全文获取类型
收费全文 | 315篇 |
免费 | 14篇 |
国内免费 | 2篇 |
专业分类
化学 | 244篇 |
晶体学 | 4篇 |
力学 | 12篇 |
数学 | 11篇 |
物理学 | 60篇 |
出版年
2024年 | 2篇 |
2023年 | 2篇 |
2022年 | 8篇 |
2021年 | 9篇 |
2020年 | 16篇 |
2019年 | 14篇 |
2018年 | 17篇 |
2017年 | 13篇 |
2016年 | 14篇 |
2015年 | 16篇 |
2014年 | 14篇 |
2013年 | 30篇 |
2012年 | 29篇 |
2011年 | 43篇 |
2010年 | 18篇 |
2009年 | 12篇 |
2008年 | 12篇 |
2007年 | 17篇 |
2006年 | 7篇 |
2005年 | 15篇 |
2004年 | 7篇 |
2003年 | 1篇 |
2002年 | 5篇 |
2001年 | 1篇 |
1998年 | 2篇 |
1996年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
排序方式: 共有331条查询结果,搜索用时 15 毫秒
41.
This paper describes a micromachined piezoelectric sensor, integrated into a cavity at the tip of a biopsy needle, and preliminary experiments to determine if such a device can be used for real-time tissue differentiation, which is needed for needle positioning guidance during fine needle aspiration (FNA) biopsy. The sensor is fabricated from bulk lead zirconate titanate (PZT), using a customized process in which micro electro-discharge machining is used to form a steel tool that is subsequently used for batch-mode ultrasonic micromachining of bulk PZT ceramic. The resulting sensor is 50 microm thick and 200 microm in diameter. It is placed in the biopsy needle cavity, against a steel diaphragm which is 300 microm diameter and has an average thickness of 23 microm. Devices were tested in materials that mimic the ultrasound characteristics of human tissue, used in the training of physicians, and with porcine fat and muscle tissue. In both schemes, the magnitude and frequency of an electrical impedance resonance peak showed tissue-specific characteristics as the needle was inserted. For example, in the porcine tissue, the impedance peak frequency changed approximately 13 MHz from the initial 163 MHz, and the magnitude changed approximately 1600 Omega from the initial 2100 Omega, as the needle moved from fat to muscle. Samples including oils and saline solution were tested for calibration, and an empirical tissue contrast model shows an approximately proportional relationship between measured frequency shift and sample acoustic impedance. These results suggest that the device can complement existing methods for guidance during biopsies. 相似文献
42.
Delafuente DA Kosturko GW Graham PM Harman WH Myers WH Surendranath Y Klet RC Welch KD Trindle CO Sabat M Harman WD 《Journal of the American Chemical Society》2007,129(2):406-416
A series of pyridine complexes are prepared of the general form TpW(NO)(PMe3)(pyr) where pyr is either pyridine or a substituted pyridine. Depending on substitution pattern, the pyridine can be either N- or eta2-coordinated, and the role of the pyridine substituents and metal oxidation state in determining this equilibrium is explored. For eta2-pyridine complexes, the substituent pattern and solubility characteristics also determine the ratio of coordination diastereomers. Rates of both intra- and interfacial linkage isomerizations are explored along with the pyridine rotational barrier. This study is supported by DFT calculations and X-ray data and includes characterization of both eta2-pyridine and eta2-pyridinium complexes. 相似文献
43.
Neha Taneja Patrizia Bocchetta Ashwani Kumar Pallavi Gupta Meenal Gupta Pushpa Singh Bharti Beniwal Namrata Agrawal Yogesh Kumar 《Macromolecular Symposia》2024,413(1):2300016
The study has prepared highly conducting polymer electrolyte films using solution cast technique with poly(vinylidene fluoride-co-hexafluoropropylene) PVDF-HFP, mixture of ethylene carbonate (EC), and propylene carbonate (PC) as plasticizer and latex of Calotropis gigantea (CGL) as an ionic source. In this study, four films are prepared using PVDF-HFP:CGL in ratio 1:1 with the increasing concentration of EC+PC as 1, 2, 3, and 4 M named as 1:1:1, 1:1:2, 1:1:3, 1:1:4. The prepared polymer electrolyte is examined by polarized optical microscopy (POM), elemental dispersive X-ray technique (EDX), and complex impedance spectroscopy. EDX and POM are studied for the surface morphology of all prepared samples and to investigate the porous nature of films. The enhancement in ionic conductivity occurs due to CGL and increasing amount of EC-PC. Conductivity of highest composition (1:1:4) polymer electrolyte film is found to be ≈10−3 S cm−1. The optimized polymer electrolyte film is considered as a promising candidate for application in supercapacitors. 相似文献
44.
In this framework, the novel analytical approach is presented to predict the dual solutions of Jeffery–Hamel (JH) transport model utilizing KKL (Koo–Kleinstreuer–Li) Al2O3 model with magnetic field, Ohmic heating and viscous dissipation. The predictor homotopy analysis method (PHAM) is applied to realize the existence of multiple solutions (bifurcation) for stretching/shrinking parameter and channel angle. It is observed that the dual solutions exist only for convergent channel. The eigenvalue problem is constructed to perform stability analysis which shows the physically stability of the upper branch. A numerical validation with Runge–Kutta–Fehlberg (RKF) shooting method using MATLAB is also carried out for verification. The Reynolds number is responsible to increase the velocity of fluid for both branches of the solution. For the increasing values of Ec and M, the Nusselt number decreases and increases respectively. 相似文献
45.
