全文获取类型
收费全文 | 4797篇 |
免费 | 799篇 |
国内免费 | 545篇 |
专业分类
化学 | 3341篇 |
晶体学 | 45篇 |
力学 | 342篇 |
综合类 | 24篇 |
数学 | 606篇 |
物理学 | 1783篇 |
出版年
2024年 | 17篇 |
2023年 | 103篇 |
2022年 | 97篇 |
2021年 | 171篇 |
2020年 | 205篇 |
2019年 | 199篇 |
2018年 | 182篇 |
2017年 | 138篇 |
2016年 | 269篇 |
2015年 | 220篇 |
2014年 | 256篇 |
2013年 | 368篇 |
2012年 | 472篇 |
2011年 | 456篇 |
2010年 | 308篇 |
2009年 | 288篇 |
2008年 | 307篇 |
2007年 | 249篇 |
2006年 | 244篇 |
2005年 | 210篇 |
2004年 | 185篇 |
2003年 | 158篇 |
2002年 | 132篇 |
2001年 | 112篇 |
2000年 | 95篇 |
1999年 | 100篇 |
1998年 | 73篇 |
1997年 | 73篇 |
1996年 | 73篇 |
1995年 | 60篇 |
1994年 | 45篇 |
1993年 | 44篇 |
1992年 | 26篇 |
1991年 | 38篇 |
1990年 | 35篇 |
1989年 | 26篇 |
1988年 | 12篇 |
1987年 | 12篇 |
1986年 | 15篇 |
1985年 | 18篇 |
1984年 | 8篇 |
1983年 | 10篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1974年 | 2篇 |
1944年 | 4篇 |
1943年 | 1篇 |
1942年 | 3篇 |
1941年 | 1篇 |
1940年 | 1篇 |
排序方式: 共有6141条查询结果,搜索用时 15 毫秒
991.
By using elementary symmetric functions, this paper presents an explicit representation for the Lagrangian numerical differentiation formula as well as the error estimate for local approximation. And we also point out that the numerical differentiation formula constructed by Li [J.P. Li, General explicit difference formulas for numerical differentiation, J. Comput. Appl. Math. 183 (2005) 29-52] is actually a special case of the Lagrangian numerical differentiation formula to approximate the values of the derivatives at the nodes. 相似文献
992.
Precondition plays a critical role in the numerical methods for large and sparse linear systems. It is also true for nonlinear algebraic systems. In this paper incomplete Gröbner basis (IGB) is proposed as a preconditioner of homotopy methods for polynomial systems of equations, which transforms a deficient system into a system with the same finite solutions, but smaller degree. The reduced system can thus be solved faster. Numerical results show the efficiency of the preconditioner. 相似文献
993.
994.
Motivated by the pooling designs over the incidence matrices of matchings with various sizes of the complete graph K2n considered by Ngo and Du [Ngo and Du, Discrete Math. 243 (2003) 167–170], two families of pooling designs over the incidence matrices oft-cliques (resp. strongly t-cliques) with various sizes of the Johnson graph J(n,t) (resp. the Grassmann graph Jq(n,t)) are considered. Their performances as pooling designs are better than those given by Ngo and Du. Moreover, pooling designs associated with other special distance-regular graphs are also considered. 相似文献
995.
在原始对偶内点算法的设计和分析中,障碍函数对算法的搜索方法和复杂性起着重要的作用.本文由核函数来确定障碍函数,设计了一个求解半正定规划问题的原始-对偶内点算法.这个障碍函数即可以定义算法新的搜索方向,又度量迭代点与中心路径的距离,同时对算法的复杂性分析起着关键的作用.我们计算了算法的迭代界,得出了关于大步校正法和小步校正法的迭代界,它们分别是O(√n log n 10g n/ε)和O(√n log n/ε),这里n是半正定规划问题的维数.最后,我们根据一个算例,说明了算法的有效性以及对核函数的参数的敏感性. 相似文献
996.
Kernel functions play an important role in defining new search directions for primal-dual interior-point algorithm for solving linear optimization problems. In this paper we present a new kernel function which yields an algorithm with the best known complexity bound for both large- and small-update methods. 相似文献
997.
