant and the number of ether oxygens was rationalized with a simple statistical thermodynamic model. Enthalpies of interactions ranged between –19 and –23 kJ-mol–1. In agreement with PCILO calculations, enthalpies of interaction were essentially independent of the number of oxygen atoms in the ether; no significant difference in enthalpies of interaction between cyclic and acyclic ethers was found. 相似文献
154.
O.M. Hussain K. Srinivasa Rao K.V. Madhuri C.V. Ramana B.S. Naidu S. Pai J. John R. Pinto 《Applied Physics A: Materials Science & Processing》2002,75(3):417-422
Molybdenum trioxide thin films were prepared by reactive pulsed laser deposition on Corning 7059 glass substrates. The influence
of oxygen partial pressure and deposition temperature on the structure, surface morphology and optical properties of these
films was studied to understand the growth mechanism of MoO3 thin films. The films formed at 473 K in an oxygen partial pressure of 100 mTorr exhibited predominantly a (0k0) orientation,
corresponding to an orthorhombic layered structure of α-MoO3. The evaluated optical band gap of the films was 3.24 eV. The crystallite size increased with increase of deposition temperature.
The films formed at an oxygen partial pressure of pO2=100 mTorr and at a deposition temperature greater than 700 K exhibited both (0k0) and (0kl) orientations, representing α-β
mixed phases of MoO3. The films formed at an oxygen partial pressure less than 100 mTorr were found to be sub-stoichiometric with α-β mixed phases.
The investigation revealed the growth of polycrystalline and single-phase orthorhombic-layered-structure α-MoO3 thin films with composition nearly approaching the nominal stoichiometry at moderate substrate temperatures in an oxygen
partial pressure of 100 mTorr.
Received: 9 April 2001 / Accepted: 6 August 2001 / Published online: 17 October 2001 相似文献
155.
Aneeqa Khadim Tassaddaq Hussain Hassan S. Bakouch Aamir Saghir 《Mathematical Methods in the Applied Sciences》2023,46(2):2709-2728
Hydrologic design is often based on assessments of large return interval measures; it is vital to be able to conclude them as precisely as possible. Henceforth, the selection of a probability distribution is very crucial for such cases. In view of this scenario, we propose and study a pliant probability distribution for precipitation data analysis. Some mathematical and statistical properties are analyzed. In order to make stronger predictions and judge the realistic return period, we have also characterized the model via Laplace transformation. We have estimated its parameters via the maximum likelihood estimation and constructed its information matrix for developing the confidence belt of population parameters. Moreover, a real-life setup is also considered by applying the model over precipitation data of diverse regions, including Jacksonville, Florida (USA), Barkhan (Pakistan), British Columbia (Canada), and Alexandria (Egypt). This investigated study is based on various statistical parametric and nonparametric tests, which indicates that the proposed model is one of the better strategies for precipitation data analysis when compared with the famous three-parameter Kappa model. 相似文献
156.
The natural convection boundary layer on a horizontal plate with suction is investigated. The similar solutions of the boundary layer equations require suction to vary as a power law. The similarity equations have been integrated for various values of suction parameter and Prandtl number =0.72 and 6.8. For non-similar flow situation, a large suction approximation has been developed using the asymptotic approach. It is shown that large suction approximation is surprisingly good even for moderate values of suction parameter.
Einflüsse großer Wirkung auf die Grenzschicht bei freier Konvektion an einer horizontalen Platte
Zusammenfassung Es wird die Grenzschicht bei freier Konvektion auf einer horizontalen Platte unter Saugwirkung untersucht. Die Ähnlichkeitslösungen der Grenzschichtgleichungen machen es erforderlich, die Saugwirkung in Form eines Exponentialansatzes zu variieren. Die Ähnlichkeitsgleichungen wurden für verschiedene Werte des Saugparameters und für Prandtl-Zahlen zwischen 0,72 und 6,8 integriert. Für nicht-ähnliche Strömungszustände wurde eine Lösung für die Saugwirkung auf der Basis der asymptotischen Näherung entwickelt. Es wird gezeigt, daß die Näherungslösung für große Saugwirkung auch erstaunlich gute Ergebnisse für geringe Werte von Saug-Parametern liefert.相似文献
157.
Naila Raziq Muhammad Shaiq Ali Salman Zafar Muhammad Imran Ali 《Natural product research》2015,29(24):2265-2270
Phytochemical investigations on Hypericum oblongifolium led to the isolation of a flavone named folicitin (1) and a bicyclic conjugated lactone, folenolide (2) from the ethyl acetate fraction of methanolic extract. Both metabolites were characterised as new compounds based on detailed spectroscopic analyses. In vitro anti-oxidant potential of both the compounds was evaluated by the DPPH radical scavenging assay. Compound 1 exhibited significant antioxidant activity while compound 2 was found inactive. 相似文献
158.
Novel Bis(2‐(5‐((5‐phenyl‐1H‐tetrazol‐1‐yl)methyl)‐4H‐1,2,4‐triazol‐3‐yl)phenoxy)Alkanes: Synthesis and Characterization 下载免费PDF全文
In this study, 10 different substituted aromatic bis‐benzaldehydes were synthesized by treating hydroxy benzaldehydes with various dihaloalkanes. Bis aldehydes 5a , 5b , 5c , 5d , 5e , 5f , 5g , 5h , 5i , 5j were treated with 2‐(5‐phenyl‐1H‐tetrazole‐1‐yl)acetohydrazide ( 3 ) in acidic medium and in the presence of ammonium acetate to yield a series of new isomeric bis(2‐(5‐((5‐phenyl‐1H‐tetrazol‐1‐yl)methyl)‐4H‐1,2,4‐triazol‐3‐yl)phenoxy)alkanes ( 6a , 6b , 6c , 6d , 6e , 6f , 6g , 6h , 6i , 6j ) in excellent to good yield. The newly synthesized compounds were characterized by the available spectroscopic analysis. 相似文献
159.
160.
M. Hussain N. Thai Hung N. Abbas R. A. Khera I. Malik T. Patonay N. Kelzhanova Z. A. Abilov A. Villinger P. Langer 《Journal of heterocyclic chemistry》2015,52(2):497-505
Arylated benzofurans were prepared by regioselective Suzuki–Miyaura cross‐coupling reactions of 2,3‐dibromobenzofuran. The reactions proceeded with very good site‐selectivity in favor of the more electron deficient position 2. The Suzuki–Miyaura reactions of 2,3,5‐tribromobenzofuran also proceeded in favor of position 2. 相似文献