M. S. Negi Yogesh Prasad Ganesh Prasad G. S. Gusain Manjari Badoni R. C. Ramola 《Indian Journal of Physics》2009,83(8):1209-1214
The natural pollution level due to gamma radiation was measured in about 22 residential houses around the Tehri Dam Project
in Uttarakhand state by using Environmental Radiation Dosimeter. Both urban and rural houses were selected for the measurements.
The recorded gamma dose rate in indoor atmosphere was found to vary from 25.1 μR/h to 67 μR/h with a mean value 38.6 μR/h
whereas in traditional rural houses the obtained values varied from 42.6 μR/h to 83.5 μR/h with mean value 60.3 μR/h. In outdoor
atmosphere, it was found to vary from 25.1 μR/h to 60 μR/h with an average value 35.8 μR/h. It is observed that the dose rates
are higher in rural houses than that in modern houses. Efforts have also been made to observe deviation of dose rate in the
underground (Power House) atmosphere of Tehri Dam Project in vertical and horizontal mode. It was observed that dose rate
remain almost same in horizontal mode, but a significant variation has been found in the vertical mode. In addition, the variation
of dose rate with type of building material, trend and mode of construction of houses and the age of houses are also discussed
in detail. 相似文献
46.
Ganesh Prasad Yogesh Prasad G. S. Gusain Manjari Badoni J. M. S. Rana R. C. Ramola 《Indian Journal of Physics》2009,83(6):887-892
Radon was measured in soil-gas and groundwater in the Budhakedar area of Tehri Garhwal, India in summer and winter to obtain
the seasonal variation and its correlation with radon exhalation rate. The environmental surface gamma dose rate was also
measured in the same area. The radon exhalation rate in the soil sample collected from different geological unit of Budhakedar
area was measured using plastic track detector (LR-115 type II) technique. The variation in the radon concentration in soil-gas
was found to vary from 1098 to 31,776 Bq.m−3 with an average of 7456 Bq.m−3 in summer season and 3501 to 42883 Bq.m−3 with an average of 17148 Bq.m−3 in winter season. In groundwater, it was found to vary from 8 to 3047 Bq.l−1 with an average value 510 Bq.l−1 in summer and 26 to 2311 Bq.l−1 with an average value 433 Bq.L−1 in winter. Surface gamma dose rate in the study area varied from 32.4 to 83.6 μR.h−1 with an overall mean of 58.7 μ-R.h−1 in summer and 34.6 to 79.3 μR.h−1 with an average value 58.2 μR.h−1 in winter. Radon exhalation rate from collected soil samples was found to vary from 0.1 × 10−5 to 5.7 × 10−5 Bq.kg−1.h−1 with an average of 1.5 × 10−5 Bq.kg−1.h−1 in summer season and 1.7 × 10−5 to 9.6 × 10−5 Bq.kg−1.h−1 with an average of 5.5 × 10−5 Bq.kg−1.h−1. A weak negative correlation was observed between radon exhalation rate from soil and radon concentration in the soil. Radon
exhalation rate from the soil was also not found to be correlated with the gamma dose rate, while it shows a positive correlation
with radon concentration in water in summer season. Inter-correlations among various parameters are discussed in detail.
相似文献
47.
When divalent metal chloride solutions of Mn, Fe, Co, Ni and Cd were mixed with potassium titanyl oxalate solution, mixed metal oxalates were obtained in the case of Fe, Co and Ni at room temperature in the pH range 1.5–3. In the case of manganese, heating was found to be necessary to induce precipitation and complete precipitation occurred at 80 °C. Mixed cadmium and titanyl oxalate precipitation was complete at a pH of 3 at room temperature. Various physico-chemical techniques were employed to characterize the as-dried oxalate precursors and the final MTiO3 oxide powders (M = Mn, Fe, Co, Ni and Cd) obtained on thermal decomposition. All these experimental results relating to the synthesis and characterizations of MTiO3 oxides are presented in this paper. The results suggest that the reaction of potassium titanyl oxalate and metal chloride solutions may not lead to the formation of a single molecular precursor by direct salt elimination reaction in the pH range 1.5–3. 相似文献
48.
49.
In the present article, we have analyzed the dispersion of electromagnetic wave in the one dimensional magnetized ferrite photonic crystals near the resonance in the permeability of the constituent materials for transverse magnetization in the transverse electric mode. The dispersion relation is obtained by transfer matrix method. It is observed that in the vicinity of resonant frequency, large numbers of oscillations occur in the normalized Bloch wave number. These oscillations in the Bloch wave number are strongly dependent on external magnetic fields, filling factor, and damping constant. The frequency regime of these oscillations is found to be shifted in higher frequency range with increase in the magnitude of the magnetic fields. With increase in the filling factor keeping length of periods fixed, number of oscillations is found to be increased. Near the resonance, effect of incident angle is negligible. It is demonstrated that these nearly equidistant oscillations occurring in the vicinity of resonance may be used for making filter in micro wave frequency range. 相似文献
50.
Parmod Kumar Yogesh Kumar Hitendra K. Malik S. Annapoorni Sanjeev Gautam Keun Hwa Chae K. Asokan 《Applied Physics A: Materials Science & Processing》2014,114(2):453-457
Room-temperature multiferroic properties in Mg-doped ZnO samples are reported wherein Mg replaces Zn in the ZnO matrix and retains hexagonal wurtzite structure. The saturation magnetisation is increased from ~2×10?4 emu/g to 3×10?4 emu/g for the dilute doping of 2 % Mg in pure ZnO and the ferroelectricity is also increased. Higher concentration of Mg does not lead to a significant enhancement in the magnetisation but improves the ferroelectric properties. An X-ray absorption spectroscopic study shows an enhancement in O vacancies with dilute doping of Mg. The origin of the multiferroic behaviour is understood based on their crystal and electronic structures. 相似文献