It can reflect the nature of approximate reasoning and meet more application expectations to design the approximate reasoning
matching schemes and the corresponding algorithms with similarity relation Q instead of equivalence relation R. In this paper, based on similarity relation Q, we introduce type V matching scheme and corresponding approximate reasoning type V Q-algorithm with the given input A* and knowledge A → B. Besides, we present completeness of type V and its perfection on knowledge base K in Q-logic ℂ
Q
in this paper. 相似文献
998.
He K Pauli GF Zheng B Wang H Bai N Peng T Roller M Zheng Q 《Journal of chromatography. A》2006,1112(1-2):241-254
Black cohosh has become one of the most important herbal products in the US dietary supplements market. It is manufactured from roots and rhizomes of Cimicifuga racemosa (Ranunculaceae). Botanical identification of the raw starting material is a key step in the quality control of black cohosh preparations. The present report summarizes a fingerprinting approach based on high performance liquid chromatography-photodiode array/mass spectrometric/evaporative light scattering detection (HPLC-PDA/MS/ELSD) that has been developed and validated using a total of 10 Cimicifuga species. These include three North American species, Cimicifuga racemosa, Cimicifuga americana, Cimicifuga rubifolia, and seven Asian species, Cimicifuga acerina, Cimicifuga biternat, Cimicifuga dahurica, Cimicifuga heracleifolia, Cimicifuga japonica, Cimicifuga foetida, and Cimicifuga simplex. The chemotaxonomic distinctiveness of the HPLC fingerprints allows identification of all 10 Cimicifuga species. The triterpene glycoside cimigenol-3-O-arabinoside (3), cimifugin (12), and cimifugin-3-O-glucoside (18) were determined to be suitable species-specific markers for the distinction of C. racemosa from the other Cimicifuga species. In addition to identification, the fingerprint method provided insight into chemical interconversion processes occurring between the diverse triterpene glycosides contained in black cohosh. The reported method has proven its usefulness in the botanical standardization and quality control of black cohosh products. 相似文献
999.
Bai YL Tao J Wernsdorfer W Sato O Huang RB Zheng LS 《Journal of the American Chemical Society》2006,128(51):16428-16429
A novel single-chain magnet, [MnIII3O(Meppz)3(EtOH)4(OAc)] (1), has been successfully synthesized from a secondary building block [MnIII3O(Meppz)3(EtOH)5Cl] (2) with an S = 1 ground state. SCM 1 exhibits both magnetization relaxation and dielectric relaxation properties. 相似文献
1000.
Bai Y Koh CG Boreman M Juang YJ Tang IC Lee LJ Yang ST 《Langmuir : the ACS journal of surfaces and colloids》2006,22(22):9458-9467
A novel surface treatment method using poly(ethyleneimine) (PEI), an amine-bearing polymer, was developed to enhance antibody binding on the poly(methyl methacrylate) (PMMA) microfluidic immunoassay device. By treating the PMMA surface of the microchannel on the microfluidic device with PEI, 10 times more active antibodies can be bound to the microchannel surface as compared to those without treatment or treated with the small amine-bearing molecule, hexamethylenediamine (HMD). Consequently, PEI surface modification greatly improved the immunoassay performance of the microfluidic device, making it more sensitive and reliable in the detection of IgG. The improvement can be attributed to the spacer effect as well as the functional amine groups provided by the polymeric PEI molecules. Due to the smaller dimensions (140x125 microm) of the microchannel, the time required for antibody diffusion and adsorption onto the microchannel surface was reduced to only several minutes, which was 10 times faster than the similar process carried out in 96-well plates. The microchip also had a wider detection dynamic range, from 5 to 1000 ng/mL, as compared to that of the microtiter plate (from 2 to 100 ng/mL). With the PEI surface modification, PMMA-based microchips can be effectively used for enzyme linked immunosorbent assays (ELISA) with a similar detection limit, but much less reagent consumption and shorter assay time as compared to the conventional 96-well plate. 相似文献